KR910000525A - 제올라이트 촉매, 이의 제조 방법 및 수소전환 공정에 있어서의 이의 사용 - Google Patents

제올라이트 촉매, 이의 제조 방법 및 수소전환 공정에 있어서의 이의 사용 Download PDF

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KR910000525A
KR910000525A KR1019890008351A KR890008351A KR910000525A KR 910000525 A KR910000525 A KR 910000525A KR 1019890008351 A KR1019890008351 A KR 1019890008351A KR 890008351 A KR890008351 A KR 890008351A KR 910000525 A KR910000525 A KR 910000525A
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zeolite
catalyst
ion
hydrogenation component
silica
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KR1019890008351A
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English (en)
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후이징가 톰
획크 아렌트
쉐퍼 헨니
헨드 리크 클라징가 아안
Original Assignee
오노 알버어스
셀 인터나쵸 나아레 레사아치 마아츠샤피 비이부이
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Application filed by 오노 알버어스, 셀 인터나쵸 나아레 레사아치 마아츠샤피 비이부이 filed Critical 오노 알버어스
Publication of KR910000525A publication Critical patent/KR910000525A/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/088—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/106—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/14—Iron group metals or copper
    • B01J29/146—Y-type faujasite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • C10G47/12—Inorganic carriers
    • C10G47/16—Crystalline alumino-silicate carriers
    • C10G47/20—Crystalline alumino-silicate carriers the catalyst containing other metals or compounds thereof

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  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Saccharide Compounds (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

내용 없음

Description

제올라이트 촉매, 이의 제조 방법 및 수소전환 공정에 있어서의 이의 사용
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (21)

  1. 최대한 0.13의 알칼리금속 옥사이드/알루미늄 옥사이드 몰비를 갖는 Y-유형의 제올라이트를 0.6-1.0A의 양이온 반경을 갖는 다가 금속염의 용액으로 처리하고 하소 단계없이 이온-교환된 제올라이트를 8족 및/또는 6b족 금속의 수소화 성분과 결합시키는 것을 포함하는 제올라이트 촉매의 제조방법.
  2. 제1항에 있어서, 고( )나트륨 옥사이드 함유 Y 제올라이트를 암모늄 화합물로 처리함으로 얻어진 출발 Y 제올라이트를 사용하는 방법.
  3. 제1항 또는 제2항에 있어서, 양이온 반경이 0.60-0.80A인 다가 금속 이온의 용액을 사용하는 방법.
  4. 제3항에 있어서, 갈륨, 철, 구리, 마그네슘, 코발트 및 니켈의 하나 또는 그 이상의 염들이 사용되는 방법.
  5. 제4항에 있어서, 갈륨 또는 니켈 염이 사용되는 방법.
  6. 제1항 내지 제5항중 어느 한 항에 있어서, 다가 금속의 염화물 또는 질산염이 사용되는 방법.
  7. 제1항 내지 제6항중 어느 한 항에 있어서, 0.005-2의 몰농도를 갖는 다가 금속염의 용액이 사용되는 방법.
  8. 제7항에 있어서, 0.01-1의 몰농도를 갖는 다가 금속염의 용액이 사용되는 방법.
  9. 제1항 내지 제8항중 어느 한 항에 있어서, 다가 금속염 용액으로 처리하는 것이 10-95°C의 온도에서 수행되는 방법.
  10. 제1항 내지 제9항 중 어느 한 항에 있어서, 이온-교환된 제올라이트가 200°C까지의 온도에서 건조 처리되는 방법.
  11. 제1항 내지 제10항 중 어느 한 항에 있어서, 이온-제올라이트가 함침 또는 특히 공-분쇄에 의해 수소화 성분(들)과 결합되는 방법.
  12. 제11항에 있어서, 이온-교환된 제올라이트와 수소화 성분(들)을 결합제와 함께 공-분쇄시킴으로 이온-교환된 제올라이트가 수소화 성분(들)과 결합되는 방법.
  13. 제12항에 있어서, 결합제가 실리카, 알루미나, 실리카-알루미나, 점토, 지르코니아, 실리카-지르코니아, 티타니아, 실리카-보리아 및 그의 혼합물로 구성된 내화 산화물의 군으로부터 선택되는 방법.
  14. 제13항에 있어서, 결합제가 실리카-알루미나 및 알루미나의 혼합물인 방법.
  15. 제1항 내지 제14항중 어느 하나에 따른 방법에 의해 얻을수 있으며, 최대한 0.13의 알카리 금속 옥사이드/알루미늄 옥사이드의 몰비와 이온-교환가능한 위치에서 0.6-1.0A의 양이온 반경을 갖는 다가 양이온 및 8족 및/또는 6b족 금속의 적어도 하나의 수소화 성분을 포함하는 촉매.
  16. 제15항에 있어서, 수소화 성분이 니켈, 코발트, 텅스텐, 몰리브덴, 백금 및 팔라듐 성분으로부터 선택된 촉매.
  17. 제15항 또는 제16항에 있어서, 결합제를 합유하는 촉매.
  18. 제1항 내지 제14항중 어느 한 항에 따른 방법에 의해 제조된 촉매.
  19. 수소전환 공정에 있어서, 제15항 내지 제18항중 어느 한 항에 따른 촉매의 사용.
  20. 탄화수소질 공급원료를 수소전환 조건하, 수소존재 하에서 제15항 내지 제18항중 어느 한 항에 따른 촉매인 제올라이트 촉매와 접촉시키는 수소 전환방법.
  21. 제20항에 있어서, 온도가 250-500°C이고 수소 압력이 300 바아이하이며 공간 속도가 0.1-1kg/1.h 이고 H2/공급원료 비가 100-5000 NI/kg인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890008351A 1988-06-20 1989-06-16 제올라이트 촉매, 이의 제조 방법 및 수소전환 공정에 있어서의 이의 사용 KR910000525A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB888814601A GB8814601D0 (en) 1988-06-20 1988-06-20 Process for preparation of zeolitic catalysts
GB88-14601.4 1988-06-20

