KR910011912A - 올레핀 중합용 촉매 성분과 이로부터 얻어진 촉매 - Google Patents
올레핀 중합용 촉매 성분과 이로부터 얻어진 촉매 Download PDFInfo
- Publication number
- KR910011912A KR910011912A KR1019900020927A KR900020927A KR910011912A KR 910011912 A KR910011912 A KR 910011912A KR 1019900020927 A KR1019900020927 A KR 1019900020927A KR 900020927 A KR900020927 A KR 900020927A KR 910011912 A KR910011912 A KR 910011912A
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst
- compound
- catalyst component
- olefin polymerization
- dimethoxypropane
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims 14
- 150000001336 alkenes Chemical class 0.000 title claims 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims 7
- 238000006116 polymerization reaction Methods 0.000 title claims 7
- -1 magnesium halide Chemical class 0.000 claims 11
- 150000001875 compounds Chemical class 0.000 claims 10
- 239000010936 titanium Substances 0.000 claims 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims 4
- 239000007795 chemical reaction product Substances 0.000 claims 4
- 239000011777 magnesium Substances 0.000 claims 3
- 229910052719 titanium Inorganic materials 0.000 claims 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims 2
- 125000001033 ether group Chemical group 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 229910052749 magnesium Inorganic materials 0.000 claims 2
- 235000011147 magnesium chloride Nutrition 0.000 claims 2
- 229910044991 metal oxide Inorganic materials 0.000 claims 2
- 150000004706 metal oxides Chemical class 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- 238000006467 substitution reaction Methods 0.000 claims 2
- MEPSBRTXOHFWCF-UHFFFAOYSA-N (2-cyclohexyl-1,3-dimethoxypropan-2-yl)cyclohexane Chemical compound C1CCCCC1C(COC)(COC)C1CCCCC1 MEPSBRTXOHFWCF-UHFFFAOYSA-N 0.000 claims 1
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 claims 1
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 claims 1
- DNZXTVCIOVBBGV-UHFFFAOYSA-N 5,5-bis(methoxymethyl)-2,8-dimethylnonane Chemical compound CC(C)CCC(COC)(CCC(C)C)COC DNZXTVCIOVBBGV-UHFFFAOYSA-N 0.000 claims 1
- IQERUFYGVPQBMO-UHFFFAOYSA-N C(CC)C(CCOC)OC Chemical compound C(CC)C(CCOC)OC IQERUFYGVPQBMO-UHFFFAOYSA-N 0.000 claims 1
- 125000002877 alkyl aryl group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 125000003710 aryl alkyl group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 125000005982 diphenylmethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])(*)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 125000003854 p-chlorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1Cl 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical group Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 이할로겐화 마그네슘 및 할로겐화 티타늄 또는 티타늄 할로겐 알콜레이트, 및 두개 이상의 에트르기를 함유하는 전자-공여 화합물이 담지된 다공성 산화물을 포함하는 올레핀 중합용 촉매 성분에서, 전자-공여 화합물이 MgCl2100g 당 60 밀리몰이하의 양으로 무수 이염화마그네슘과 착물화될 수 있으며 TiCl4와 미반응되어 치환반응을 일으키거나, 치환 방식으로 50몰 % 미만에 대하여 반응을 일으킬수 있음을 특징으로 하는 올레핀 중합용 촉매성분.
- 제1항에 있어서, 할로겐화 티타늄이 사염화 티타늄이고, 이할로겐화 마그네슘이 이염화마그네슘이며, Mg/Ti 몰비가 0.5:1 내지 10:1 이고, Ti/전자-공여 화합물 몰비가 0.5:1 내지 3:1 이며, 금속 산화물이 성분의 총중량에 대하여 40중량 이상의 양으로 존재하는 촉매성분.
- 제1항에 있어서 금속 산화물이 실리카, 알루미나, 및 이의 혼합물로 이루어진 군으로부터 선택된 촉매 성분.
- 제1항에 있어서 에테르기를 함유하는 화합물이 다음 일반식의 화합물로부터 선택되는 촉매 성분.상기식에서, R, R1및 R2는 서로 같거나 다르며, C1~C18알킬, C3~C18시클로알킬, C6~C18아릴 C7~C18아르알킬 또는 알킬아릴기이고, R1및 R2는 수소원자일 수도 있다.
- 제4항에 있어서, R이 메틸이고, R1및 R2가 서로 같거나 다르며, 메틸, 에틸, 프로필, 부틸 이소부틸, t-부틸 이소-펜틸, 2-에틸헥실, 시클로헥실, 메틸시클로헥실, 페닐, 및 베질중에서 선택되며, R1이 수소이면, R2는 에틸, 부틸, sec-부틸, t-부틸, 2-에틸헥실, 시클로헥실, 디페닐메틸, p-클로로페닐, 1-나프릴, 1-데카히드로나프틸인 촉매 성분.
