KR940013809A - 표면 광택성이 뛰어난 중공 성형 다층 용기 및 이의 제조 방법 - Google Patents

표면 광택성이 뛰어난 중공 성형 다층 용기 및 이의 제조 방법 Download PDF

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KR940013809A
KR940013809A KR1019930029465A KR930029465A KR940013809A KR 940013809 A KR940013809 A KR 940013809A KR 1019930029465 A KR1019930029465 A KR 1019930029465A KR 930029465 A KR930029465 A KR 930029465A KR 940013809 A KR940013809 A KR 940013809A
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plastic container
multilayer plastic
flow characteristic
logτ
seconds
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야스히로 오다
요시쯔구 마루바시
고우자부로 사카노
유지 야마구찌
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미키 히로시
도요 세이칸 가부시키가이샤
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/22Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor using multilayered preforms or parisons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a non-planar shape
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/16Layered products comprising a layer of synthetic resin specially treated, e.g. irradiated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0036Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • B65D1/02Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00Containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material, by deep-drawing operations performed on sheet material
    • B65D1/02Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
    • B65D1/0207Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by material, e.g. composition, physical features
    • B65D1/0215Bottles or similar containers with necks or like restricted apertures, designed for pouring contents characterised by material, e.g. composition, physical features multilayered
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/07Preforms or parisons characterised by their configuration
    • B29C2949/081Specified dimensions, e.g. values or ranges
    • B29C2949/0811Wall thickness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/07Preforms or parisons characterised by their configuration
    • B29C2949/081Specified dimensions, e.g. values or ranges
    • B29C2949/0811Wall thickness
    • B29C2949/0819Wall thickness of a layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/07Preforms or parisons characterised by their configuration
    • B29C2949/081Specified dimensions, e.g. values or ranges
    • B29C2949/082Diameter
    • B29C2949/0821Diameter of the lip, i.e. the very top of the preform neck
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2949/00Indexing scheme relating to blow-moulding
    • B29C2949/07Preforms or parisons characterised by their configuration
    • B29C2949/081Specified dimensions, e.g. values or ranges
    • B29C2949/0829Height, length
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/02Combined blow-moulding and manufacture of the preform or the parison
    • B29C49/04Extrusion blow-moulding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/08Surface shaping of articles, e.g. embossing; Apparatus therefor by flame treatment ; using hot gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/04Polymers of ethylene
    • B29K2023/06PE, i.e. polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • B29K2023/10Polymers of propylene
    • B29K2023/12PP, i.e. polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/712Containers; Packaging elements or accessories, Packages
    • B29L2031/7158Bottles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2310/00Treatment by energy or chemical effects
    • B32B2310/04Treatment by energy or chemical effects using liquids, gas or steam
    • B32B2310/0445Treatment by energy or chemical effects using liquids, gas or steam using gas or flames
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/40Closed containers
    • B32B2439/60Bottles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
  • Laminated Bodies (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)

Abstract

본 발명은 하기 식(1) 및 (2)을 만족하는 유동 특성을 갖는 올레핀 수지를 용기의 바깥쪽 표면으로 중공 성형시킴으로써 샤크스킨이나 플로우 마크의 발생을 방지하며, 더구나 중공 성형물의 바깥쪽 표면을 용융처리로 부착시킴으로써, 금형 샌드 블라스트 면에 의해 요철 무늬도 해소시키고, 표면 광택성이 뛰어난 중공 성형 다층 플라스틱 용기를 제공하는 것이다.
logτ ≤ n+ 5.15 (1)
logτ ≥ n+ 4.95 (2)
상기 식에서, τ는 상기 세관 유동계에 의한 흐름 특성 시험 방법에 있어서의 전단 웅력 (dyne/cm2)이며,는 상기 특정에 있어서의 전단 속도(초-1)이고, n은 0.39-0.41의 수이며,은 9×101내지 1.2×103-1범위이다.

Description

표면 광택성이 뛰어난 중공 성형 다층 용기 및 이의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 올레핀 수지의 용융물에 대해 절단 응력(τ)과 전단 속도(와의 관계를 나타낸 그래프이다.
제2도는 본 발명 중공 성형 다층 플라스틱 용기의 일례를 나타낸 측면 단면도이다.
제3도는 제2도의 용기벽 Ⅲ의 단면 구조를 확대해서 나타낸 단면도이다.
제4도는 중공 성형 다층 플라스틱 용기의 단면구조의 다른 예를 나타낸 단면도이다.

