KR940004008A - 광학재료용 조성물 - Google Patents

광학재료용 조성물 Download PDF

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Publication number
KR940004008A
KR940004008A KR1019930016532A KR930016532A KR940004008A KR 940004008 A KR940004008 A KR 940004008A KR 1019930016532 A KR1019930016532 A KR 1019930016532A KR 930016532 A KR930016532 A KR 930016532A KR 940004008 A KR940004008 A KR 940004008A
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South Korea
Prior art keywords
optical material
composition
diallyl
dicarboxylate
general formula
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KR1019930016532A
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English (en)
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KR100284388B1 (ko
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히로시 우치다
야스지 다나카
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무라다 하지메
쇼와 덴코 카부시키카이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/14—Esters of polycarboxylic acids
    • C08F218/16—Esters of polycarboxylic acids with alcohols containing three or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/14—Esters of polycarboxylic acids
    • C08F218/16—Esters of polycarboxylic acids with alcohols containing three or more carbon atoms
    • C08F218/18—Diallyl phthalate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/24—Esters of carbonic or haloformic acids, e.g. allyl carbonate
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/041—Lenses

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Optical Record Carriers And Manufacture Thereof (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

선상 또는 분지된 알킬렌글리콜의 폴리알릴 카보네이트, 말단에 알릴에스테르기를 가지며 지환족디카르복실산 및 다가포화알코올로 부터 유도된 주쇄를 가지는 알릴에스테르 올리고머와, 필요에 따라서 디알릴에스테르, 알킬 (메스)아크릴레이트, 디알킬말레이트 또는 디알킬푸말레이트 단량체로 본질적으로 이루어지는 광학재료용 조성물.

Description

광학재료용 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 선상 또는 분지된 알킬렌글리콜의 폴리알릴 카보네이트 5내지 8wt%: 그 말단에 알릴에스테르기를 가지며 다음 일반식 (1)로 표시된 반복 단위를 가지는 알릴에스테르 올리고머 20내지 7wt%
    (식에서, X는 1내지 10의 정수. A는 다음 구조 1내지 6중 하나로 표시된 유기잔기률 나타내며,
    Z는 X+1수산기를 갖는 C2내 지 C30폴리올로 부터 유도된 유기잔기이다.) : 와 디알릴 1,2-, 1,3- 및 1,4-시플로헥산디카르복실레이트, 디알릴 4-시클로헥센-7,2-디카르복실레이트, 디알릴메킬-4-시클로헥센-1.2-디카르복실레이트, 디알릴[2,2,1] 비시클로-2-헵탄-5.6-디카르복실레이트, 디알릴[2,2,1]비시클로-헵 탄-2.3-디카르복실레이트. 아크릴산알킬. 메타크릴산알킬, 말레인산디알킬 및 푸마르산디알킬로 이루어지는 군으로 부터 선정된 적어도 한 단량체 7내지 5wt%로 본질적으로 이루어지는 것을 특징으로 하는 광학재료용 조성물,
  2. 제1항에 있어서, 상기 폴리알릴 카모네이트가 다음 일반식 (ll)로 표시되는 화합물로 부터 선정되는 것을 특징으로 하는 광학재료용 조성물.
    식에서, y는 1내지 10의 정수이고, Y는 y+1수산기를 갖는 C2내지 C12폴리올로 부터 유도된 유기잔기이다.
  3. 제1항에 있어서, 상기 폴리알릴카보네이트가 디에틸렌글리콜 디알릴 카보네이트인 것을 특징으로 하는 광학 재료용 조성물.
  4. 제1항에 있어서, 상기 일반식 (I)에서 Z가 에틸렌글리콜. 프로필렌글리콜, 1,3-부탄디올, 2-메틸-1, 3-프로판디올 및 네오펜틸글리콜로 부터 유도된 유기잔기로 부터 선정되는 것을 특징으로 하는 광학재료용 조성물.
  5. 제1항에 있어서, 30℃에서 20내지 20,000cp의 점도를 가지는 것을 특징으로 하는 광학재료용 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930016532A 1992-08-26 1993-08-25 광학재료용 조성물 KR100284388B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP92-248921 1992-08-26
JP24892192A JP3266162B2 (ja) 1992-08-26 1992-08-26 光学材料用組成物

Publications (2)

Publication Number Publication Date
KR940004008A true KR940004008A (ko) 1994-03-14
KR100284388B1 KR100284388B1 (ko) 2001-03-02

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Country Status (5)

