IT1255523B - Componenti e catalizzatori per la polimerizzazione di olefine - Google Patents
Componenti e catalizzatori per la polimerizzazione di olefineInfo
- Publication number
- IT1255523B IT1255523B ITMI922197A ITMI922197A IT1255523B IT 1255523 B IT1255523 B IT 1255523B IT MI922197 A ITMI922197 A IT MI922197A IT MI922197 A ITMI922197 A IT MI922197A IT 1255523 B IT1255523 B IT 1255523B
- Authority
- IT
- Italy
- Prior art keywords
- radicals
- formula
- components
- polymerization
- compound
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 4
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- -1 magnesium halide Chemical class 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 239000011777 magnesium Substances 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 239000010936 titanium Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/09—Diamines
- C07C211/11—Diaminopropanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/25—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing rings other than six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/26—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing at least one six-membered aromatic ring
- C07C211/27—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an unsaturated carbon skeleton containing at least one six-membered aromatic ring having amino groups linked to the six-membered aromatic ring by saturated carbon chains
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
Abstract
Componenti di catalizzatori per la polimerizzazione di olefine, comprendenti un alogenuro di magnesio in forma attiva, e supportati sullo stesso, un alogenuro o alogeno alcolato di titanio e un composto elettron-donatore scelto tra le ammine di formula (FORMULA I) in cui i radicali da R1 a R10, uguali o differenti, sono idrogeno o radicali idrocarburici C1-C18, a condizione che almeno uno dei radicali R7 e R8 e almeno uno dei radicali R9 e R10 non siano idrogeno.Catalizzatori ottenuti da detti componenti catalitici e da un composto Al-alchilico e inoltre catalizzatori ottenuti per reazione di un composto Al-alchilico e un'ammina di formula (1) con un componente catalitico solido comprendente un alogenuro o alogeno alcolato di titanio e un composto elettron-donatore avente particolari caratteristiche di estraibilità con Al-trietile, supportati su un alogenuro di magnesio in forma attiva.
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI922197A IT1255523B (it) | 1992-09-24 | 1992-09-24 | Componenti e catalizzatori per la polimerizzazione di olefine |
FI934152A FI111082B (fi) | 1992-09-24 | 1993-09-22 | Komponentteja ja katalyyttejä olefiinien polymerointia varten |
CA002106835A CA2106835C (en) | 1992-09-24 | 1993-09-23 | Components and catalysts for the polymerization of olefins |
KR1019930019497A KR100293575B1 (ko) | 1992-09-24 | 1993-09-23 | 올레핀중합용촉매성분및촉매 |
DK93115444.7T DK0589474T3 (da) | 1992-09-24 | 1993-09-24 | Bestanddele og katalysatorer til polymerisation af olefiner |
JP26168693A JP3429819B2 (ja) | 1992-09-24 | 1993-09-24 | オレフィン重合用触媒成分および触媒 |
DE69310300T DE69310300T2 (de) | 1992-09-24 | 1993-09-24 | Katalysatorbestandteile und Katalysatore für Olefinpolymerisation |
AT93115444T ATE152456T1 (de) | 1992-09-24 | 1993-09-24 | Katalysatorbestandteile und katalysatore für olefinpolymerisation |
CN93119343A CN1032310C (zh) | 1992-09-24 | 1993-09-24 | 烯烃聚合催化组分及催化剂 |
EP93115444A EP0589474B1 (en) | 1992-09-24 | 1993-09-24 | Components and catalysts for the polymerization of olefins |
US08/391,327 US5552359A (en) | 1992-09-24 | 1995-02-21 | Components and catalyst for the polymerization of olefins |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI922197A IT1255523B (it) | 1992-09-24 | 1992-09-24 | Componenti e catalizzatori per la polimerizzazione di olefine |
Publications (3)
Publication Number | Publication Date |
---|---|
ITMI922197A0 ITMI922197A0 (it) | 1992-09-24 |
ITMI922197A1 ITMI922197A1 (it) | 1994-03-24 |
IT1255523B true IT1255523B (it) | 1995-11-09 |
Family
ID=11363995
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ITMI922197A IT1255523B (it) | 1992-09-24 | 1992-09-24 | Componenti e catalizzatori per la polimerizzazione di olefine |
Country Status (11)
Country | Link |
---|---|
US (1) | US5552359A (it) |
EP (1) | EP0589474B1 (it) |
JP (1) | JP3429819B2 (it) |
KR (1) | KR100293575B1 (it) |
CN (1) | CN1032310C (it) |
AT (1) | ATE152456T1 (it) |
CA (1) | CA2106835C (it) |
DE (1) | DE69310300T2 (it) |
DK (1) | DK0589474T3 (it) |
FI (1) | FI111082B (it) |
IT (1) | IT1255523B (it) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5500396A (en) * | 1995-02-09 | 1996-03-19 | Phillips Petroleum Company | Process to make small, discrete, spherical adducts |
US6436864B1 (en) * | 1999-10-06 | 2002-08-20 | Sri International | Unsaturated nitrogenous compounds as electron donors for use with ziegler-natta catalysts |