- 제4항에 있어서, 에테르기를 함유하는 화합물이 2,2-디이소부틸-1,3-디메톡시프로판, 2-이소프로필-2-이소펜틸-1,3-디메톡시프로판, 2,2-n-프로필-1,3-디메톡시프로판, 2,2-디이소펜틸-1,3-디메톡시프로판, 2,2-디시클로헥실-1,3-디메톡시프로판중에서 선택된 촉매 성분.
- 제1항의 촉매 성분과 Al-알킬 화합물의 반응 생성물을 포함하는 올레핀 중합용 촉매.
- 제3항의 촉매성분과 Al-알킬 화합물의 반응 생성물을 포함하는 올레핀 중합용 촉매.
- 제5항의 촉매 성분과 Al-트리알킬 화합물의 반응 생성물을 포함하는 올레핀 중합용 촉매.
- 제6항의 촉매 성분과 Al-트리알킬 화합물의 반응 생성물을 포함하는 올레핀 중합용 촉매.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT22826A/89 | 1989-12-22 | ||
| IT02282689A IT1237812B (it) | 1989-12-22 | 1989-12-22 | Componenti e catalizzatori per la polimerizzazione di olefine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR910011912A true KR910011912A (ko) | 1991-08-07 |
| KR0162493B1 KR0162493B1 (ko) | 1999-01-15 |
Family
ID=11200891
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019900020927A KR0162493B1 (ko) | 1989-12-22 | 1990-12-18 | 올레핀 중합용 촉매성분 및 이로부터 얻어진 촉매 |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US5122492A (ko) |
| EP (1) | EP0434082B1 (ko) |
| JP (1) | JP2974789B2 (ko) |
| KR (1) | KR0162493B1 (ko) |
| CN (1) | CN1022326C (ko) |
| AT (1) | ATE129505T1 (ko) |
| AU (1) | AU629434B2 (ko) |
| BR (1) | BR9006523A (ko) |
| CA (1) | CA2032424A1 (ko) |
| DE (1) | DE69023213T2 (ko) |
| DK (1) | DK0434082T3 (ko) |
| ES (1) | ES2080782T3 (ko) |
| FI (1) | FI99242C (ko) |
| HU (1) | HU219764B (ko) |
| IL (1) | IL96532A (ko) |
| IT (1) | IT1237812B (ko) |
| MX (1) | MX23881A (ko) |
| NO (1) | NO176053C (ko) |
| PL (1) | PL288412A1 (ko) |
| PT (1) | PT96329B (ko) |
| RO (1) | RO107123B1 (ko) |
| RU (1) | RU2032689C1 (ko) |
| SK (1) | SK279546B6 (ko) |
| YU (1) | YU242190A (ko) |
| ZA (1) | ZA909818B (ko) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1227258B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| US5726262A (en) * | 1990-04-13 | 1998-03-10 | Mitsui Petrochemical Industries, Ltd. | Solid titanium catalyst component for olefin polymerization, olefin polymerization catalyst, prepolymerized polyolefin-containing catalyst and method of olefin polymerization |
| IT1245249B (it) * | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1245250B (it) * | 1991-03-27 | 1994-09-13 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
| IT1264679B1 (it) | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori per la (co)polimerizzazione di etilene |
| DE69502312T2 (de) * | 1994-02-18 | 1998-10-08 | Mitsui Chemicals Inc | Ethylenpolymer und Verfahren zur Herstellung desselben |
| AU2199695A (en) * | 1994-03-31 | 1995-10-23 | Exxon Chemical Patents Inc. | Supported lewis acid catalysts for hydrocarbon conversion reactions |
| US7049377B1 (en) * | 1995-02-21 | 2006-05-23 | Basell Poliolefine Italia S.R.L. | 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers |
| IL117114A (en) * | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
| IT1274253B (it) * | 1995-02-21 | 1997-07-15 | Himont Inc | Processo per la preparazione di componenti catalitici solidi per la polimerizzazione di olefine |
| JP3895050B2 (ja) * | 1997-08-11 | 2007-03-22 | 三井化学株式会社 | 固体状チタン触媒成分の調製方法 |
| FR2812642B1 (fr) * | 2000-08-03 | 2003-08-01 | Atofina | Procede de preparation d'un support de catalyseur pour la poymerisation de l'ethylene et des alpha-olefines, le support ainsi obtenu et le catalyseur correspondant |
| CN1169845C (zh) * | 2002-02-07 | 2004-10-06 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用 |
| WO2003106511A1 (en) * | 2002-06-13 | 2003-12-24 | Basell Poliolefine Italia S.P.A. | Catalyst components for the polymerization of olefins |
| CN1659190A (zh) * | 2002-06-13 | 2005-08-24 | 巴塞尔聚烯烃意大利有限公司 | 乙烯共聚物的制备方法 |
