KR910009688A - 광색성 화합물,이의 제조방법 및 용도 - Google Patents
광색성 화합물,이의 제조방법 및 용도 Download PDFInfo
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Abstract
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Claims (23)
1-펜옥시-4-메틸크산텐-9-온을 제외한 일반식(Ⅰ)의 화합물.
상기식에서, X는 O, S, SO, SO2또는 NR13이고, R1내지 R5는 각각 독립적으로 수소, C1-C12알킬, C1-C12알콕시, C1-C12알킬티오, C1-C4알킬-SO-, C1-C4알킬-SO2-, 할로겐, -CF3, -CN, -NO2, -OH, -COOR14, -CON(R15)2, 또는 -N(R15)2또는 일반식
(여기서, R16및 R17은 각각 독립적으로 C1-C6알킬, 페닐, C1-C6알킬페닐 또는 (C1-C6알킬)2-페닐이다)의 라디칼이거나, R3 및R4또는 R4및 R5각각은 함께 -CH=CH-CH=CH-를 형성하고;R6내지 R12는 각각 독립적으로 수소, C1-C12알킬, C1-C12알콕시, C1-C12알킬티오, C1-C12알킬-SO-, C1-C12알킬-SO2-, 벤질 또는 1 또는 2개의 -CN 및/또는 -COOR14에 의해 1-치환된 C1-C4알크-1-일, C6-C10아릴, C7-C14알랄킬, C6-C10아릴-CO, C6-C10아릴옥시, C6-C10아릴티오, C6-C10아릴-SO3-, C6-C10아릴-CO, C6-C10아릴옥시, C6-C10아릴-SO2, C7-C14아랄킬옥시, C7-C14아랄킬티오, C7-C14아랄킬-SO-, C7-C14아랄킬, C7-C14아랄킬-SO-, C7-C14아랄-SO2-, C1-C18아실-O-, -COOR14, -CON(R15)2, C1-C18아실-NR15-, (R15)2N-, 할로겐, -CF3또는 -CN이거나, R6내지 R12중 두개의 인접한 라디칼 각각은 그룹 -CO-O-CO- 또는 -CO-NR13-CO-이며, 이때 아릴 라디칼 및 아릴 그룹을 함유하는 라디칼은 할로겐, -CN, -CF3, C1-C6알킬티오, C1-C6알콕시, C1-C6알킬, -COOR14, -CO-N(R15)2또는 C1-C12알실-O-에 의해 치환되고, R13은 수소, C1-C12알킬 또는 C1-C12아실, 비치환되거나, C1-C6알킬, C1-C6알콕시, C1-C6알킬티오, 할로겐 또는 -COOR14에 의해 치환된 페닐 또는 벤질이고, 두개의 R15는 함께 C4-C6알킬렌, 3-옥시-1,5-페틸렌, 3-티아-1,5-펜틸렌, 1,3-부타디엔-1,4-디일 또는 2-아자-1,3-부타디엔-1,4-디일이거나, R15라디칼은 각각 독립적으로 수소, C1-C12알킬 또는 비치환되거나, C1-C6알킬, C1-C6알콕시, C1-C6알킬티오, 할로겐 또는 -COOR14에 의해 치환된 페닐 또는 벤질이며, R14는 수소 또는 OH그룹이 떨어져나간 방향족 또는 지방족 알코올이다.
제1항에 있어서, 일반식(Ⅰ)에서 R1내지 R5가 각각 독립적으로 수소, C1-C6알킬, C1-C6알콕시, 할로겐, CF3, -CN, -NO2, -COOR14, -OH 또는 -N(R15)2이거나, R3및 R4또는 R4및 R5가 각각 함께 -CH=CH-CH=CH-을 나타내고, R15는 각각은 C1-C6알킬이며, R14가 직쇄 또는 측쇄 C1-C18알킬인 화합물.
제2항에 있어서, 일반식(Ⅰ)에서 라디칼 R1내지 R5중의 2개 이상의 수소인 화합물.