Country Link
US (1) US5380809A (ko)
EP (1) EP0593877B1 (ko)
JP (1) JP3266162B2 (ko)
KR (1) KR100284388B1 (ko)
DE (1) DE69323262T2 (ko)

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DE69408466T2 (de) * 1993-08-24 1998-08-20 Akzo Nobel Nv Linsen zur korrektur von sehfehlern
US5756618A (en) * 1997-02-14 1998-05-26 Akzo Nobel Nv Polyol(allyl carbonate) compositions containing epoxy for reduced shrinkage
JP2001518633A (ja) 1997-09-30 2001-10-16 アクゾ ノーベル ナムローゼ フェンノートシャップ 眼科用レンズ
AU2114099A (en) * 1998-01-30 1999-08-16 Ppg Industries Ohio, Inc. Polymerizable polyol(allyl carbonate) composition
WO1999063365A1 (fr) * 1998-06-02 1999-12-09 Showa Denko K.K. Composition de resines utile dans des verres plastiques et de tels verres
JP2001201604A (ja) * 1999-11-11 2001-07-27 Showa Denko Kk プラスチックレンズ用組成物、プラスチックレンズ及び該プラスチックレンズの製造方法
JP2001201605A (ja) * 1999-11-11 2001-07-27 Showa Denko Kk プラスチックレンズ用組成物、プラスチックレンズ及び該プラスチックレンズの製造方法
JP2001201603A (ja) * 1999-11-11 2001-07-27 Showa Denko Kk プラスチックレンズ用組成物、プラスチックレンズ及び該プラスチックレンズの製造方法
CN1214256C (zh) * 2000-04-11 2005-08-10 昭和电工株式会社 塑料透镜材料,制备该材料的方法,塑料透镜组合物,通过固化该组合物得到的塑料透镜以及制备该塑料透镜的方法
US6545120B1 (en) 2000-06-16 2003-04-08 Showa Denko K.K. Production of alicyclic (meth)allyl esters for plastic lens compositions
AU2001264230A1 (en) * 2000-06-16 2001-12-24 Showa Denko K K Material for plastic lens, production process of the material, composition for plastic lens, plastic lens obtained by curing the composition, and production process of the plastic lens
JP2002069133A (ja) * 2000-06-16 2002-03-08 Showa Denko Kk プラスチックレンズ材料、該材料の製造方法、プラスチックレンズ用組成物、該組成物を硬化してなるプラスチックレンズ、及び該プラスチックレンズの製造方法
JP4754712B2 (ja) * 2000-06-16 2011-08-24 昭和電工株式会社 脂環式（メタ）アリルエステルモノマーの製造方法、脂環式（メタ）アリルエステル化合物、該化合物の製造方法、該化合物を含有するプラスチックレンズ用組成物、該組成物を硬化してなるプラスチックレンズ及びその製造方法
WO2002072651A1 (en) * 2001-03-09 2002-09-19 Showa Denko K. K. Plastic lens composition, plastic lens, and process for producing the plastic lens
JP4892963B2 (ja) * 2005-12-22 2012-03-07 住友ベークライト株式会社 樹脂組成物及び樹脂組成物を使用して作製した半導体装置
TWI412576B (zh) * 2006-04-06 2013-10-21 Showa Denko Kk Transparent conductive substrate
US8518524B2 (en) * 2006-07-21 2013-08-27 Showa Denko K.K. Transparent composite material
TW201326231A (zh) * 2011-09-09 2013-07-01 Showa Denko Kk 自由基聚合性化合物及自由基硬化性組成物
WO2016104389A1 (ja) 2014-12-22 2016-06-30 昭和電工株式会社 活性エネルギー線硬化性組成物およびその用途
JP2020050735A (ja) * 2018-09-26 2020-04-02 岡本化学工業株式会社 光学的立体造形用組成物、並びに立体造形物、及びその製造方法

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IT1228546B (it) * 1987-07-31 1991-06-20 Enichem Sintesi Composizione liquida polimerizzabile in vetri organici dotati di elevata stabilita' termica
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JP2592010B2 (ja) * 1990-08-20 1997-03-19 昭和電工株式会社 アリルエステルオリゴマー組成物およびそれを用いた光学材料用有機ガラス

Also Published As

Publication number Publication date
KR100284388B1 (ko) 2001-03-02
DE69323262D1 (de) 1999-03-11
JPH0673145A (ja) 1994-03-15
EP0593877A1 (en) 1994-04-27
DE69323262T2 (de) 1999-09-09
JP3266162B2 (ja) 2002-03-18
EP0593877B1 (en) 1999-01-27
US5380809A (en) 1995-01-10

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