KR890700566A - 디올레핀의 선택적 히드로에스테르화 방법 - Google Patents

디올레핀의 선택적 히드로에스테르화 방법

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Publication number
KR890700566A
KR890700566A KR1019880701415A KR880701415A KR890700566A KR 890700566 A KR890700566 A KR 890700566A KR 1019880701415 A KR1019880701415 A KR 1019880701415A KR 880701415 A KR880701415 A KR 880701415A KR 890700566 A KR890700566 A KR 890700566A
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Prior art keywords
phenyl
formula
represented
ethylene
ethylphenyl
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KR1019880701415A
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English (en)
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KR950014220B1 (ko
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이소오 시미즈
야스오 마쓰무라
유다까 아라이
Original Assignee
가다야마 유다까
니혼 세끼유 가가꾸 가부시끼가이샤
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Publication of KR890700566A publication Critical patent/KR890700566A/ko
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Publication of KR950014220B1 publication Critical patent/KR950014220B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/46—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings and other rings, e.g. cyclohexylphenylacetic acid
    • C07C57/48—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings and other rings, e.g. cyclohexylphenylacetic acid having unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/325—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom
    • C07C1/326—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom the hetero-atom being a magnesium atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/50—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals polycyclic non-condensed
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/30—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings
    • C07C57/42—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms containing six-membered aromatic rings having unsaturation outside the rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/612—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety
    • C07C69/618—Esters of carboxylic acids having a carboxyl group bound to an acyclic carbon atom and having a six-membered aromatic ring in the acid moiety having unsaturation outside the six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

내용 없음.

Description

디올레핀의 선택적 히드로에스테르화 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 하기식(I)로 표시되는 (1-아릴에텐일)비닐벤젠을, 반응온도 : 40∼200℃, 일산화탄소압 20∼700kg/cm2의 조건에서, 귀금속착체 카르보닐화 촉매의 존재하에, 일산화탄소 및 물 또는 저급알코올과 반응시킴으로써 하기식(II)으로 표시되는 α-((1-아릴에텐일)페닐)프로피온산 또는 그 알킬에스테르를 제조하는 것을 특징으로하는 선택적 히드로 에스테르화 방법.
    (식중, Ar은 비닐기 이외의 치환기로 치환될 수 있는 치환 아릴기이고, R은 수소 또는 저급알칼이다.)
  2. 제1항에 있어서, 상기식(I)의 3-(1-페닐에텐일)비닐벤젠을 반응시킴으로써 α-(3-(1-페닐에텐일)페닐)프로피온산 또는 그 에스테르를 제조하는 것을 특징으로하는 선택적 히드로 에스테르화 방법.
  3. 제1항에 있어서, 상기식(I)의 (1-아릴에텐일)비닐벤젠이 하기 식(III)으로 표시되는 1, 1-디(치환아릴)에틸렌과의 혼합물인 것을 특징으로하는 방법.
    식중, Ar1, Ar2는 동일 또는 다른 치환 아릴기이고 어느것도 비닐기 이외의 치환기로 치환될 수 있다.
  4. 제3항에 있어서, 상기 식(III)의 1, 1-디(치환아릴)에틸렌이 1-페닐-1-에틸페닐에틸렌인 것을 특징으로하는 방법.
  5. 제3항에 있어서, 하기 공정(I) 및 공정(II)로 이루어지는 것을 특징으로하는 방법. 공정(I) : 식(A)으로 표시되는 1-페닐-1-에틸페닐-에탄을, 비활성 기체의 공존하에 온도 400℃ 내지 650℃에 있어서 산화철계 및/또는 산화크롬계 탈수소 촉매와 접촉시켜서 적어도 식(B)으로 표시되는 1-페닐-1-에틸페닐-에틸렌 및 식(C)로 표시되는 1-페닐-1-비닐페닐-에틸렌을 함유하는 탈수소 반응물을 얻는 공정, 및 공정(II) : 공정(I)에서 얻은 적어도 식(B)으로 표시되는 1-페닐-1-에틸페닐-에틸렌 및 식(C)로 표시되는 1-페닐-1-비닐페닐-에틸렌을 함유하는 탈수소 반응물을 반응온도 : 40 내지 200℃, 반응압력 20 내지 700kg/cm2의 조건에서 귀금속착체 카르보닐화 촉매의 존재하에서, 일산화탄소 및 물 또는 탄소수가 1 내지 4인 저급알코올에 의해 히드로에스테르화하고, 선택적으로 식(C)으로 표시되는 1-페닐-1-비닐페닐-에틸렌을 히드로에스테르화 하는 공정.
  6. 제5항에 있어서, 1-페닐-1-에틸페닐-에탄이, 에틸렌을 벤젠으로 알킬화함으로써 에틸벤젠 제조시에 부생하는 중질분에서 회수된 1-페닐-1-에틸페닐-에탄을 함유하는 유분인 것을 특징으로하는 방법.
  7. 제6항에 있어서, 상기 알킬화에 사용하는 촉매가 염화알루미늄 또는 합성 제올라이트 촉매인 것을 특징으로하는 방법.
  8. 제1항에 있어서, 상기 귀금속 착체촉매에 있어서의 귀금속이 Pd, Rh, Ir에서 선택되는 것을 특징으로하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880701415A 1987-03-12 1988-03-12 디올레핀의 선택적 히드로에스테르화 방법 KR950014220B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP62057099A JPH07100679B2 (ja) 1987-03-12 1987-03-12 α−（３−ベンゾイルフエニル）プロピオン酸またはそのエステルの製造方法
JP62-57099 1987-03-12
PCT/JP1988/000264 WO1988007034A1 (en) 1987-03-12 1988-03-12 Process for selectively hydroesterifying diolefin