제1항에 있어서, 일반식(I)에서 R6내지 R12는 각각 독립적으로 수소, C1-C6알킬, C1-C6알콕시, C1-C6알킬티오, C1-C6알킬-SO-, C1-C6알킬-SO2-, 1 또는 2개의 -CN 및/또는 -COOR14에 의해 1-치환된 C1- 또는 C2알킬, 페닐, 페닐-C1-C4알킬렌, 페닐-CO-, 페닐옥시, 페닐티오, 페닐-SO-, 페닐-SO2-, 벤질옥시, 벤질티오, 벤질-SO-, 벤질-SO2-, C1-C8아실-NR15-, -COOR14, -CO-N(R15)2, (R15)2N-, -T, -Cl, -Br, -CF3또는 -CN이거나, 두개의 인접한 R6내지 R12라디칼 각각은 함께 -CO-O-CO- 또는 -CO-NR13-CO-를 나타내며, R13이 C1-C6알킬 또는 비치환되거나, C1-C4알킬, C1-C4알콕시, F,Cl,Br 또는 -COOR14에 의해 치환된 페닐 또는 벤질이고, 두개의 R14는 수소, 직쇄 또는 측쇄 함께 C1-C16알킬, 페닐, 벤질 또는 (CnH-O)mR18(여기서, n은 정수 2 내지 6이고, m은 1 내지 20이며, R18은 수소, C1-C16알킬, 사이클로헥실, 페닐 또는 벤질이다)이며, R15,가 C1-C6알킬 또는 비치환되거나, C1-C4알킬, C1-C4알콕시, -F, -Cl, -Br 또는 -COOR14에 의해 치환된 페닐 또는 벤질이거나, 두개의 R15라디칼이 함께 1,4-부틸렌, 1,5-펜틸렌, 3-옥시-1,5-펜틸렌, 또는 1,3-부타디엔-1,4-디일인 화합물.
제1항에 있어서, 일반식(Ⅰ)에서 라디칼 R6내지 R12중 2개 이상이 수소인 화합물.
제1항에 있어서, 일반식(Ⅰ)에서 R6가 수소, -Cl, -Br 또는 메틸인 화합물.
제1항에 있어서, 일반식(Ⅰ)에서 R9가 수소 또는 -Cl인 화합물.
제1항에 있어서, 일반식(Ⅰ)에서 R11이 수소 또는 -Cl인 화합물.
제1항에 있어서, 일반식(Ⅰ)에서 R10및/또는 R12가 -Cl, -Br, 비치환되거나 치환된 펜옥시 또는 -COO-(C1-C2알킬)인 화합물.
제1항에 있어서, 일반식(Ⅰ)에서, R6가 수소, -Cl, -Br 또는 메틸이거나, R9가 수소 또는 -Cl이거나, R11이 수소 또는 -Cl이거나, R10및/또는 R12가 -Cl, -Br, 비치환되거나 치환된 펜옥시 또는 -COO-(C1-C2알킬)이거나, R7및/또는 R8이 수소, -F, -Cl, -NO2, CF3-, -Br, C1-C4알킬, C1-C4알콕시, 페닐-CO-, α-시아노벤질, C1-C8아실-NR15-, 피릴, -COO-(C1-C12알킬)펜옥시, 또는 비치환 되거나 -F, -CL, C1-C4알콕시, -COOH 또는 -COO-CC1-C12알킬)에 의해 치환된 페닐티오 또는 페닐티오닐이거나, R7또는 R8이 함께이고, R13이 수소 또는 C1-C6알킬인 화합물.
제1항에 있어서, 일반식(Ⅰ)에서 R13이 C1-C4알킬 또는 C1-C8아실, 또는 비치환되거나 F 또는 -COOR14에 의해 치환된 페닐 또는 벤질이고, R14는 수소 또는 C1-C12알킬인 화합물.
제1항에 있어서, 일반식(Ⅰ)에서 R14가 수소, C1-C18알킬, -CnH27-O-mH(여기서, n은 1 내지 6의 정수이고, m은 1 내지 20이다), 페닐, C1-C6알킬페닐, 벤질, C1-C6알킬벤질 또는 사이클로헥실인 화합물.
제1항에 있어서, 일반식(Ⅰ)에서 R15가 수소, C1-C6알킬, 페닐, 벤질이거나 두개의 R15라디칼이 함께 테트타메틸렌, 펜타메틸렌, 3-옥사-1,5-펜틸렌 또는 1,3-부타디엔-1,4-디일인 화합물.
제1항에 있어서, R1내지 R5가 수소이거나, R1,R2,R4및 R5가 수소이고, R3는 -CO2C2H5이며, R6및 R8이 Cl이고, R7및 R9내지 R12가 수소이며 X는 NCH3또는 N-n-C3H7인 화합물.
