KR940007061A - 올레핀 중합용 촉매성분 및 촉매 - Google Patents
올레핀 중합용 촉매성분 및 촉매 Download PDFInfo
- Publication number
- KR940007061A KR940007061A KR1019930019497A KR930019497A KR940007061A KR 940007061 A KR940007061 A KR 940007061A KR 1019930019497 A KR1019930019497 A KR 1019930019497A KR 930019497 A KR930019497 A KR 930019497A KR 940007061 A KR940007061 A KR 940007061A
- Authority
- KR
- South Korea
- Prior art keywords
- radicals
- catalyst
- hydrogen
- radical
- titanium
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract 16
- 150000001336 alkenes Chemical class 0.000 title claims abstract 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract 5
- 238000006116 polymerization reaction Methods 0.000 title claims abstract 5
- -1 magnesium halides Chemical class 0.000 claims abstract 21
- 150000001875 compounds Chemical class 0.000 claims abstract 9
- 229910052719 titanium Inorganic materials 0.000 claims abstract 9
- 239000010936 titanium Substances 0.000 claims abstract 9
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 7
- 239000001257 hydrogen Substances 0.000 claims abstract 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract 5
- 150000004985 diamines Chemical class 0.000 claims abstract 5
- 229910052736 halogen Inorganic materials 0.000 claims abstract 5
- 229910052749 magnesium Inorganic materials 0.000 claims abstract 4
- 239000011777 magnesium Substances 0.000 claims abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract 2
- 229930195733 hydrocarbon Natural products 0.000 claims abstract 2
- 150000003254 radicals Chemical class 0.000 claims 8
- 125000003118 aryl group Chemical group 0.000 claims 2
- 150000005840 aryl radicals Chemical class 0.000 claims 2
- 239000007795 chemical reaction product Substances 0.000 claims 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 2
- 238000000605 extraction Methods 0.000 claims 2
- 150000002431 hydrogen Chemical class 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 claims 1
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 claims 1
- 125000002877 alkyl aryl group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 125000000596 cyclohexenyl group Chemical group C1(=CCCCC1)* 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 150000002367 halogens Chemical group 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- GBXQPDCOMJJCMJ-UHFFFAOYSA-M trimethyl-[6-(trimethylazaniumyl)hexyl]azanium;bromide Chemical compound [Br-].C[N+](C)(C)CCCCCC[N+](C)(C)C GBXQPDCOMJJCMJ-UHFFFAOYSA-M 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000011949 solid catalyst Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/09—Diamines
- C07C211/11—Diaminopropanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/25—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing rings other than six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/26—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing at least one six-membered aromatic ring
- C07C211/27—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing at least one six-membered aromatic ring having amino groups linked to the six-membered aromatic ring by saturated carbon chains
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
본 발명은 활성 형태의 마그네슘 할라이드, 및 여기에 담지된 티타늄 할라이드 또는 티타늄 할로겐 알콜레이트 및 하기 일반식(Ⅰ)의 디아민으로 부터 선택된 전자 공여 화합물을 함유하는 올레핀 중합용 촉매 성분에 관한 것이다.
(상기 식에서, 라디칼 R1∼R10은 동일하거나 상이하며 수소 또는 C1-C18탄화수소 라디칼이며, 단, R7및 R8라디칼의 적어도 하나 및 R9및 R10라디칼의 적어도 하나는 수소가 아니다)
또한, 상기한 촉매 성분 및 Al-알킬 화합물로 부터 수득한 촉매, 및 Al-알킬 화합물 및 일반식(Ⅰ)의 디아민과 티타늄 할라이드 또는 티타늄 할로겐 알콜레이트, 및 Al-트리에틸을 사용한 특이한 특성을 가진 전자-공여 화합물을 함유하는 고형 촉매 성분과의 반응으로 부터 수득한 촉매가 기재되어 있다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 활성 형태의 마그네슘 할라이드, 및 그위에 담지된 티타늄 할라이드 또는 티타늄 할로겐 알콜레이트 및 하기 일반식(Ⅰ)의 디아민으로 부터 선택된 전자 공여 화합물을 함유하는 올레핀 중합용 촉매 성분.(상기 식에서, 라디칼 R1∼R10은 동일하거나 상이하며 수소 도는 C1-C18탄화수소 라디칼, C3-C18시클로알킬라디칼, C6-C18아릴 라디칼, C7-C18알카릴 또는 아르알킬 라디칼이며, 단, R7및 R8라디칼의 적어도 하나 및 R9및 R10라디칼의 적어도 하나는 수소가 아니다)
- 제1항에 있어서, 라디칼 R1∼R8이 수소, 메틸, 에틸, n-프로필, 이소프로필, n-부틸, 이소부틸, sec-부틸, tert-부틸, 시클로헥실, 시클로헥세닐, 시클로헥실메틸, 페닐 및 벤질로 구성된 군으로부터 선택된 촉매 성분.
- 제1항에 있어서, 라디칼 R7∼R10이 C1-C6알킬 및 C3-C6시클로알킬로 구성된 군으로부터 선택된 촉매 성분.