Publications (1)

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KR910000525A true KR910000525A (ko) 1991-01-29

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Country Link
US (1) US5006496A (ko)
EP (1) EP0348001B1 (ko)
JP (1) JPH0240238A (ko)
KR (1) KR910000525A (ko)
CN (1) CN1026956C (ko)
AT (1) ATE105507T1 (ko)
AU (1) AU615307B2 (ko)
BR (1) BR8902925A (ko)
CA (1) CA1335587C (ko)
CS (1) CS275782B6 (ko)
DD (1) DD283951A5 (ko)
DE (1) DE68915209T2 (ko)
ES (1) ES2052884T3 (ko)
GB (1) GB8814601D0 (ko)
HU (1) HU204730B (ko)
IN (1) IN173676B (ko)
NZ (1) NZ229598A (ko)
RU (1) RU1813012C (ko)
TR (1) TR24411A (ko)
ZA (1) ZA894591B (ko)

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BRPI0714518B8 (pt) * 2006-08-03 2017-05-16 Shell Int Research método para produzir um catalisador altamente estável para hidrodessulfurização de hidrocarbonetos pesados e processo para dessulfurizar um suprimento de hidrocarbonetos pesados
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Also Published As

Publication number Publication date
ES2052884T3 (es) 1994-07-16
JPH0240238A (ja) 1990-02-09
US5006496A (en) 1991-04-09
IN173676B (ko) 1994-06-25
ZA894591B (en) 1990-02-28
EP0348001A1 (en) 1989-12-27
DD283951A5 (de) 1990-10-31
AU3647689A (en) 1989-12-21
CA1335587C (en) 1995-05-16
CS275782B6 (en) 1992-03-18
BR8902925A (pt) 1990-02-06
DE68915209T2 (de) 1994-08-18
TR24411A (tr) 1991-10-08
HU204730B (en) 1992-02-28
DE68915209D1 (de) 1994-06-16
ATE105507T1 (de) 1994-05-15
RU1813012C (ru) 1993-04-30
CN1026956C (zh) 1994-12-14
NZ229598A (en) 1990-10-26
CN1038594A (zh) 1990-01-10
AU615307B2 (en) 1991-09-26
EP0348001B1 (en) 1994-05-11
GB8814601D0 (en) 1988-07-27
HUT52739A (en) 1990-08-28

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