KR900018152A - 올레핀 중합용 성분 및 촉매 - Google Patents

올레핀 중합용 성분 및 촉매 Download PDF

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KR900018152A
KR900018152A KR1019890007468A KR890007468A KR900018152A KR 900018152 A KR900018152 A KR 900018152A KR 1019890007468 A KR1019890007468 A KR 1019890007468A KR 890007468 A KR890007468 A KR 890007468A KR 900018152 A KR900018152 A KR 900018152A
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catalyst component
compound
catalyst
electron donor
magnesium
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KR0161262B1 (ko
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카밀로 바르베 피에르
노리스티 루시아노
펜니니 기안니
알비자티 엔리코
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원본미기재
히몬트 인코포레이티드
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/68—Vanadium, niobium, tantalum or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/658—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in a single group of groups C08F4/653 - C08F4/657

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

내용 없음

Description

올레핀 중합용 성분 및 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (20)

  1. 다공질 중합성 지지체에 지지된 티탄 또는 바나듐 화합물을 함유함을 특징으로 하는, 촉매성분의 다공도가 0.2cc/g이상이고 세공분포는 세공중 최소한 30%의 반경이 150Å인 것과 같은 올레핀 중합용 촉매성분.
  2. 제1항에 있어서, 2-할로겐화 마그네슘을 추가로 함유하는 촉매성분.
  3. 제2항에 있어서, 티탄 또는 바나듐 화합물이 최소한 하나의 Ti-할로겐 또는 V-할로겐 결합을 갖는 촉매성분.
  4. 제3항에 있어서, 2-할로겐화 마그네슘의 가장 강한 희절선이 그 가장 강한 희절선의 위치에 비하여 쉬프트된 초대 강도의 할로에 의해 치환되는 X-선 스펙트럼을 나타내는 촉매성분.
  5. 제4항에 있어서, 금속 Ti, V 및 Mg 각각으로 나타내어 티탄 또는 바나듐 화합물 및 2-할로겐화 마그네슘이 1내지 10중량%로 존재하는 촉매성분.
  6. 제4항에 있어서, 전자 공여체 화합물을 추가로 함유하는 촉매성분.
  7. 제6항에 있어서, 전자 공요체 화합물을 방향족 모노 또는 비카르복실산의 알킬, 아릴 또는 시클로알킬 에스테르로 이루어지는 군에서 선택하는 촉매성분.
  8. 제7항에 있어서, 에스테르가 프탈산 에스테르인 촉매성분.
  9. 제6항에 있어서, 전자 공여체 화합물이 2,2,5,5, 테트라메틸피페리딘인 촉매성분.
  10. 제6항에 있어서, 전자 공여체 화합물이 최소한 하나의 Si-OR결합(이중, R은 1내지 6탄소원자의 알킬라디칼이다)또는 최소한 하나의 SiOR'결합(이중, R'는 3내지 18탄소원자의 측쇄 알킬라디칼 또는 시클로알킬라디칼이다)을 갖는 실리콘 화합물인 촉매성분.
  11. 제2항에 있어서, 다공도가 1내지 2cc/g이고 세공분포는 세공중 최소한 40%의 반경이 150내지 350Å인 것과 같은 촉매성분.
  12. 제2항에 기재된 촉매성분과 A1-알킬 화합물을 반응시키므로써 수득되는 생성물을 함유함을 특징으로하는 올레핀 중합용 촉매.
  13. 제2항에 있어서, 다공질 지지체가 부분적으로 교차결합된 스티렌 디비닐벤젠 공중합체인 촉매 성분.
  14. 중합성 지지체를 2-할로겐화 마그네슘 또는 할로겐화 제와 반응하여 2-할로겐화 마그네슘으로 변형 가능한 마그네슘 화합물 용액에 현착시키고, 증발에 의하여 용매를 제거하고 수득한 고형분을 티탄 또는 바나듐 화합물과 반응시킴을 특징으로하는, 다공도가 0.3cc/g이상이고, 세공 크기 분포는 세공중 최소한 40%의 반경이 150Å이상인 것과 같은 입자상인 촉매 성분의 제조방법.
  15. 제14항에 있어서, 마그네슘 화합물 용액이 MgCl2·2Ti(OC4H9)4화합물 또는 알콜에 용해된 2-염화마그네슘 용액을 함유하고, 용매를 증발시킨 후에 수득한 고형분을 TiCl4와 반응시키는 제조방법.
  16. 제1항에 기재된 촉매 성분과 Al-알킬 화합물과의 반응 생성물을 함유함을 특징으로하는 올레핀 중합용 촉매.
  17. 할로겐화 티탄 및 전자공여체 화합물을 함유하는 제3항에 기재된 촉매성분과 Al-트리알킬 화합물과의 반응 생성물을 함유함을 특징으로하는 올레핀 중합용 촉매.
  18. 제17항에 있어서, 전자 공여체 화합물을 Al-트리알킬 화합물의 함께 사용하는 촉매.
  19. 제18항에 있어서, 전자 공여체 화합물을 최소한 하나의 Si-OR결합(이중, R은 1 내지 8탄소원자의 알킬라디칼이다)또는 하나의 SiOR'결합 (이중, R'는 3내지 18탄소원자의 측쇄 알킬라디칼 또는 시클로알킬 라디칼이다)을 갖는 실리콘인 촉매.
  20. 제17항에 기재된 촉매에 의하여 수득된 편구형 올레핀 중합체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890007468A 1988-05-31 1989-05-31 올레핀 중합용 성분 및 촉매 KR0161262B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT20811/88A IT1217744B (it) 1988-05-31 1988-05-31 Componenti e catalizzatori per la polimerizzazione di olefine
IT20811A/88 1988-05-31

