IT1252205B - Processo per la preparazione di poliolefine stabilizzate e prodotti cosi` ottenuti. - Google Patents
Processo per la preparazione di poliolefine stabilizzate e prodotti cosi` ottenuti.Info
- Publication number
- IT1252205B IT1252205B ITMI913346A ITMI913346A IT1252205B IT 1252205 B IT1252205 B IT 1252205B IT MI913346 A ITMI913346 A IT MI913346A IT MI913346 A ITMI913346 A IT MI913346A IT 1252205 B IT1252205 B IT 1252205B
- Authority
- IT
- Italy
- Prior art keywords
- compound
- electron
- donor
- products
- preparation
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 229920000098 polyolefin Polymers 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- -1 alkyl aluminum compound Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 229910001629 magnesium chloride Inorganic materials 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Laminated Bodies (AREA)
- Fluid-Damping Devices (AREA)
Abstract
Si ottengono poliolefine stabilizzate contro i fenomeni di ossidazione, impiegando un processo comprendente la polimerizzazione dei monomeri mediante un catalizzatore preparato per reazione di un composto alchilico di alluminio ed eventualmente un composto elettron-donatore con un componente solido comprendente un composto di Ti e un composto elettron-donatore supportati su cloruro di magnesio, detta polimerizzazione essendo condotta in presenza di uno o più stabilizzanti fenolici e impiegando, come composto elettron-donatore nel componente catalitico solido, un composto scelto tra particolari classi di eteri.
Priority Applications (16)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI913346A IT1252205B (it) | 1991-12-13 | 1991-12-13 | Processo per la preparazione di poliolefine stabilizzate e prodotti cosi` ottenuti. |
AU30013/92A AU657379B2 (en) | 1991-12-13 | 1992-12-09 | Process for the preparation of stabilized polyolefins and products obtained therefrom |
TW081109885A TW239151B (it) | 1991-12-13 | 1992-12-10 | |
BR9204981A BR9204981A (pt) | 1991-12-13 | 1992-12-10 | Processo para a preparacao de poliolefinas estabilizadas e polimero de olefina na forma de particulas nao extrusadas |
US07/988,646 US5278210A (en) | 1991-12-13 | 1992-12-10 | Process for the preparation of stabilized polyolefins and products obtained therefrom |
EP92121170A EP0546573B1 (en) | 1991-12-13 | 1992-12-11 | Process for the preparation of stabilized polyolefins and products obtained therefrom |
DE69224711T DE69224711T2 (de) | 1991-12-13 | 1992-12-11 | Verfahren zur Herstellung stabilisierter Polyolefine und daraus hergestellte Produkte |
ES92121170T ES2114905T3 (es) | 1991-12-13 | 1992-12-11 | Procedimiento para la preparacion de poliolefinas estabilizadas y productos obtenidos. |
CA002085194A CA2085194A1 (en) | 1991-12-13 | 1992-12-11 | Process for the preparation of stabilized polyolefins and products obtained therefrom |
AT92121170T ATE163944T1 (de) | 1991-12-13 | 1992-12-11 | Verfahren zur herstellung stabilisierter polyolefine und daraus hergestellte produkte |
RU9292004528A RU2070206C1 (ru) | 1991-12-13 | 1992-12-11 | Способ получения стабилизированного полипропилена |
FI925637A FI105819B (fi) | 1991-12-13 | 1992-12-11 | Menetelmä stabiloitujen polyolefiinien valmistamiseksi ja näistä saatuja tuotteita |
NO924795A NO301123B1 (no) | 1991-12-13 | 1992-12-11 | Fremgangsmåte for fremstilling av stabiliserte polyolefiner |
KR1019920024092A KR100258489B1 (ko) | 1991-12-13 | 1992-12-12 | 안정화 올레핀의 제조방법 및 이로 부터 수득된 생성물 |
CN92115246.9A CN1035385C (zh) | 1991-12-13 | 1992-12-12 | 制备稳定的聚烯烃的方法 |
JP35348092A JP3311405B2 (ja) | 1991-12-13 | 1992-12-14 | 安定化したポリオレフィンの製造方法およびそれにより得られる生成物 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI913346A IT1252205B (it) | 1991-12-13 | 1991-12-13 | Processo per la preparazione di poliolefine stabilizzate e prodotti cosi` ottenuti. |
Publications (3)
Publication Number | Publication Date |
