KR940005767A - 플루오로엘라스토머 도포용 조성물 - Google Patents

플루오로엘라스토머 도포용 조성물 Download PDF

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KR940005767A
KR940005767A KR1019930009699A KR930009699A KR940005767A KR 940005767 A KR940005767 A KR 940005767A KR 1019930009699 A KR1019930009699 A KR 1019930009699A KR 930009699 A KR930009699 A KR 930009699A KR 940005767 A KR940005767 A KR 940005767A
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chloride
group
groups
bromide
composition
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KR1019930009699A
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다쯔오 후꾸시
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게리 엘. 그리스울드
미네소타 마이닝 앤드 매뉴팩츄어링 캄파니
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Publication of KR940005767A publication Critical patent/KR940005767A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025—Crosslinking or vulcanising agents; including accelerators
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers

Abstract

본 발명은 예를들어, 자동차 가스켓의 제조에 유용한, 하기 성분들을 포함하는 도표용 조성물에 관한 것이다 : (1) 플루오로엘라스토머; (2) 4급 암모늄 또는 4급 포스포늄 염 촉진제; (3) 폴리올: (4) 산수용체: (5) 유용성 킬레이트화제: 및(6) 유기 용매

Description

플루오로엘라스토머 도포용 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 유용성 킬레이트화제를 함유하는 본 발명의 조성물 (실시예 1)의 시간에 대한 정도 변화와 유용성 킬레이트화제를 함유하지 않은 조성물(비교실시예 1) 시간에 대한 점도변화를 비교하는 그래프이다

Claims (11)