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KR900018152A true KR900018152A (ko) 1990-12-20
KR0161262B1 KR0161262B1 (ko) 1999-01-15

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EP (1) EP0344755B2 (ko)
JP (1) JP2776888B2 (ko)
KR (1) KR0161262B1 (ko)
CN (1) CN1040378A (ko)
AU (1) AU612264B2 (ko)
BR (1) BR8902484A (ko)
DE (1) DE68912827T3 (ko)
FI (1) FI101544B (ko)
HU (1) HU209975B (ko)
IT (1) IT1217744B (ko)
MX (1) MX16272A (ko)
NO (1) NO174154C (ko)
ZA (1) ZA894123B (ko)

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GB8827782D0 (en) * 1988-11-28 1988-12-29 Ici Plc Catalyst supports
US5055534A (en) * 1989-12-28 1991-10-08 Union Carbide Chemicals And Plastics Technology Corporation Preparation of very low molecular weight polyethylene in a fluidized bed
US5034366A (en) * 1989-12-29 1991-07-23 Union Carbide Chemicals And Plastics Technology Corporation High activity vanadium-based catalyst
IT1241062B (it) * 1990-01-10 1993-12-29 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1246265B (it) * 1990-09-07 1994-11-17 Enimont Anic Srl Componente solido di catalizzatore per la (co)polimerizzazione dell'etilene
US5227439A (en) * 1990-09-07 1993-07-13 Ecp Enichem Polimeri S.R.L. Solid component of catalyst for the (co) polymerization of ethylene
IT1245249B (it) * 1991-03-27 1994-09-13 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
IT1246614B (it) 1991-06-03 1994-11-24 Himont Inc Procedimento per la polimerizzazione in fase gas delle olefine
BE1007040A3 (fr) 1993-05-25 1995-02-28 Solvay Support de catalyseur et catalyseur de polymerisation des alpha-olefines; procedes pour leur obtention et polymerisation des alpha-olefines en presence du catalyseur.
FR2728181B1 (fr) 1994-12-16 1997-01-31 Appryl Snc Composante catalytique pour la polymerisation des olefines, son procede de fabrication, et procede de polymerisation des olefines en presence de ladite composante catalytique
US7049377B1 (en) 1995-02-21 2006-05-23 Basell Poliolefine Italia S.R.L. 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers
EP0952162A1 (en) * 1998-04-24 1999-10-27 Fina Research S.A. Production of Ziegler-Natta catalysts
JP2002173504A (ja) 2000-11-29 2002-06-21 Basell Technology Co Bv オレフィン重合用触媒およびオレフィン重合方法
US6583082B2 (en) 2000-12-01 2003-06-24 The Governors Of The University Of Alberta Functional organic particles for catalyst supports