쌍극성 비양자성 용매 또는 양자성 용매의 존재하에 승온에서 일반식(Ⅱ)화합물을 일반식(Ⅲ)의 화합물과 반응시킴을 특징으로 하여, 제1항에 따른 일반식(Ⅰ)의 화합물을 제조하는 방법.
상기식에서, X 및 R1내지 R12는 제1항에서 정의한 바와 동일하고, Y는 -NO2또는 할로겐이며, M는 알칼리금속 양이온 또는 4급 암모늄 또는 포스포늄 양이온이다.
a)방사선-감지 유기물질 및 b)1-펜옥시-4-메틸크산텐-9-온을 포함하는 제1항에 따른 일반식(Ⅰ)의 화합물 하나 이상을 함유하는 방사선-감지 조성물.
제16항에 있어서, 일반식(Ⅰ)의 화합물이 성분 a)를 기준으로 하여 0.001 내 20중량%의 양으로 존재하는 조성물.
제16항에 있어서, 방사선-감지 유기물질이 a1)광중합성 또는 광이합성 에틸렌계 불포화 그룹을 함유하는 비휘발성 단량체, 올리고머 또는 중합체 물질, a2)양이온-경화가능한 시스템 또는 a3)광가교결합 가능한 폴리이미드인 조성물.
제18항에 있어서, 성분a1)이, 에스테르 그룹이 하기 일반식의 라디칼을 함유하는 아크릴레이트, 메타크릴레이트 또는 말레에이트의 단독중합체 또는 공중합체인 조성물.
상기식에서, A는 비치환되거나 하이드록실-치환된 직쇄 또는 측쇄C1-C12알킬렌, 사이클로헥실렌 또는 페닐렌이고, R20및 R21은 각각 독립적으로 Cl,Br,페닐 또는 C1-C4알킬이거나, 이들은 함께 트리메틸렌, 테트라메틸렌 또는을 나타낸다.
제18항에 있어서, 성분 a2)가, 광개시제가 혼입된, 분자중에 에폭사이드 그룹2개 이상을 함유하는 혼입된 에폭사이드 화합물인 조성물.
무색 유기용매, 중합체 또는 유기 글래스 또는 복합물 글래스, 및 1-펜옥시-4-메틸크산텐-9-온을 포함하는 제1항에 따른 일반식(Ⅰ)의 화합물을 함유하는 조성물.
1-펜옥시-4-메틸크산텐-9-온을 포함하는 제1항에 따른 일반식(Ⅰ)의 화합물을 물질중에 혼입시킨 다음, 이 물질을 광-조사시킴을 특징으로 하여, 광의 작용하에서 착색물질을 제조하는 방법.
1-펜옥시-4-메틸크산텐-9-온을 포함하는 제1항에 따른 일반식(Ⅰ)의 화합물의, 광 작용하에서의 감광제, 색지시제 또는 광개폐성 성분으로서의 용도.
※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
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CH427089 | 1989-11-29 | ||
CH4270/89-7 | 1989-11-29 |
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KR910009688A true KR910009688A (ko) | 1991-06-28 |
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US (2) | US5310909A (ko) |
EP (1) | EP0430881A3 (ko) |
JP (1) | JPH03190870A (ko) |
KR (1) | KR910009688A (ko) |
CA (1) | CA2030955A1 (ko) |
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DE919107C (de) * | 1940-04-03 | 1954-10-14 | Bayer Ag | Verfahren zur Herstellung von Xanthenen oder Thioxanthenen |
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US4752813A (en) * | 1986-08-08 | 1988-06-21 | International Business Machines Corporation | Schottky diode and ohmic contact metallurgy |
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1990
- 1990-11-20 EP EP19900810897 patent/EP0430881A3/de not_active Withdrawn
- 1990-11-21 US US07/616,550 patent/US5310909A/en not_active Expired - Fee Related
- 1990-11-27 CA CA002030955A patent/CA2030955A1/en not_active Abandoned
- 1990-11-27 KR KR1019900019252A patent/KR910009688A/ko not_active Application Discontinuation
- 1990-11-29 JP JP2326148A patent/JPH03190870A/ja active Pending
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US5432049A (en) | 1995-07-11 |
EP0430881A2 (de) | 1991-06-05 |
EP0430881A3 (en) | 1991-10-23 |
US5310909A (en) | 1994-05-10 |
JPH03190870A (ja) | 1991-08-20 |
CA2030955A1 (en) | 1991-05-30 |
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