  1. (1) 플루오로엘라스토머; (2) 4급 암모늡 또는 4급 포스포늄 염 폭진제 ; (3) 폴리올, (4) 산 수용체 ; (5) 유용성 킬레이트화제; 및 (7) 유기용매를 포함하는 도포용 조성물.
  2. 제1항에 있어서 상기 플루오로엘라스토머가 비닐리덴 플루오라이드-헥사플루오로프로펜 공중합체, 비닐리덴 플루오라이드-헥사플루오로프로펜-테트라플루오로에틸렌 삼원 공중합체, 또는 테트라플루오로에틸렌-프로필렌 공중합체인 조성물.
  3. 제1항에 있어서, 상기 폴리올이 2.2-비스(4-하이드록시페닐)프로판. 2.2-비스(4-하이드록시페닐)퍼플루오로프로판. 하이드로퀴논. 카테콜, 레조르신. 4,4'-디하이드록시디페닐. 4.4'-디하이드록시페닐메탄, 4,4'-디하이드록시페닐설폰, 및 2,2-비스(4-하이드록시페닐)부탄으로 구성된 그룹으로 선택되는 조성물
  4. 제1항에 있어서, 상기 4급 암모능 촉진제 염이 하기 일반식으토 표시되는 화합물 조성물 :
    상기식에서, R1내지 R4는 알킬 그룹. 아릴 그룹. 아르알킬 그룹. 알케닐 그룹. 폴리옥시알킬렌 그룹 및 플루오로알킬 그룹으로 구성된 그룹으로부터 독립 적 으로 선택되고 , X-는 할라이드, 하이드록실레이트, 알콕실레이트, 카복실레이트, 페녹사이드, 설포네이트, 설페이트, 설파이트, 카보네이트, 및 니트레이트로 구성된 그룹으로부터 선택된 음이온이다.
  5. 제4항에 있어서, 상기 4급 암모늄 촉진제가 테트라페닐암모늄 클로라이드, 테트라페닐암모늄 브로마이드, 테트라옥틸암모늄 클로라이드, 테트라-n-부틸암모늄 클로라이드, 테트라에틸암모늄 클로라이드, 테트라메틸암모늄 클로라이드, 테트라메틸암모늄 브로마이드, 트리페닐벤질암모늄 클로라이드, 트리페닐벤질 암모늄 브로마이드, 트리페닐벤질암모늄 스테아레이트. 트리페닐벤질암모늄 벤조에이트, 트리페닐이소부틸암모늄 브로마이드, 트리옥틸-n-부틸암모늄 클로라이드. 트리옥틸벤질암모늄 클로라이드, 트리옥틸벤질암모늄 아세테이트, 트리페닐-2,4-트리클로로벤질암모늄 클로라이드, 트리옥틸메톡시에톡시에틸암모늄 클로라이드, 트리페닐에톡시카보닐메틸암모늄 클로라이드, 트리페닐알릴암모늄 클로라이드, 1-알킬피리듐 염, 5-아르알킬-1, 5-디아자비사이클로[4.3.0]-5-노네늄염 및 8-아르알킬-1.8-디 아자비사이클로(5.4.0) -7-운데케늄염으로 구성된 그룹으로부터 선택되는 조성물.
  6. 제1항에 있어서, 상기 4급 포스포늄 측진제 염이 하기 일반식으로 표시되는 화합물 조성물.
    상기식에서, Rl내지 R4는 알킬 그룹, 아릴 그룹, 아르알킬 그룹, 알케닐그룹, 폴리옥시알킬렌 그룹 및 플루오로알킬 그룹으로 구성된 그룹으로부터 독립적으로 선택되고; X-는 할라이드 하이드록실레이트 알콕실레이트카복실레이트, 페녹사이드, 설포네이트, 설페이트, 설파이트, 카보네이트, 및 니트레이트로 구성된 그룹으로부터 선택된 음이온이다.
  7. 제6항에 있어서, 상기 포스포늄 클로라이드 촉진제 염이 테트라페닐포스포늄 클로라이드. 테트라페닐포스포늄 브로마이드, 테트라옥틸포스포늄 클로라이드, 테트라-R-부틸포스포늄 클로라이드. 테트라에틸포스포늄 클로라이드, 테트라메틸포스포늄 클로라이드. 테트라메틸포스포늄 브로마이드, 트리페닐벤질포스포늄 클로라이드 트레페닐벤질포스포늄 브로마이드, 트리페닐벤질 포스포늄, 스테아레이트, 트리페닐 벤질포스포늄 벤조이에트, 트리페닐이소부틸 포스포늄 브로마이드, 트리옥틸-n-부틸포스포늄 클로라이드. 트리옥틸벤질포스포늄 클로라이드. 트리옥틸벤질포스포늄 아세테이트, 트리페닐-2, 4-디클로로벤질포스포늄 클로라이드. 트리옥틸 메톡시에톡시에틸포스포늄 클로라이드. 트리페닐에톡시카보닐메틸포스포늄 클로라이드, 및 트리페닐알릴포스포늄 클로라이드로 구성된 그룹으로부터 선택되는 조성물.
  8. 제1항에 있어서. 상기 유용성 킬레이트화제가 에틸렌디아민 테트라아세트산, 글리콜 에케르 디아민 테트라아세트산, 및 디에틸렌트리아민 펜타아세트산으로 구성된 그룹으로 부터 선택된 다염기성 카복실산의 부분 알킬아민 염인 조성물.
  9. 제1항에 있어서, 상기 조성물이 90내지 60중량%의 싱분(1)내지 (5). 및 10내지 40중량%의 성분(6)을 포함하는 조성물.
  10. 제9항에 있어서, 성분(1)내지 (5)가, (1)플루오로엘라스토머 100중량부; (2) 4급 암모늄 또는 4급 포스포늄염 촉진제 0.5내지 10중량부; (3) 폴리을 01.내지 10중량부, (4) 산 수용체 1내지 30중량부: 및 (5) 유용성 킬레이트화제 0.1내지 5중량부의 중량비로 사용되는 조성물.
  11. 제1항에 있어서, 상기 유기 용매가 케톤, 에스테르, 알콜 또는 그틀의 혼합물인 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930009699A 1992-06-11 1993-05-31 플루오로엘라스토머 도포용 조성물 KR940005767A (ko)

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JP4151710A JPH05339536A (ja) 1992-06-11 1992-06-11 フッ素ゴム塗布用組成物
JP92-151710 1992-06-11

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US (2) US5451625A (ko)
EP (1) EP0574319B1 (ko)
JP (1) JPH05339536A (ko)
KR (1) KR940005767A (ko)
CA (1) CA2096689C (ko)
DE (1) DE69316452T2 (ko)
ES (1) ES2111723T3 (ko)

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DE69316452T2 (de) 1998-09-17
EP0574319A1 (en) 1993-12-15
JPH05339536A (ja) 1993-12-21
EP0574319B1 (en) 1998-01-21
US5658671A (en) 1997-08-19
DE69316452D1 (de) 1998-02-26
CA2096689A1 (en) 1993-12-12
ES2111723T3 (es) 1998-03-16
US5451625A (en) 1995-09-19

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