- 제1항에 있어서, 마그네슘 할라이드가 MgCl2이고 티타늄 할라이드가 TiCl4인 촉매 성분.
- (A) 제1항에 정의한 촉매 성분; (B) Al-알킬 화합물; (C) 임의적으로 전자 공여 화합물의 반응 생성물을 함유함을 특징으로 하는 올레핀 중합용 촉매.
- 제5항에 있어서, Al-아킬 화합물(B)가 Al-트리알킬 화합물이 촉매.
- 제5항에 있어서, 전자 공여 화합물(C)가 하기 일반식 화합물로 부터 선택된 촉매.RmSiYnXp(상기 식에서, R은 C1-C20알킬, C2-C20알케닐, C6-C20아릴, C7-C20아르알킬, 또는 C3-C20시클로알킬이며; Y는 -OR′, -OCOR′, -NR′2라디칼(식중, R′는 R과 동일하거나 상이하며 R과 동이한 의마를 갖는다)이며; X는 할로겐 또는 수소원자이거나, 또는 -OCR″ 또는 -NR″2기(식중, R″는 R′과 동일하거나 상이하며 R′와 동일한 의미를 갖는다)이고; m은 0∼3이고, n은 1∼4이며, p는 0∼4이며, p는 0∼1이고 m+n+p는 4이다)
- Al-알킬 화합물 및 제1항의 일반식(Ⅰ)의 디아민과, 활성형태의 마그네슘 할라이드, 티타늄 할라이드 또는 티타늄 할로겐 알콜레이트, 및 Al-트리에틸을 사용하여 표준 추출 조건하에서 70몰%이상을 추출할 수 있는 전자-공여 화합물을 함유하며 추출 후 표면적이 20㎡/g보다 큰 고형 성분과의 반응 생성물을 함유함을 특징으로 하는 올레핀 중합용 촉매.
- 제8항에 있어서, 고형 성분에 존재하는 전자-공여 화합물이 프탈산 에스테르인 촉매.
- 하기 일반식(Ⅰ)의 디아민.(상기 식에서, 라디칼 R1∼R10은 동일하거나 상이하며 수소, C1-C18직쇄 또는 측쇄 알킬 라디칼, C3-C18시클로알킬 라디칼 C6-C18아릴 라디칼, C7-C18알카릴 또는 아르알킬 라디칼이며, 단 R7및 R8라디칼의 적어도 하나 및 R9및 R10라디칼의 적어도 하나는 수소가 아니다)※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI922197A IT1255523B (it) | 1992-09-24 | 1992-09-24 | Componenti e catalizzatori per la polimerizzazione di olefine |
| ITMI92A002197 | 1992-09-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR940007061A true KR940007061A (ko) | 1994-04-26 |
| KR100293575B1 KR100293575B1 (ko) | 2001-09-17 |
Family
ID=11363995
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019930019497A KR100293575B1 (ko) | 1992-09-24 | 1993-09-23 | 올레핀중합용촉매성분및촉매 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5552359A (ko) |
| EP (1) | EP0589474B1 (ko) |
| JP (1) | JP3429819B2 (ko) |
| KR (1) | KR100293575B1 (ko) |
| CN (1) | CN1032310C (ko) |
| AT (1) | ATE152456T1 (ko) |
| CA (1) | CA2106835C (ko) |
| DE (1) | DE69310300T2 (ko) |
| DK (1) | DK0589474T3 (ko) |
| FI (1) | FI111082B (ko) |
| IT (1) | IT1255523B (ko) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5500396A (en) * | 1995-02-09 | 1996-03-19 | Phillips Petroleum Company | Process to make small, discrete, spherical adducts |
| US6436864B1 (en) * | 1999-10-06 | 2002-08-20 | Sri International | Unsaturated nitrogenous compounds as electron donors for use with ziegler-natta catalysts |
| CA2485168A1 (en) * | 2002-05-06 | 2003-11-20 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed catalyst compositions for the production of polyolefins |
| EP1548035A4 (en) | 2002-09-11 | 2006-08-09 | Japan Polypropylene Corp | CATALYST FOR THE POLYMERIZATION OF AN α-OLEFIN AND METHOD FOR THE PREPARATION OF α-OLEFIN POLYMER BY USING THE SAME |
| CN1318457C (zh) * | 2004-09-02 | 2007-05-30 | 中国石油化工股份有限公司<Del/> | 用于烯烃聚合反应的催化剂组分和催化剂 |
| US8288606B2 (en) * | 2005-03-08 | 2012-10-16 | Ineos Usa Llc | Propylene polymer catalyst donor component |
| JP4905938B2 (ja) * | 2006-08-29 | 2012-03-28 | 東邦チタニウム株式会社 | オレフィン類重合用触媒及びこれを用いたオレフィン類重合体の製造方法 |
| CN101735346B (zh) | 2008-11-07 | 2012-05-30 | 中国石油天然气股份有限公司 | 一种丙烯均聚和共聚的催化剂及其制备方法和应用 |
| KR20190038812A (ko) * | 2016-06-30 | 2019-04-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 낮은 공 단량체 도입용 전촉매 조성물 및 이의 제조 공정 |
| EP3339333B1 (en) * | 2016-12-22 | 2020-10-07 | Borealis AG | Ziegler-natta catalyst and preparation thereof |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL113050C (ko) * | 1958-09-17 | |||
| YU35844B (en) * | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
| NL162664B (nl) * | 1969-06-20 | 1980-01-15 | Montedison Spa | Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1. |
| LU61374A1 (ko) * | 1970-07-20 | 1972-04-04 | ||
| US4107414A (en) * | 1971-06-25 | 1978-08-15 | Montecatini Edison S.P.A. | Process for the stereoregular polymerization of alpha olefins |