Claims (7)

  1. 2종 이상의 수지층이 적층된 구조의 중공 성형 다층 플라스틱 용기에 있어서, 가장 바깥쪽의 표면층이 직경 lmm 및 길이 10mm의 노즐 및 측정 온도 190℃의 세관 유동계에 의한 흐름 특성 시험 방법 (JIS K7199)에 있어서, 하기 식 (1) 및 (2)을 만족하는 유동 특성을 갖는 올레핀 중합체로 형성되며, 또한 가장 바깥쪽 표면이 용융 처리되어 있는 것을 특징으로 하는 표면 광택성이 뛰어난 다층 플라스틱 용기 :
    logτ ≤ n+ 5.15 (1)
    logτ ≥ n+ 4.95 (2)
    상기 식에서, τ는 상기 세관 유동계에 의한 흐름 특성 시험 방법에 있어서의 전단 웅력 (dyne/cm2)이며,는 상기 측정에 있어서의 전단 속도(초-1)이고, n은 0.39-0.41의 수이며,은 9×101내지 1.2×103-1범위내이다.
  2. 제1항에 있어서, 올레핀 중합체가 에틸렌·프로필렌·랜덤 공중합체인 다층 플라스틱 용기.
  3. 제2항에 있어서, 에틸렌·프로필렌·랜덤 공중합체가 27×104내지 33×104의 중량 평균 분자량을 갖는 다층 플라스틱 용기.
  4. 제2항에 있어서, 에틸렌·프로필렌·공중합체가 2 내지 8중량%의 에틸렌 함유량을 갖는 것인 다층 플라스틱 용기.
  5. 제1항에 있어서, 바깥 표면층 이외의 수지가 중공 성형 등급의 올레핀 수지로 이루어진 다층 플라스틱 용기.
  6. 중공 성형 등급의 올레핀 수지를 기질로하고, 직경 1mm 및 길이 10mm의 노즐 및 측정 온도 190℃의 세관 유동계에 의한 흐름 특성 시험 방법 (JIS K 7199)에 있어서, 하기 식 (1) 및 (2)을 만족하는 유동특성을 갖는 올레핀수지를 바깥층으로서 공압출시키고, 샌드 블라스트 면을 갖는 중공 형내에서 상기 압출된 파리손을 중공 성형시키고, 이어서 중공 성형물의 가장 바깥쪽면을 용융 처리하는 것을 특징으로 하는 표면 광택성이 뛰어난 다층 플라스틱 용기의 제조 방법 :
    logτ ≤+ 5.15 (1)
    logτ ≥+ 4.95 (2)
    상기 식에서, τ는 상기 세관 유동계에 의한 흐름 특성 시험 방법에 있어서의 전단 웅력 (dyne/cm2)이며,는 상기 특정에 있어서의 전단 속도(초-1)이고, n은 0.39-0.41의 수이며,는 9×101내지 1.2×103-1범위내이다.
  7. 제6항에 있어서, 중공 성형물의 가장 바깥쪽 면을 화염 처리에 의해 용융시킨 다층 플라스틱 용기의 제조 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930029465A 1992-12-25 1993-12-24 표면 광택성이 뛰어난 중공 성형 다층 용기 및 이의 제조 방법 KR100220281B1 (ko)

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JP92-344975 1992-12-25
JP34497592A JP2606645B2 (ja) 1992-12-25 1992-12-25 表面光沢性に優れたブロー成形多層プラスチック容器

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KR940013809A true KR940013809A (ko) 1994-07-16
KR100220281B1 KR100220281B1 (ko) 1999-09-15

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EP (1) EP0604239B1 (ko)
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AU591926B2 (en) * 1986-09-08 1989-12-21 American National Can Company Reducing development of off-flavours in comestibles in packaged plastic containers
JPH0717042B2 (ja) * 1989-02-17 1995-03-01 東洋製罐株式会社 表面光沢性に優れた多層プラスチック容器
JP2942802B2 (ja) * 1990-08-10 1999-08-30 株式会社吉野工業所 高光沢性容器の製造法
JP3143244B2 (ja) * 1991-12-05 2001-03-07 チッソ株式会社 好外観成形品の製造方法

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US5443868A (en) 1995-08-22
EP0604239A1 (en) 1994-06-29
DE69300812T2 (de) 1996-04-18
JPH06190993A (ja) 1994-07-12
AU672057B2 (en) 1996-09-19
EP0604239B1 (en) 1995-11-15
DE69300812D1 (de) 1995-12-21
AU5273093A (en) 1994-07-07
KR100220281B1 (ko) 1999-09-15
JP2606645B2 (ja) 1997-05-07
DK0604239T3 (da) 1995-12-18

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