KR910001014A - 액체 세제조성물 - Google Patents

액체 세제조성물 Download PDF

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KR910001014A
KR910001014A KR1019890008051A KR890008051A KR910001014A KR 910001014 A KR910001014 A KR 910001014A KR 1019890008051 A KR1019890008051 A KR 1019890008051A KR 890008051 A KR890008051 A KR 890008051A KR 910001014 A KR910001014 A KR 910001014A
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detergent composition
liquid detergent
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polymer
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그라함 몬타그 피터
코르넬리스 반 드 파스 요하네스
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에이치.드 로이
유니레버 엔.브이.
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/228—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with phosphorus- or sulfur-containing groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
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    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
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    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
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    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
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    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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    • C11D1/72—Ethers of polyoxyalkylene glycols

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Abstract

내용 없음

Description

액체 세제조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
첨부도면은 라벨라상의 부피분율과 점도사이의 관계를 도시한 그래프.

Claims (15)

  1. 수성 연속상 중에 라멜라액적의 분산액을 함유하는 액체세제조성물로서, pH는 12.5이하이며, 제조시로부터 21일동안 25℃에서 보관시 상분리가 2부피% 이하이며, 또한 친수성 백본과 하나이상의 소수성 곁사슬을 가지는 탈응집성 폴리머를 함유하는 것을 특징으로 하는 액체세제조성물.
  2. 조성물이 3-12중량%의 알킬벤젠술폰산 칼륨, 2-8중량%의 지방산 칼륨비누, 0.5-5중량%의 비이온 계면활성제, 및 1-25중량%의 트리폴리인산나트륨 및/또는 피로인산사칼륨을 함유하며, 상기 술폰산염대 상기 비이온 계면활성제의 중량비가 3:5-25:1 이고 술폰산염, 비누 및 비이온 계면활성제의 총량이 7.5-20중량%인 경우,감결합 폴리머는 부분 에스테르화된 중화된 말레산 무수물과 비닐 메틸에테르 에틸렌 또는 스티렌의 코폴리머만으로 구성되지 않는다는 것을 전제로 하는, 제조시로부터 21일동안 25℃에서 보관시 상분리가 2부피% 이하이며, 수성연속상 중에 라멜라 액적의 분산액을 함유하고, 또한 친수성 백본과 하나이상의 소수성 곁사슬을 가지는 탈응집성 폴리머를 함유하는 것을 특징으로 하는 액체세제 조성물.
  3. 제1항에 있어서, 폴리머는 다음과 같은 일반식(I)
    [위식에서, Z는 1이고, (x+y) : Z는 4:1-1000:1, 바람직하게는 6:1-250:1이며, 모노머단위는 임의의 수이고, y는 바람직하게 0에서부터 최고 x까지의 수이며 n은 1이상인 수이다 : R1은 -CO-O-, -O-,-O-CO-, -CH2, -CO-NH- 또는 생략가능하다 : R2는 C1-50알킬렌옥시기이거나 또는 생략가능하며, R3이 생략되고, R4가 H 또는 4이하의 탄소원자를 함유할때 R2는 C3이상의 알킬렌옥시기를 함유해야 한다는 것을 전제로 한다 : R3는 페닐렌 연쇄기이거나 생략가능하다.
    R4는 H 또는 C1-24알킬기 또는 C1-24알케닐기로서 a)R1이 -O-CO-인 경우, R2및 R3가 생략되고, R4가 5이상의 탄소원자를 함유해야 하는 것과 b) R2가 생략되는 경우R4는 H 이어서는 안되고, R3가 생략되는 경우 R4는 5이상의 탄소원자를 함유해야 하는 것을 전제로 한다 : R5는 H 또는 -COOA4기이다 : R6는 H 또는 C1-4알킬이다 : A1,A2,A3및 A4는 각각 수고, 알칼리금속, 알칼리토금속, 암모늄, 아민 및 C1-4중에서 선택된다]을 가지거나 또는 다음과 같은 일반식(II)
    [위식에서, Q2는 다음과 같은 일반식(IIa)을 가지는 분자단위이다 :
    (이 식에서 Z 및 R1-6는 일반식(I)에서 정의한 바와같고, A1-4는 일반식(I)에서 정의한 바와같거나 (C2H1O), H
