KR930012921A - 폴리우레탄 발포체 - Google Patents

폴리우레탄 발포체 Download PDF

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KR930012921A
KR930012921A KR1019920024447A KR920024447A KR930012921A KR 930012921 A KR930012921 A KR 930012921A KR 1019920024447 A KR1019920024447 A KR 1019920024447A KR 920024447 A KR920024447 A KR 920024447A KR 930012921 A KR930012921 A KR 930012921A
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마레티 구이도
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수잔 제인 젠틀
임페리얼 케미칼 인더스트리이즈 피엘시
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
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    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4804—Two or more polyethers of different physical or chemical nature
    • C—CHEMISTRY; METALLURGY
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • C08G18/6685—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38 with compounds of group C08G18/3225 or polyamines of C08G18/38
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0008—Foam properties flexible
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0083—Foam properties prepared using water as the sole blowing agent

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

본 발명은 폴리이소시아네이트, 발포제인 물 및 에틸렌-옥사이드(EO) 함량이 적은 폴리올, EO 함량이 많은 폴리올 및 아민 사슬 연장제/가교제로 이루어진 이소시아네이트 반응성 조성무로부터 가요성 발표체를 제조하는 방법에 관한 것이다.

Description

폴리우레탄 발포체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 폴리이소시아네이트 성분, 폴리올 조성물 및 발포제인 물로 이루어진 반응 혼합물로부터 가요성 폴리우레탄 발포체를 제조하는 방법에 있어서, 폴리이소시아네이트 성분이 2 내지 2.4의 평균 이소시아네이트 관능가를 갖는 디페닐메탄 디이소시아네이트 조성물로 이루어지며, 폴리올 조성물이 (1) 옥시에틸렌 잔기를 함유한 1종 이상의 포리옥시알킬렌 폴리올로 이루어지고, 3이상의 평균 공칭 히드록실 관능가, 1500 이상의 평균 히드록실당량, 10 내지 20중량%의 평균 옥시에틸렌 함량 및 50% 이상의 평균 1차 히드록실기 함량을 갖는 제1폴리올 성분, (2)옥시에틸엔 잔기를 함유한 1종 이상의 폴리옥시알킬렌 폴리올로 이루어지고, 2 이상의 평균 공칭 히드록실 관능가, 1000 이상의 평균 히드록실 당량 및 50 내지 85중량%의 평균 옥시에틸렌 함량을 갖는 제2폴리올 성분, 및 (3)2개 이상의 이소시아네이트-반응기를 가지며, 그 중 1개 이상이 1급 또는 2급 아미노기이고, 분자량이 500 미만이 1종 이상의 화합물로 이루어진 사슬 연장제 및(또는) 가교제로 이루어지며, 상기 조성물은 (1) 성분 100 중량부 당 (2) 및 (3) 성분을 합쳐서 4 내지 20중령부의 양으로 함유하고, (3) 성분에 대한 (2) 성분의 중량비가 1:1 내지 20:1인 것을 특징으로 하는 방법.
  2. 제1항에 있어서, 제1폴리올 성분이 3 내지 4의 평균 공칭 히드록실 관능가를 갖고, 제2폴리올 성분이2 내지 4의 평균 공칭 히드록실 관능가를 갖는 것인 방법.
  3. 제1항 또는 2항에 있어서, 폴리올 조성물에 존재하는 각 폴리올 성분이 3 내지 4의 평균 공칭 히드록실 관능가를 갖는 것인 방법.
  4. (A) 2 내지 2.4의 평균 이소시아네이트 관능가를 갖는 디페닐메탄 디이소시아네이트 조성물, (B) (1) 옥시에틸렌 잔기를 함유한 1종 이상의 폴리옥시알킬렌 폴리올로 이루어지고, 3 이상의 평균 공칭 히드록실 관능가, 1500 이상의 평균 히드록실 당량, 10 내지 20중량%의 평균 옥시에틸렌 함량 및 50% 이상의 평균 1차 히드록실기 함량을 갖는 제1폴리올 성분, 92) 옥시에틸렌 잔기를 함유한 1종 이상의 폴리옥시알킬렌 폴리올로 이루어지고, 2 이상의 평균 공칭 히드록실기 관능가, 1000 이상의 평균 히드록실 당량 및 50 내지 85중량%의 평균 옥시에틸렌함량을 갖는 제2폴리올 성분, 및 (3) 2개 이상의 이소시아네이트-반응기를 가지며, 즈 중 1개 이상이 1급 또는 2급 아미노기이고, 분자량이 500 미만인 1종 이상의 화합물로 이루어진 사슬 연장제 및 (또는) 가교제로 이루어지며, 상기 조성물은 (1) 성분 100 중량부 당 (2) 및 (3) 성분을 합쳐서 4 내지 20중량부의 양으로 함유되고, (3)성분에 대한 (2) 성분의 중량비는 1:1 내지 20:1인 폴리올 조성물, (C) 발포제인 물, 및, 임의로 (D) 발포배합물에 통상적으로 사용되는 1종 이상의 첨가제로 이루어지는 반응계.
  5. 제4항에 있어서, 제1폴리올 성분이 3 내지 4의 평균 공칭 히드록실 관능가를 갖고, 제2폴리올 성분이 2 내지 4의 평균 공칭 히드록실 관능가를 갖는 반응계.
  6. 제4항 또는 5항에 있어서, 폴리올 조성물에 존재하는 각 폴리올 성분이 3 내지 4의 평균 공칭 히드록실 관능가를 갖는 반응계.
  7. (1) 옥시에틸렌 잔기를 함유한 1종 이상의 폴리옥시알킬렌 폴리올로 이루어지고, 3이상의 평균 공칭 히드록실 관능가, 1500 이상의 평균 히드록실 당량, 10 내지 20중량%의 평균 옥시에틸렌 함량 및 50% 이상의 평균 1차 히드록실기 함량을 갖는 제1폴리올 성분, (2) 옥시에틸렌 잔기를 함유한 1종 이상의 포리옥시알킬렌 폴리올로 이루어지고, 2 이상의 평균 공칭 히드록실 관능가, 1000 이상의 평균 히드록실 당량 및 50 내지 85중랴%의 평균 옥시에틸렌 함량을 갖는 제2폴리올 성부, 및 (3)2개 이상의 이소시아네이트-반응기를 가지며, 그 중 1개 이상이 1급 또는 2급 아미노기이고, 분자량이 500 미만인 1종 이상의 화합물로 이루어진 사슬 연장제 및(또는) 가교제로 이루어지며, 상기 (1) 성분 100 중량부 당 (2) 및 (3) 성분은 합쳐서 4 내지 20중량부의 양으로 함유되고, (3)성분에 대한 (2) 성분의 중량비는 1:1 내지 20:1인 폴리올 조성물.
  8. 제7항에 있어서, 제1폴리올 성분이 3 내지 4의 평균 공칭 히드록실 관능기를 갖고, 제2폴리올 성분이 2 내지 4의 평균 공칭 히드록실 관능가를 갖는 폴리올 조성물.
  9. 제7항 또는 8항에 있어서, 폴리올 조성물에 존재하는 각 폴리올 성분이 3 내지 4의 평균 공칭 히드록실 관능가를 갖는 폴리올 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920024447A 1991-12-17 1992-12-16 폴리우레탄 발포체 KR930012921A (ko)

