KR920003609B1 - 올리고머화에 의한 알파-올레핀의 제조방법 - Google Patents

올리고머화에 의한 알파-올레핀의 제조방법 Download PDF

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Publication number
KR920003609B1
KR920003609B1 KR1019870007905A KR870007905A KR920003609B1 KR 920003609 B1 KR920003609 B1 KR 920003609B1 KR 1019870007905 A KR1019870007905 A KR 1019870007905A KR 870007905 A KR870007905 A KR 870007905A KR 920003609 B1 KR920003609 B1 KR 920003609B1
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South Korea
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group
catalyst
ligand
benzene ring
ring
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KR880001705A (ko
Inventor
유진 머레이 렉스
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유니온 카바이드 코포레이션
티모시 엔. 비숍
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2252—Sulfonate ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
KR1019870007905A 1986-07-21 1987-07-21 올리고머화에 의한 알파-올레핀의 제조방법 Expired KR920003609B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US06/887,183 US4689437A (en) 1986-07-21 1986-07-21 Oligomerization to alpha-olefins
US887,183 1986-07-21
US887183 1986-07-21

Publications (2)

Publication Number Publication Date
KR880001705A KR880001705A (ko) 1988-04-26
KR920003609B1 true KR920003609B1 (ko) 1992-05-04

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019870007905A Expired KR920003609B1 (ko) 1986-07-21 1987-07-21 올리고머화에 의한 알파-올레핀의 제조방법

Country Status (18)

Country Link
US (1) US4689437A (enExample)
EP (1) EP0254277B1 (enExample)
JP (5) JPH0764759B2 (enExample)
KR (1) KR920003609B1 (enExample)
CN (2) CN1011694B (enExample)
AR (1) AR243858A1 (enExample)
AT (1) ATE86957T1 (enExample)
AU (1) AU597397B2 (enExample)
BR (1) BR8703795A (enExample)
CA (1) CA1329608C (enExample)
DE (1) DE3784800T2 (enExample)
ES (1) ES2046185T3 (enExample)
FI (1) FI88802C (enExample)
GR (1) GR3008105T3 (enExample)
MY (1) MY101763A (enExample)
NO (1) NO173600C (enExample)
NZ (1) NZ221148A (enExample)
ZA (1) ZA875353B (enExample)

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CN105562095B (zh) * 2014-10-08 2018-06-15 中国石油化工股份有限公司 一种乙烯四聚催化剂组合物及乙烯四聚方法
CN105562099B (zh) * 2014-10-08 2018-01-23 中国石油化工股份有限公司 一种乙烯四聚催化剂组合物及乙烯四聚方法
CN105562098B (zh) * 2014-10-08 2018-03-02 中国石油化工股份有限公司 一种乙烯齐聚催化剂组合物及其应用
CN105562096B (zh) * 2014-10-08 2018-08-17 中国石油化工股份有限公司 一种乙烯四聚催化剂组合物及乙烯四聚方法
CN105562100B (zh) * 2014-10-13 2018-04-10 中国石油化工股份有限公司 一种乙烯四聚催化剂组合物及乙烯四聚方法
CN105498840B (zh) * 2014-10-13 2018-04-13 中国石油化工股份有限公司 一种乙烯四聚催化剂组合物及乙烯四聚方法
CN105478167B (zh) * 2014-10-13 2017-11-07 中国石油化工股份有限公司 一种乙烯齐聚催化剂组合物及乙烯齐聚方法
CN108484668A (zh) * 2018-04-25 2018-09-04 中山大学 具有磺酰基官能团的有机膦化合物及其制备方法和应用
CN110935489B (zh) * 2019-05-31 2021-10-26 东华大学 通过氢键作用的负载型过渡金属催化剂体系及其制备方法
CN110760336A (zh) * 2019-09-17 2020-02-07 中国科学院青岛生物能源与过程研究所 一种合成气直接制备高品质航油的方法
FR3117891B1 (fr) * 2020-12-23 2024-12-20 Ifp Energies Now Reacteur gaz/liquide d’oligomerisation comprenant une conduite centrale
CN113600241B (zh) * 2021-06-15 2022-12-09 华东理工大学 一种用于乙烯选择性三聚的催化剂体系及其制备和应用
CN115057427B (zh) * 2022-07-12 2023-07-04 江苏师范大学 一种金属单原子掺杂C/Se复合正极材料及其制备方法与应用
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NO173600B (no) 1993-09-27
DE3784800T2 (de) 1993-08-19
CN1051312A (zh) 1991-05-15
JPH0764759B2 (ja) 1995-07-12
ZA875353B (en) 1988-04-27
CN1011694B (zh) 1991-02-20
JPH10195000A (ja) 1998-07-28
ATE86957T1 (de) 1993-04-15
NZ221148A (en) 1989-04-26
FI873199L (fi) 1988-01-22
NO873048D0 (no) 1987-07-21
CN1022989C (zh) 1993-12-08
MY101763A (en) 1992-01-17
NO873048L (no) 1987-01-22
ES2046185T3 (es) 1994-02-01
JPH10195090A (ja) 1998-07-28
EP0254277A2 (en) 1988-01-27
GR3008105T3 (enExample) 1993-09-30
CN87105841A (zh) 1988-03-09
JPH10195089A (ja) 1998-07-28
EP0254277B1 (en) 1993-03-17
EP0254277A3 (en) 1988-12-28
KR880001705A (ko) 1988-04-26
AU597397B2 (en) 1990-05-31
CA1329608C (en) 1994-05-17
US4689437A (en) 1987-08-25
JP2915302B2 (ja) 1999-07-05
FI873199A0 (fi) 1987-07-21
JP2920126B2 (ja) 1999-07-19
JPS63113006A (ja) 1988-05-18
JP2948181B2 (ja) 1999-09-13
DE3784800D1 (de) 1993-04-22
AR243858A1 (es) 1993-09-30
AU7594987A (en) 1988-01-28
FI88802C (fi) 1993-07-12
NO173600C (no) 1994-01-05
JP2930921B2 (ja) 1999-08-09
BR8703795A (pt) 1988-03-29
FI88802B (fi) 1993-03-31
JPH07165821A (ja) 1995-06-27

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