| US4186107A (en) * | 1978-04-14 | 1980-01-29 | Hercules Incorporated | Solid catalyst component for olefin polymerization |
| GB2054616B (en) * | 1979-07-09 | 1983-03-02 | El Paso Polyolefins | Propylene polymerization process and product |
| GB2054618B (en) * | 1979-07-24 | 1984-02-08 | Mitsui Toatsu Chemicals | Thermosetting resin composition |
| DE3068239D1 (en) * | 1979-11-20 | 1984-07-19 | Shell Int Research | Preparation of catalyst components and polymerization of olefins employing such catalyst components |
| US4277372A (en) * | 1980-01-09 | 1981-07-07 | Hercules Incorporated | Solid catalyst component for olefin polymerization |
| US4487845A (en) * | 1980-05-09 | 1984-12-11 | Stauffer Chemical Company | Method of enhancing stereospecificity of a catalyst system |
| IT1209255B (it) * | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
| EP0072129B2 (en) * | 1981-08-07 | 1990-02-28 | Imperial Chemical Industries Plc | Supported transition metal composition |
| IT1190682B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine |
| IT1190683B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| JPS58138705A (ja) * | 1982-02-12 | 1983-08-17 | Mitsui Petrochem Ind Ltd | オレフイン系重合体の製造方法 |
| US4532313A (en) * | 1982-10-13 | 1985-07-30 | Himont Incorporated | Method for preparing an improved catalyst support, Ziegler-Natta catalyst utilizing said support and polymerization of 1-olefins utilizing said catalyst |
| US4506029A (en) * | 1982-12-20 | 1985-03-19 | Stauffer Chemical Company | Supported catalyst for polymerization of olefins |
| US5196138A (en) * | 1989-06-30 | 1993-03-23 | Cyprus Foote Mineral Company | Preparation of mixed lithium amide reagents |
| IT1241093B (it) * | 1990-03-30 | 1993-12-29 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| US5182346A (en) * | 1990-08-02 | 1993-01-26 | Borden, Inc. | Accelerators for curing phenolic resole resins |
-
1992
- 1992-09-24 IT ITMI922197A patent/IT1255523B/it active IP Right Grant
-
1993
- 1993-09-22 FI FI934152A patent/FI111082B/fi active
- 1993-09-23 KR KR1019930019497A patent/KR100293575B1/ko not_active IP Right Cessation
- 1993-09-23 CA CA002106835A patent/CA2106835C/en not_active Expired - Fee Related
- 1993-09-24 JP JP26168693A patent/JP3429819B2/ja not_active Expired - Fee Related
- 1993-09-24 DE DE69310300T patent/DE69310300T2/de not_active Expired - Fee Related
- 1993-09-24 AT AT93115444T patent/ATE152456T1/de not_active IP Right Cessation
- 1993-09-24 CN CN93119343A patent/CN1032310C/zh not_active Expired - Fee Related
- 1993-09-24 EP EP93115444A patent/EP0589474B1/en not_active Expired - Lifetime
- 1993-09-24 DK DK93115444.7T patent/DK0589474T3/da active
-
1995
- 1995-02-21 US US08/391,327 patent/US5552359A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1087918A (zh) | 1994-06-15 |
| FI111082B (fi) | 2003-05-30 |
| DK0589474T3 (da) | 1997-12-22 |
| FI934152A0 (fi) | 1993-09-22 |
| EP0589474A3 (en) | 1994-10-19 |
| US5552359A (en) | 1996-09-03 |
| EP0589474A2 (en) | 1994-03-30 |
| DE69310300T2 (de) | 1997-12-18 |
| EP0589474B1 (en) | 1997-05-02 |
| IT1255523B (it) | 1995-11-09 |
| FI934152A (fi) | 1994-03-25 |
| CA2106835C (en) | 1999-02-02 |
| ITMI922197A0 (it) | 1992-09-24 |
| JP3429819B2 (ja) | 2003-07-28 |
| ITMI922197A1 (it) | 1994-03-24 |
| DE69310300D1 (de) | 1997-06-05 |
| ATE152456T1 (de) | 1997-05-15 |
| CA2106835A1 (en) | 1994-03-25 |
| CN1032310C (zh) | 1996-07-17 |
| JPH06263816A (ja) | 1994-09-20 |
| KR100293575B1 (ko) | 2001-09-17 |
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