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Application Number Priority Date Filing Date Title
GB9126741.9 1991-12-17
GB919126741A GB9126741D0 (en) 1991-12-17 1991-12-17 Polyurethane foams

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KR930012921A true KR930012921A (ko) 1993-07-21

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US (1) US5441993A (ko)
EP (1) EP0549120B1 (ko)
JP (1) JPH05255474A (ko)
KR (1) KR930012921A (ko)
CN (1) CN1043235C (ko)
AU (1) AU651743B2 (ko)
CA (1) CA2084808A1 (ko)
DE (1) DE69223756T2 (ko)
ES (1) ES2110477T3 (ko)
GB (1) GB9126741D0 (ko)
HK (1) HK1004606A1 (ko)
ZA (1) ZA929109B (ko)

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GB9126740D0 (en) * 1991-12-17 1992-02-12 Ici Plc Polyol compositions
GB9325043D0 (en) † 1993-12-07 1994-02-02 Polyol Int Bv Polyol compositions and their use in the preparation of high resilience polyurethane foams
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JP2584955B2 (ja) * 1994-12-07 1997-02-26 大同鋼板株式会社 変性ポリイソシアヌレート発泡体及びその製造法並びにポリオール組成物
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DE19725020C2 (de) * 1997-06-13 2001-10-31 Bayer Ag Verfahren zur Herstellung elastischer Polyurethanweichschaumstoffe
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EP1240227B1 (en) * 1999-11-02 2012-05-09 Huntsman International Llc Process for making high resilience foams
ES2204705T3 (es) * 1999-11-02 2004-05-01 Huntsman International Llc Procedimiento para elaborar espumas biscoelasticas, combinacion de polioles y sistema de reaccion utiles para el mismo.
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DE69223756D1 (de) 1998-02-05
GB9126741D0 (en) 1992-02-12
HK1004606A1 (en) 1998-11-27
ZA929109B (en) 1993-06-21
JPH05255474A (ja) 1993-10-05
CA2084808A1 (en) 1993-06-18
AU651743B2 (en) 1994-07-28
CN1043235C (zh) 1999-05-05
AU2858292A (en) 1993-06-24
US5441993A (en) 1995-08-15
DE69223756T2 (de) 1998-04-23
CN1073691A (zh) 1993-06-30
EP0549120A1 (en) 1993-06-30

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