JP2005524742A (ja) * | 2002-05-06 | 2005-08-18 | ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション | ポリオレフィンを製造するための混合触媒組成物 |
CN1314714C (zh) | 2002-09-11 | 2007-05-09 | 日本聚丙烯公司 | 聚合α-烯烃的催化剂和使用其制备α-烯烃聚合物的方法 |
CN1318457C (zh) * | 2004-09-02 | 2007-05-30 | 中国石油化工股份有限公司<Del/> | 用于烯烃聚合反应的催化剂组分和催化剂 |
US8288606B2 (en) * | 2005-03-08 | 2012-10-16 | Ineos Usa Llc | Propylene polymer catalyst donor component |
JP4905938B2 (ja) * | 2006-08-29 | 2012-03-28 | 東邦チタニウム株式会社 | オレフィン類重合用触媒及びこれを用いたオレフィン類重合体の製造方法 |
CN101735346B (zh) | 2008-11-07 | 2012-05-30 | 中国石油天然气股份有限公司 | 一种丙烯均聚和共聚的催化剂及其制备方法和应用 |
KR20190038812A (ko) * | 2016-06-30 | 2019-04-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 낮은 공 단량체 도입용 전촉매 조성물 및 이의 제조 공정 |
EP3339333B1 (en) * | 2016-12-22 | 2020-10-07 | Borealis AG | Ziegler-natta catalyst and preparation thereof |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL258909A (it) * | 1958-09-17 | |||
YU35844B (en) * | 1968-11-25 | 1981-08-31 | Montedison Spa | Process for obtaining catalysts for the polymerization of olefines |
NL162664B (nl) * | 1969-06-20 | 1980-01-15 | Montedison Spa | Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1. |
LU61374A1 (it) * | 1970-07-20 | 1972-04-04 | ||
US4107414A (en) * | 1971-06-25 | 1978-08-15 | Montecatini Edison S.P.A. | Process for the stereoregular polymerization of alpha olefins |
US4186107A (en) * | 1978-04-14 | 1980-01-29 | Hercules Incorporated | Solid catalyst component for olefin polymerization |
GB2054616B (en) * | 1979-07-09 | 1983-03-02 | El Paso Polyolefins | Propylene polymerization process and product |
GB2054618B (en) * | 1979-07-24 | 1984-02-08 | Mitsui Toatsu Chemicals | Thermosetting resin composition |
EP0029623B1 (en) * | 1979-11-20 | 1984-06-13 | Shell Internationale Researchmaatschappij B.V. | Preparation of catalyst components and polymerization of olefins employing such catalyst components |
US4277372A (en) * | 1980-01-09 | 1981-07-07 | Hercules Incorporated | Solid catalyst component for olefin polymerization |
US4487845A (en) * | 1980-05-09 | 1984-12-11 | Stauffer Chemical Company | Method of enhancing stereospecificity of a catalyst system |
IT1209255B (it) * | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
EP0072129B2 (en) * | 1981-08-07 | 1990-02-28 | Imperial Chemical Industries Plc | Supported transition metal composition |
IT1190682B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine |
JPS58138705A (ja) * | 1982-02-12 | 1983-08-17 | Mitsui Petrochem Ind Ltd | オレフイン系重合体の製造方法 |
IT1190683B (it) * | 1982-02-12 | 1988-02-24 | Montedison Spa | Componenti e catalizzatori per la polimerizzazione di olefine |
US4532313A (en) * | 1982-10-13 | 1985-07-30 | Himont Incorporated | Method for preparing an improved catalyst support, Ziegler-Natta catalyst utilizing said support and polymerization of 1-olefins utilizing said catalyst |
US4506029A (en) * | 1982-12-20 | 1985-03-19 | Stauffer Chemical Company | Supported catalyst for polymerization of olefins |
US5196138A (en) * | 1989-06-30 | 1993-03-23 | Cyprus Foote Mineral Company | Preparation of mixed lithium amide reagents |
IT1241093B (it) * | 1990-03-30 | 1993-12-29 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
US5182346A (en) * | 1990-08-02 | 1993-01-26 | Borden, Inc. | Accelerators for curing phenolic resole resins |
-
1992
- 1992-09-24 IT ITMI922197A patent/IT1255523B/it active IP Right Grant
-
1993
- 1993-09-22 FI FI934152A patent/FI111082B/fi active
- 1993-09-23 KR KR1019930019497A patent/KR100293575B1/ko not_active IP Right Cessation
- 1993-09-23 CA CA002106835A patent/CA2106835C/en not_active Expired - Fee Related
- 1993-09-24 JP JP26168693A patent/JP3429819B2/ja not_active Expired - Fee Related
- 1993-09-24 CN CN93119343A patent/CN1032310C/zh not_active Expired - Fee Related
- 1993-09-24 DK DK93115444.7T patent/DK0589474T3/da active
- 1993-09-24 EP EP93115444A patent/EP0589474B1/en not_active Expired - Lifetime
- 1993-09-24 DE DE69310300T patent/DE69310300T2/de not_active Expired - Fee Related
- 1993-09-24 AT AT93115444T patent/ATE152456T1/de not_active IP Right Cessation
-
1995
- 1995-02-21 US US08/391,327 patent/US5552359A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JP3429819B2 (ja) | 2003-07-28 |
FI934152A (fi) | 1994-03-25 |
US5552359A (en) | 1996-09-03 |
KR940007061A (ko) | 1994-04-26 |
FI934152A0 (fi) | 1993-09-22 |
FI111082B (fi) | 2003-05-30 |
KR100293575B1 (ko) | 2001-09-17 |
EP0589474B1 (en) | 1997-05-02 |
EP0589474A3 (en) | 1994-10-19 |
ATE152456T1 (de) | 1997-05-15 |
CA2106835C (en) | 1999-02-02 |
ITMI922197A0 (it) | 1992-09-24 |
DE69310300D1 (de) | 1997-06-05 |
EP0589474A2 (en) | 1994-03-30 |
DE69310300T2 (de) | 1997-12-18 |
DK0589474T3 (da) | 1997-12-22 |
CN1087918A (zh) | 1994-06-15 |
CN1032310C (zh) | 1996-07-17 |
JPH06263816A (ja) | 1994-09-20 |
CA2106835A1 (en) | 1994-03-25 |
ITMI922197A1 (it) | 1994-03-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
0001 | Granted | ||
TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19970923 |