---|---|
ITMI913346A0 ITMI913346A0 (it) | 1991-12-13 |
ITMI913346A1 ITMI913346A1 (it) | 1993-06-13 |
IT1252205B true IT1252205B (it) | 1995-06-05 |
Family
ID=11361329
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ITMI913346A IT1252205B (it) | 1991-12-13 | 1991-12-13 | Processo per la preparazione di poliolefine stabilizzate e prodotti cosi` ottenuti. |
Country Status (16)
Country | Link |
---|---|
US (1) | US5278210A (it) |
EP (1) | EP0546573B1 (it) |
JP (1) | JP3311405B2 (it) |
KR (1) | KR100258489B1 (it) |
CN (1) | CN1035385C (it) |
AT (1) | ATE163944T1 (it) |
AU (1) | AU657379B2 (it) |
BR (1) | BR9204981A (it) |
CA (1) | CA2085194A1 (it) |
DE (1) | DE69224711T2 (it) |
ES (1) | ES2114905T3 (it) |
FI (1) | FI105819B (it) |
IT (1) | IT1252205B (it) |
NO (1) | NO301123B1 (it) |
RU (1) | RU2070206C1 (it) |
TW (1) | TW239151B (it) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1255233B (it) * | 1992-07-17 | 1995-10-20 | Himont Inc | Procedimento per la stabilizzazione di polimeri olefinici |
IT1264679B1 (it) * | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori per la (co)polimerizzazione di etilene |
US6207737B1 (en) | 1994-03-14 | 2001-03-27 | Ppg Industries Ohio, Inc. | Glass fiber sizing, sized glass fibers and polyolefin reinforced articles |
CN1068338C (zh) * | 1994-08-29 | 2001-07-11 | 中国石化扬子石油化工公司 | 一种α-烯烃的聚合方法 |
WO1998009995A1 (en) * | 1996-09-04 | 1998-03-12 | The Dow Chemical Company | Incorporation of free radical inhibitors in polyolefins |
US5948720A (en) * | 1997-01-07 | 1999-09-07 | Huntsman Polymers Corporation | Catalyst for the production of flexible polyolefin compositions, methods for making and using same, and products thereof |
US6777470B2 (en) * | 2001-05-29 | 2004-08-17 | Sunoco, Inc. (R&M) | Polyolefin additive packages for producing articles with enhanced stain resistance |
WO2003106511A1 (en) * | 2002-06-13 | 2003-12-24 | Basell Poliolefine Italia S.P.A. | Catalyst components for the polymerization of olefins |
JP4969070B2 (ja) | 2005-03-11 | 2012-07-04 | 株式会社Adeka | 安定化されたポリマーの製造方法 |
KR101787927B1 (ko) * | 2007-12-21 | 2017-10-18 | 더블유.알. 그레이스 앤드 캄파니-콘. | 두자리 내부 공여체를 가진 자기-제한성 촉매 조성물 |
US20110065876A1 (en) * | 2008-06-05 | 2011-03-17 | Adeka Corporation | Aluminum phenoxide compound and process for producing stabilized polymer by using the same |
WO2010024841A1 (en) | 2008-08-25 | 2010-03-04 | Dupont Electronic Polymers L.P. | New propanoates and processes for preparing the same |
DE102009023651B4 (de) * | 2009-05-26 | 2021-07-01 | Aesculap Ag | Verfahren zur Herstellung eines mit einem Stabilisator dotierten Polyethylens und Verwendung eines nach diesem Verfahren hergestellten Polyethylens |
WO2011027793A1 (ja) | 2009-09-04 | 2011-03-10 | 株式会社Adeka | フェノール系酸化防止剤の再生方法、オレフィン重合体の製造方法、ポリオレフィンパウダー、及び繊維 |
JP5710186B2 (ja) | 2010-09-10 | 2015-04-30 | 株式会社Adeka | 安定化ポリマーの製造方法 |
US20130237114A1 (en) | 2010-11-16 | 2013-09-12 | Adeka Corporation | Method for stabilizing polymer for long term, method for producing nonwoven fabric, and method for producing elastomer composition |
BR112016008951B1 (pt) | 2013-10-21 | 2021-11-03 | Adeka Corporation | Método para produção de polímero estabilizado |
JP6909594B2 (ja) | 2017-03-03 | 2021-07-28 | 株式会社Adeka | 安定化されたオレフィン系樹脂組成物の製造方法 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3477991A (en) * | 1968-06-05 | 1969-11-11 | Exxon Research Engineering Co | Alkenyl hindered phenol and a copolymer of an alkenyl phenol and a monoolefin |
IT1096661B (it) * | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
DE2841645A1 (de) * | 1978-09-25 | 1980-04-03 | Basf Ag | Verfahren zum herstellen von homo- und copolymerisaten von alpha -monoolefinen |
IT1207491B (it) * | 1985-01-30 | 1989-05-25 | Himont Inc | Procedimento per preparare polimeri olefinici, termicamente stabili. |
