KR910002978A - 알콕시화 만니히 축합물을 포함하는 폴리올 및 이의 제조방법 - Google Patents

알콕시화 만니히 축합물을 포함하는 폴리올 및 이의 제조방법 Download PDF

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Publication number
KR910002978A
KR910002978A KR1019890010552A KR890010552A KR910002978A KR 910002978 A KR910002978 A KR 910002978A KR 1019890010552 A KR1019890010552 A KR 1019890010552A KR 890010552 A KR890010552 A KR 890010552A KR 910002978 A KR910002978 A KR 910002978A
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South Korea
Prior art keywords
polyol
oxide
diethanolamine
propylene oxide
mixture
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KR1019890010552A
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English (en)
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KR0156240B1 (ko
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이. 매러그 존
에이. 피. 갠쇼 미하엘
에이. 퇸 요한
Original Assignee
리차드 지. 워터맨
더 다우 케미칼 캄파니
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Publication of KR910002978A publication Critical patent/KR910002978A/ko
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Publication of KR0156240B1 publication Critical patent/KR0156240B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C08G18/5033—Polyethers having heteroatoms other than oxygen having nitrogen containing carbocyclic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/54—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups bound to carbon atoms of at least one six-membered aromatic ring and amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings of the same carbon skeleton
    • C07C217/56—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups bound to carbon atoms of at least one six-membered aromatic ring and amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings of the same carbon skeleton with amino groups linked to the six-membered aromatic ring, or to the condensed ring system containing that ring, by carbon chains not further substituted by singly-bound oxygen atoms
    • C07C217/58—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups bound to carbon atoms of at least one six-membered aromatic ring and amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings of the same carbon skeleton with amino groups linked to the six-membered aromatic ring, or to the condensed ring system containing that ring, by carbon chains not further substituted by singly-bound oxygen atoms with amino groups and the six-membered aromatic ring, or the condensed ring system containing that ring, bound to the same carbon atom of the carbon chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/54—Polycondensates of aldehydes
    • C08G18/544—Polycondensates of aldehydes with nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyethers (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음.

Description

알콕시화 만니히 축합물을 포함하는 폴리올 및 이의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. (a)페놀 불활성적으로 치환된 페닐, (b) 포름알데하이드 및 (c)(ⅰ) 디에틴올아민과 (ⅱ) 디에탄올아민이 아닌 적어도 다른 하나의 알칸올아민의 혼합물(여기서, 다른 알칸올아민에 대한 디에탄올아민의 중량비는 1:19 내지 19:1 이다)의 알콕시화 만니히 축합물을 포함하는 폴리올.
  2. 제1항에 있어서, 하이드록시 수가 200 내지 700인 폴리올.
  3. 제2항에 있어서, 다른 알칸올아민이 디이소프로판올아민, 에탄올이소프로판옥아민, 에틴올아민 또는 모노이소프로판올아민인 폴리올.
  4. 제1항에 있어서, 성분(a) 및 (b)의 몰비가 1:0.9 내지 1:3.5 이고, 성분(b) 및 (c)의 몰비가 1:0.75 내지 1:1.5인 폴리올.
  5. 제4항에 있어서, 만니히 축합물을 만니히 축합물의 하이드록시 그룹 하나당 에틸렌 옥사이드, 프로필렌 옥사이드 및 이의 혼합물로 부터 선택된 알킬렌 옥사이드 0.5 내지 5몰로 알콕시화시킨 폴리올.
  6. 제5항에 있어서, 알킬렌 옥사이드가 프로필렌 옥사이드 또는 에틸렌 옥사이드와 프로필렌 옥사이드의 혼합물인 폴리올.
  7. 제6항에 있어서, 만니히 축합물을 에틸렌 옥사이드와 반응시킨 다음, 프로필렌 옥사이드와 반응시킨 폴리올.
  8. 제5항에 있어서, 성분(a) 대 (b)의 비가 1:1.5내지 1:2.25이고;만니히 축합물을 축합물상의 히이드록시 그룹 하나당 알킬렌 옥사이드 1 내지 1.2몰로 알콕시화 시키며:알킬렌 옥사이드는 프로필렌 옥사이드 또는 에틸렌 옥사이드와 프로필렌 옥사이드와 혼합물이고; 만니히 축합물을 에틸렌 옥사이드와 반응시킨 다음, 프로필렌 옥사이드와 반응시킨 폴리올.
  9. 폴리이소시아네이트 발포제 및 제1항, 제4항 또는 제8항의 폴리올을 포함하는 반응 혼합물의 반응생성물인 폴리우레탄 발포체.
  10. (a) 페놀성 화합물, (b)포름알데하이드 및 (c)(ⅰ)디에탄올아민과 (ⅱ)디에탄올아민이 아닌 적어도 하나의 다른 알칸올아민의 혼합물을 축합시키고, 축합 생성물을 알콕시화시키는 공정을 포함하는 폴리올의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890010552A 1988-07-27 1989-07-26 알콕시화 만니히 축합물을 포함하는 폴리올 및 이의 제조방법 KR0156240B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/225,313 US4883826A (en) 1988-07-27 1988-07-27 Tertiary amine-containing polyols prepared in a mannich condensation reaction using a mixture of alkanolamines
US225,313 1988-07-27

Publications (2)

Publication Number Publication Date
KR910002978A true KR910002978A (ko) 1991-02-26
KR0156240B1 KR0156240B1 (ko) 1998-12-01

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KR1019890010552A KR0156240B1 (ko) 1988-07-27 1989-07-26 알콕시화 만니히 축합물을 포함하는 폴리올 및 이의 제조방법

Country Status (11)

Country Link
US (1) US4883826A (ko)
EP (1) EP0352775B1 (ko)
JP (1) JP3145380B2 (ko)
KR (1) KR0156240B1 (ko)
AT (1) ATE93836T1 (ko)
AU (1) AU614650B2 (ko)
BR (1) BR8903799A (ko)
CA (1) CA1336440C (ko)
DE (1) DE68908811T2 (ko)
ES (1) ES2058414T3 (ko)
NZ (1) NZ230064A (ko)

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Also Published As

Publication number Publication date
BR8903799A (pt) 1990-03-20
AU3902889A (en) 1990-02-01
NZ230064A (en) 1991-12-23
JP3145380B2 (ja) 2001-03-12
ES2058414T3 (es) 1994-11-01
ATE93836T1 (de) 1993-09-15
EP0352775A1 (en) 1990-01-31
DE68908811D1 (de) 1993-10-07
DE68908811T2 (de) 1994-03-24
CA1336440C (en) 1995-07-25
AU614650B2 (en) 1991-09-05
US4883826A (en) 1989-11-28
KR0156240B1 (ko) 1998-12-01
JPH02132115A (ja) 1990-05-21
EP0352775B1 (en) 1993-09-01

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