US6683710B2 (en) 2001-06-01 2004-01-27 Optical Research Associates Correction of birefringence in cubic crystalline optical systems
WO2002100904A1 (en) 2001-06-13 2002-12-19 Basell Poliolefine Italia S.P.A Components and catalysts for the (co)polymerization of olefins
KR100451085B1 (ko) * 2001-10-31 2004-10-02 주식회사 효성 올레핀 중합용 촉매의 제조방법
JP2005529225A (ja) 2002-06-13 2005-09-29 バセル　ポリオレフィン　イタリア　エス．ピー．エー． エチレンコポリマー類の製造方法
CA2423921A1 (en) 2003-03-28 2004-09-28 Nova Chemicals Corporation Halogenated organic particles for catalyst supports
CN100447167C (zh) * 2006-06-30 2008-12-31 吉林市朋力科技开发有限公司 烯烃聚合用聚合物载体齐格勒-纳塔催化剂及制备方法
CN104448065B (zh) * 2014-12-11 2017-07-25 中国科学院长春应用化学研究所 一种烯烃聚合催化剂、其制备方法及聚乙烯的制备方法
BR112020018181B1 (pt) * 2018-03-07 2023-10-03 Mitsui Chemicals, Inc Método para produzir um copolímero em bloco de propileno e componente de catalisador de titânio sólido
CN110283261B (zh) * 2019-06-28 2021-08-03 上海化工研究院有限公司 一种烯烃聚合催化剂的主体组分及其制备方法

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Publication number Priority date Publication date Assignee Title
IT1098011B (it) * 1978-08-08 1985-08-31 Euteco Spa Catalizzatori supportati per la omo- o co-polimerizzazione di affa-olefine
GB2036761B (en) * 1978-11-28 1983-04-13 Inst Khim Fiz Akad Nauk Ssr & Catalyst for di-oligo-co and polymerization of vinyl monomers
ZA884614B (en) * 1987-06-29 1989-03-29 Shell Oil Co Method for crystallizing magnesium chloride for use in a catalyst composition
JPH072798B2 (ja) * 1987-10-28 1995-01-18 住友化学工業株式会社 オレフィン重合用固体触媒成分

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MX16272A (es) 1994-02-28
NO174154C (no) 1994-03-23
EP0344755A1 (en) 1989-12-06
CN1040378A (zh) 1990-03-14
JPH0297508A (ja) 1990-04-10
EP0344755B2 (en) 1997-09-10
FI892614A0 (fi) 1989-05-30
NO892180D0 (no) 1989-05-30
BR8902484A (pt) 1990-01-16
AU3588689A (en) 1989-12-07
FI101544B1 (fi) 1998-07-15
NO174154B (no) 1993-12-13
AU612264B2 (en) 1991-07-04
DE68912827T2 (de) 1994-08-04
FI101544B (fi) 1998-07-15
IT8820811A0 (it) 1988-05-31
HUT51304A (en) 1990-04-28
DE68912827T3 (de) 1998-04-02
FI892614A (fi) 1989-12-01
HU209975B (en) 1995-01-30
NO892180L (no) 1989-12-01
DE68912827D1 (de) 1994-03-17
EP0344755B1 (en) 1994-02-02
ZA894123B (en) 1990-03-28
KR0161262B1 (ko) 1999-01-15
JP2776888B2 (ja) 1998-07-16
IT1217744B (it) 1990-03-30

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