    (여기에서 t는 1-50임)이며, 모노머단위는 임의의 수이다)
    Q1는 폴리머의 분자화를 가능하게 하는 다관능 모노머로서, 폴리머의 모너모들은 어느 방향으로든 임의의 수로 Q1에 연결될 수 있으며, 이로 인해 결과적으로 분지형 폴리머의 생성이 가능하다 : n 및 Z는 앞에서 정의한 바와 같고. V=1. (x+y+p+q+r) ;Z는 4:1-1000:1. 바람직하게는 6:1-250:1이고, 모노머단위는 임의의 수이다 : R7및 R8은 -CH3또는 -H이다 : R9및 R10은 각각 -SO3Na, -CO-O-C2H4-OSO3Na, -CO-O-NH-C(CH3)2-SONa, -CO-NH2, -O-CO-CH3, -OH 중에서 선택된다]을 가지는 것을 특징으로 하는 액체세제조성물.
  4. 제1항에 있어서, 폴리머는 다음과 같은 일반식(III)
    (위식에서, X는 4-1000이고, n, Z 및 R1-6은 일반식(I)에서 정의한 바와같고 모노머단위는 임의의 수이다 : A1은 일반식(I)에서 정의한 바와 같거나 또는 CO-CH2-C(OH)CO2A1-CH2-CO2A1이며, 혹은 일반식(III)의 기타 분자들이 결합되는 분지화 지점일수도 있다.)을 가지는 것을 특징으로 하는 액체세제조성물.
  5. 제1항에 있어서, 폴리머는 다음과 같은 일반식(IV)
    [위식에서, Z, n 및 A1은 일반식(I)에서 정의한 바와같고, (x+y) : z는 4:1-1000:1. 모노머단위는 임의의 수이다 : R1은 일반식(I)에서 정의한 바와 같거나, 또는 CH2-O-, -CH2-O-CO-, NH-CO-중에서 선택된다 : R2-4는 일반식(I)에서 정의한 바와 같으며 : R11은 -OH, -NH-CO-CH3, -SO3A1또는 -OSO3A1이다. R12은 -OH,-CH2OH, -CH2OSO3A1, COOA1, -CH2-OCH3중에서 선택된다]을 가지거나 또는 다음과 같은 일반식(V)
    (위식에서, n,Z 및 R1-6은 일반식(I)에서 정의한 바와같고 x는 일반식(III)에서 정의한 바와 같다)을 가지는 것을 특징으로 하는 액체세제조성물.
  6. 제1항에 있어서, 폴리머는 다음과 같은 일반식(VI)
    [위식에서, 적어도 하나의 R4기가 곁사슬로서 존재한다는 전제하에, Z가 R4기의 총수이면 (x+y) : z의 비는 4:1-1000:1이고, R4*는 R4또는 -H이며 : R2및 R4는 일반식(I)에서 정의한 바와같고 : S는 -H, -COOA1, -CH2COOA1, -CH(COOA1)2, (CH2COOA1)2H (여기서 A1은 일반식(I)에서 정의한 바와 같거나 R4이다)중에서 선택된다.]을 가지거나 또는 다음과 같은 일반식(VII)
    (위 식에서, x,z,s 및 R4는 일반식(VI)에서 정의한 바와같고(여기서 적어도 하나의 R4기가 곁사슬로서 존재함). V는 0 또는 1이다)을 가지는 것을 특징으로 하는 액체세제조성물.
  7. 제1항에 있어서, 폴리머는 폴리아크릴레이트를 표준물질로 하여 겔투과크로마토그래피에 의해 측정된 평균 분자량이 500-50000000인 것을 특징으로 하는 액체세제조성물.
  8. 제1항에 있어서, 탈응집성 폴리머의 총량은 총 조성물의 0.01-5중량%인 것을 특징으로 하는 액체세제조성물.
  9. 제1항에 있어서, 탈응집성 폴리머는 0.1이하(25℃)에서 메틸에틸케톤 100ml중 1g)의 비점도를 가지는 것을 특징으로 하는 액체세제조성물.
  10. 제1항에 있어서, pH가 11이하인 것을 특징으로 하는 액체세제조성물.
  11. 제1항에 있어서, 고체입자를 현탁상태로 함유하는 것을 특징으로 하는 액체세제조성물.
  12. 제1항에 있어서, 제조시로부터 90일간 25℃에서 보관한 후 외관상의 상분리가 0.1부피% 이하인 것을 특징으로 하는 액체세제조성물.
  13. 제1항에 있어서, 세제활성물질을 30중량%이상 함유하는 것을 특징으로 하는 액체세제조성물.
  14. 제1항에 있어서, 시어속도 21 S-1에서 1Pas이상의 점도를 가지는 것을 특징으로 하는 액체세제조성물.
  15. 이상의 청구범위중 어느 한항에 있어서, 45중량%이하의 물을 함유하는 것을 특징으로 하는 액체세제조성물.
    참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890008051A 1988-06-13 1989-06-12 액체세제 조성물 KR930002849B1 (ko)

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AU626876B2 (en) 1992-08-13
TR24781A (tr) 1992-03-09
DE68927465D1 (de) 1997-01-02
JPH0737635B2 (ja) 1995-04-26
DE68927465T2 (de) 1997-03-20
EP0727479A1 (en) 1996-08-21
ZA894428B (en) 1991-02-27
ES2096554T3 (es) 1997-03-16
EP0719857A1 (en) 1996-07-03
JPH0238500A (ja) 1990-02-07
ZA894482B (en) 1991-02-27
KR930002849B1 (ko) 1993-04-12
EP0346995A2 (en) 1989-12-20
MY107076A (en) 1995-09-30
EP0346995B1 (en) 1996-11-20
US5147576A (en) 1992-09-15
AU3632989A (en) 1989-12-14
GB8813978D0 (en) 1988-07-20
CA1336385C (en) 1995-07-25
ZA894481B (en) 1991-02-27
EP0346995A3 (en) 1990-09-19
BR8902764A (pt) 1990-02-01
IN169826B (ko) 1991-12-28

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