US4960593A (en) * | 1985-01-30 | 1990-10-02 | Hilmont Incorporated | Process for preparing thermally stable olefinic polymers |
GB2183244B (en) * | 1985-11-26 | 1989-11-15 | Toho Titanium Co Ltd | Olefin-polymerization catalysts and component therefor |
IT1213312B (it) * | 1986-07-30 | 1989-12-20 | Enichem Sintesi | Procedimento di (co)polimerizzazioni di alfa olefine in presenta di stabilizzanti. |
IT1196980B (it) * | 1986-07-23 | 1988-11-25 | Enichem Sintesi | Procedimento di (co)polimerizzazione di alfa-olefine in presenza di antiossidanti |
IT1197320B (it) * | 1986-10-02 | 1988-11-30 | Ausimont Spa | Catalizzatori per la preparazione di copolimeri olefinici elastomerici,saturi ed insaturi,e vopolimeri con essi ottenuti |
US4818799A (en) * | 1987-11-13 | 1989-04-04 | Shell Oil Company | Process for the in-reactor stabilization of polyolefins |
US4879141A (en) * | 1988-01-25 | 1989-11-07 | Shell Oil Company | In-reactor stabilization of polyolefins via coated stabilizers |
US5045577A (en) * | 1988-06-30 | 1991-09-03 | Ciba-Geigy Corporation | Process for the preparation of heat-stable olefin polymers |
EP0350444A1 (de) * | 1988-06-30 | 1990-01-10 | Ciba-Geigy Ag | Verfahren zum Stabilisieren von Polyolefinen |
IT1227258B (it) * | 1988-09-30 | 1991-03-28 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
US5064878A (en) * | 1989-07-05 | 1991-11-12 | Shell Oil Company | In-reactor stabilization of polymers via coated stabilizers |
WO1991002758A1 (en) * | 1989-08-18 | 1991-03-07 | Tonen Corporation | CATALYTIC COMPONENT FOR α-OLEFIN POLYMERIZATION |
IT1241062B (it) * | 1990-01-10 | 1993-12-29 | Himont Inc | Componenti e catalizzatori per la polimerizzazione di olefine |
-
1991
- 1991-12-13 IT ITMI913346A patent/IT1252205B/it active IP Right Grant
-
1992
- 1992-12-09 AU AU30013/92A patent/AU657379B2/en not_active Ceased
- 1992-12-10 BR BR9204981A patent/BR9204981A/pt not_active Application Discontinuation
- 1992-12-10 US US07/988,646 patent/US5278210A/en not_active Expired - Lifetime
- 1992-12-10 TW TW081109885A patent/TW239151B/zh active
- 1992-12-11 ES ES92121170T patent/ES2114905T3/es not_active Expired - Lifetime
- 1992-12-11 FI FI925637A patent/FI105819B/fi active
- 1992-12-11 DE DE69224711T patent/DE69224711T2/de not_active Expired - Fee Related
- 1992-12-11 EP EP92121170A patent/EP0546573B1/en not_active Expired - Lifetime
- 1992-12-11 AT AT92121170T patent/ATE163944T1/de not_active IP Right Cessation
- 1992-12-11 CA CA002085194A patent/CA2085194A1/en not_active Abandoned
- 1992-12-11 NO NO924795A patent/NO301123B1/no not_active IP Right Cessation
- 1992-12-11 RU RU9292004528A patent/RU2070206C1/ru active
- 1992-12-12 CN CN92115246.9A patent/CN1035385C/zh not_active Expired - Fee Related
- 1992-12-12 KR KR1019920024092A patent/KR100258489B1/ko not_active IP Right Cessation
- 1992-12-14 JP JP35348092A patent/JP3311405B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
TW239151B (it) | 1995-01-21 |
FI925637A0 (fi) | 1992-12-11 |
DE69224711T2 (de) | 1998-09-24 |
FI105819B (fi) | 2000-10-13 |
FI925637A (fi) | 1993-06-14 |
NO301123B1 (no) | 1997-09-15 |
CN1074222A (zh) | 1993-07-14 |
JPH05271335A (ja) | 1993-10-19 |
AU3001392A (en) | 1993-06-17 |
BR9204981A (pt) | 1993-06-15 |
ATE163944T1 (de) | 1998-03-15 |
NO924795D0 (no) | 1992-12-11 |
CN1035385C (zh) | 1997-07-09 |
EP0546573B1 (en) | 1998-03-11 |
KR100258489B1 (ko) | 2000-06-15 |
EP0546573A1 (en) | 1993-06-16 |
ITMI913346A0 (it) | 1991-12-13 |
ES2114905T3 (es) | 1998-06-16 |
CA2085194A1 (en) | 1993-06-14 |
ITMI913346A1 (it) | 1993-06-13 |
AU657379B2 (en) | 1995-03-09 |
NO924795L (no) | 1993-06-14 |
DE69224711D1 (de) | 1998-04-16 |
US5278210A (en) | 1994-01-11 |
RU2070206C1 (ru) | 1996-12-10 |
JP3311405B2 (ja) | 2002-08-05 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
0001 | Granted | ||
TA | Fee payment date (situation as of event date), data collected since 19931001 |
Effective date: 19971217 |