KR960022584A - 올레핀의 중합반응용 촉매계 - Google Patents
올레핀의 중합반응용 촉매계 Download PDFInfo
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- KR960022584A KR960022584A KR1019940033314A KR19940033314A KR960022584A KR 960022584 A KR960022584 A KR 960022584A KR 1019940033314 A KR1019940033314 A KR 1019940033314A KR 19940033314 A KR19940033314 A KR 19940033314A KR 960022584 A KR960022584 A KR 960022584A
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst system
- group
- catalyst
- butyl
- silane compound
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims abstract 9
- 150000001336 alkenes Chemical class 0.000 title claims abstract 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract 4
- 238000006116 polymerization reaction Methods 0.000 title claims abstract 3
- -1 silane compound Chemical class 0.000 claims abstract 11
- 229910000077 silane Inorganic materials 0.000 claims abstract 4
- 125000000217 alkyl group Chemical group 0.000 claims abstract 3
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims abstract 2
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims abstract 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims abstract 2
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims abstract 2
- 239000002685 polymerization catalyst Substances 0.000 claims abstract 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- 125000005234 alkyl aluminium group Chemical group 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 125000000962 organic group Chemical group 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0204—Ethers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
- B01J31/0275—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 also containing elements or functional groups covered by B01J31/0201 - B01J31/0269
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
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- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
본 발명은 Ziegler-Natta 형태의 중합촉매와 전자주게인 일반식(I)로 표시되는 실란화합물로 이루어지는 올레핀 중합반응용 촉매계에 관한 것이다.
일반식(I)에서 R′은 트리메틸실릴메틸 혹은 2-페닐프로필기를 나타내고, R2는 1-헥실, 시클로헥실, 시클로펜틸, 노말-부틸, 이소-부틸 또는 프로필 등의 C3-C6의 직쇄형, 고리형 혹은 가지달린 직쇄형의 알킬기를 나타내며, R3는 C1-C3인 알킬기이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (6)
- Ziegler-Natta 형태의 중합촉매와 전자주게인 일반식(I)로 표시되는 공간장애가 큰 유기기를 가진 실란 화합물을 함유하는 올레핀의 중합용 촉매계상기식에서 R1은 트리메틸실릴메틸 흑은 치환되거나 치환되지 않은 2-페닐프로필기이고; R2는 C3-C6인 직쇄형 또는 가지달린 직쇄형의 알킬 또는 시클로알킬기를 나타내며; R3는 C1-C3인 알킬기이다.
- 제1항에 있어서, 상기 R2가 1-헥실, 시클로헥실, 시클로펜틸, 노말-부틸, 이소-부틸 및 프로필로 구성되는 군으로부터 선택되는 촉매계.
- 제1항에 있어서, 상기 촉매가 알킬알루미늄과 티타늄 할라이드로 이루어지는 촉매계.
- 제4항에 있어서, 상기 알루미늄 할라이드와 상기 실란화합물의 몰비가 1-200인 촉매계.
- 제5항에 있어서, 상기 알루미늄 할라이드와 상기 실란화합물의 몰비가 10-100인 촉매계.
- 제1항에 있어서, 상기 올레핀이 프로필렌인 촉매계.※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019940033314A KR0139089B1 (ko) | 1994-12-08 | 1994-12-08 | 올레핀의 중합반응용 촉매계 |
| US08/491,212 US5556822A (en) | 1994-08-12 | 1995-06-19 | Catalyst system for polyermization of olefin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019940033314A KR0139089B1 (ko) | 1994-12-08 | 1994-12-08 | 올레핀의 중합반응용 촉매계 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR960022584A true KR960022584A (ko) | 1996-07-18 |
| KR0139089B1 KR0139089B1 (ko) | 1998-05-01 |
Family
ID=19400733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019940033314A KR0139089B1 (ko) | 1994-08-12 | 1994-12-08 | 올레핀의 중합반응용 촉매계 |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US5556822A (ko) |
| KR (1) | KR0139089B1 (ko) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100723365B1 (ko) * | 2005-09-30 | 2007-05-30 | 삼성토탈 주식회사 | 분자 구조 중에 트리알킬실릴기를 포함하는 알콕시실란화합물을 사용하는 프로필렌 중합체 제조방법 |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5869418A (en) * | 1994-05-31 | 1999-02-09 | Borealis Holding A/S | Stereospecific catalyst system for polymerization of olefins |
| ES2162024T3 (es) * | 1995-02-13 | 2001-12-16 | Toho Titanium Co Ltd | Componente catalitico solido para la polimerizacion de olefinas y catalizador. |
| US5849655A (en) * | 1996-12-20 | 1998-12-15 | Fina Technology, Inc. | Polyolefin catalyst for polymerization of propylene and a method of making and using thereof |
| KR100236609B1 (ko) * | 1997-08-01 | 2000-02-01 | 박호군 | 클로로하이드로실란 유도체 및 이의 제조방법 |
| JP2000248015A (ja) * | 1999-02-26 | 2000-09-12 | Idemitsu Petrochem Co Ltd | オレフィン−スチレン類共重合用触媒及びオレフィン−スチレン系共重合体の製造方法 |
| US6689849B1 (en) * | 2000-04-24 | 2004-02-10 | Idemitsu Petrochemical Co., Ltd. | Catalyst for bulk polymerization, catalyst for vapor phase polymerization, method of polymerization using these, and olefin polymer obtained with these |
| PL1947123T3 (pl) * | 2005-10-31 | 2016-12-30 | Składnik katalityczny do polimeryzacji etylenu, jego wytwarzanie i katalizator zawierający go |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59117509A (ja) * | 1982-12-24 | 1984-07-06 | Mitsui Petrochem Ind Ltd | オレフインの重合方法 |
| JPH06104693B2 (ja) * | 1986-01-06 | 1994-12-21 | 東邦チタニウム株式会社 | オレフイン類重合用触媒 |
| CA1310955C (en) * | 1987-03-13 | 1992-12-01 | Mamoru Kioka | Process for polymerization of olefins and polymerization catalyst |
| US4927797A (en) * | 1987-04-09 | 1990-05-22 | Fina Technology, Inc. | Catalyst system for the polymerization of olefins |
| DE3730717A1 (de) * | 1987-09-12 | 1989-03-23 | Basf Ag | Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems |
| JP3132030B2 (ja) * | 1991-03-22 | 2001-02-05 | 東ソー株式会社 | 立体規則性ポリオレフィンの製造方法 |
| KR940010290B1 (ko) * | 1991-12-24 | 1994-10-22 | 한국과학기술연구원 | 비스실릴메탄 및 그들의 제조방법 |
| US5308818A (en) * | 1992-06-08 | 1994-05-03 | Fina Technology, Inc. | Catalyst system for the polymerization of olefins |
| US5296624A (en) * | 1992-11-25 | 1994-03-22 | Huls America, Inc. | Preparation of sterically-hindered organosilanes |
-
1994
- 1994-12-08 KR KR1019940033314A patent/KR0139089B1/ko not_active IP Right Cessation
-
1995
- 1995-06-19 US US08/491,212 patent/US5556822A/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100723365B1 (ko) * | 2005-09-30 | 2007-05-30 | 삼성토탈 주식회사 | 분자 구조 중에 트리알킬실릴기를 포함하는 알콕시실란화합물을 사용하는 프로필렌 중합체 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| US5556822A (en) | 1996-09-17 |
| KR0139089B1 (ko) | 1998-05-01 |
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