| EP3020738B1 (en) | 2002-08-19 | 2018-03-21 | Toho Titanium Co., Ltd. | Catalyst and catalyst component thereof |
| US7491456B2 (en) | 2003-03-28 | 2009-02-17 | Kyocera Corporation | Fuel cell assembly and electricity generation unit used in same |
| JP2008533226A (ja) * | 2005-03-11 | 2008-08-21 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン類の重合触媒成分 |
| WO2008061662A1 (en) * | 2006-11-21 | 2008-05-29 | Basell Poliolefine Italia S.R.L. | Catalyst component for the polymerization of olefins |
| KR101206940B1 (ko) * | 2007-10-16 | 2012-11-30 | 시노펙 양지 페트로케미컬 컴퍼니 엘티디. | 마그네슘 화합물 상에 담지된 비-메탈로센 촉매 및 이의 제조방법 |
| US8193288B2 (en) * | 2007-10-16 | 2012-06-05 | Sinopec Yangzi Petro-Chemical Ltd. | Supported nonmetallocene catalyst and preparation thereof |
| US20140038809A1 (en) * | 2011-12-22 | 2014-02-06 | Petroleo Brasileiro S.A. - Petrobras | Catalyst supported on alumina for use in polymerization of olefins and method of preparing them |
| US9481741B2 (en) * | 2012-11-26 | 2016-11-01 | Lummus Novolen Technology Gmbh | High performance Ziegler-Natta catalyst systems, process for producing such supported catalysts and use thereof |
| CN104926967B (zh) * | 2015-03-19 | 2018-11-27 | 青岛科技大学 | 一种以硅胶微球/氯化镁为载体的烯烃聚合催化剂及其制备方法和应用 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL113050C (ko) * | 1958-09-17 | |||
| IT1190683B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
| CA1329801C (en) * | 1987-09-21 | 1994-05-24 | Charles K. Buehler | Modified silica based catalyst |
| DE3815486A1 (de) * | 1988-05-06 | 1989-11-16 | Basf Ag | Katalysator fuer die polymerisation von ethylen, verfahren zu dessen herstellung und verwendung der erhaltenen ethylenpolymerisate zur herstellung von folien mit geringen blockeigenschaften |
| IT1227258B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
-
1989
- 1989-12-22 IT IT02282689A patent/IT1237812B/it active IP Right Grant
-
1990
- 1990-12-04 IL IL9653290A patent/IL96532A/en not_active IP Right Cessation
- 1990-12-06 ZA ZA909818A patent/ZA909818B/xx unknown
- 1990-12-06 AU AU67855/90A patent/AU629434B2/en not_active Ceased
- 1990-12-14 US US07/628,526 patent/US5122492A/en not_active Expired - Lifetime
- 1990-12-17 CA CA002032424A patent/CA2032424A1/en not_active Abandoned
- 1990-12-18 KR KR1019900020927A patent/KR0162493B1/ko not_active IP Right Cessation
- 1990-12-19 FI FI906274A patent/FI99242C/fi active IP Right Grant
- 1990-12-20 RO RO146614A patent/RO107123B1/ro unknown
- 1990-12-20 BR BR909006523A patent/BR9006523A/pt not_active IP Right Cessation
- 1990-12-20 NO NO905513A patent/NO176053C/no not_active IP Right Cessation
- 1990-12-21 ES ES90125079T patent/ES2080782T3/es not_active Expired - Lifetime
- 1990-12-21 PT PT96329A patent/PT96329B/pt not_active IP Right Cessation
- 1990-12-21 EP EP90125079A patent/EP0434082B1/en not_active Expired - Lifetime
- 1990-12-21 PL PL28841290A patent/PL288412A1/xx unknown
- 1990-12-21 YU YU242190A patent/YU242190A/sh unknown
- 1990-12-21 RU SU4894075/04A patent/RU2032689C1/ru not_active IP Right Cessation
- 1990-12-21 DE DE69023213T patent/DE69023213T2/de not_active Expired - Fee Related
- 1990-12-21 AT AT90125079T patent/ATE129505T1/de not_active IP Right Cessation
- 1990-12-21 SK SK6588-90A patent/SK279546B6/sk unknown
- 1990-12-21 CN CN90106028A patent/CN1022326C/zh not_active Expired - Fee Related
- 1990-12-21 MX MX2388190A patent/MX23881A/es unknown
- 1990-12-21 HU HU419/90A patent/HU219764B/hu unknown
- 1990-12-21 DK DK90125079.5T patent/DK0434082T3/da active
- 1990-12-25 JP JP2413654A patent/JP2974789B2/ja not_active Expired - Fee Related
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