Publications (2)

Publication Number Publication Date
KR890700566A true KR890700566A (ko) 1989-04-25
KR950014220B1 KR950014220B1 (ko) 1995-11-23

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ID=13046057

Family Applications (3)

Application Number Title Priority Date Filing Date
KR1019880002348A KR930006077B1 (ko) 1987-03-12 1988-03-07 1-(3-비닐페닐)-1-페닐에틸렌류 및 그의 제조방법
KR1019880002452A KR950014219B1 (ko) 1987-03-12 1988-03-09 (페닐에테닐)페닐프로피온산과 그 에스테르 및 (벤조일페닐)프로피온산 또는 그 에스테르의 제조방법
KR1019880701415A KR950014220B1 (ko) 1987-03-12 1988-03-12 디올레핀의 선택적 히드로에스테르화 방법

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KR1019880002348A KR930006077B1 (ko) 1987-03-12 1988-03-07 1-(3-비닐페닐)-1-페닐에틸렌류 및 그의 제조방법
KR1019880002452A KR950014219B1 (ko) 1987-03-12 1988-03-09 (페닐에테닐)페닐프로피온산과 그 에스테르 및 (벤조일페닐)프로피온산 또는 그 에스테르의 제조방법

Country Status (7)

Country Link
US (3) US4937375A (ko)
EP (3) EP0282063B1 (ko)
JP (1) JPH07100679B2 (ko)
KR (3) KR930006077B1 (ko)
CA (1) CA1299189C (ko)
DE (3) DE3865464D1 (ko)
WO (1) WO1988007034A1 (ko)

Families Citing this family (6)

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Publication number Priority date Publication date Assignee Title
JPH07100678B2 (ja) * 1987-03-12 1995-11-01 日本石油化学株式会社 α−（３−ベンゾイルフエニル）プロピオン酸の製造方法
JPS63233949A (ja) * 1987-03-23 1988-09-29 Nippon Petrochem Co Ltd ジオレフインの選択的ヒドロエステル化方法
US5237116A (en) * 1989-10-31 1993-08-17 Shell Oil Company Catalyst and process for coupling organometallic reagents with aryl or vinylic halides
US5059572A (en) * 1989-10-31 1991-10-22 Shell Oil Company Catalyst and process for coupling organometallic reagents with aryl or vinylic halides
CN101500984A (zh) * 2006-07-27 2009-08-05 于崇曦 具有快速皮肤穿透速度的带正电荷的水溶性酮洛芬及相关化合物的前药
RU2009106996A (ru) * 2006-10-17 2010-11-27 Джи-И Хелткер АС (NO) Способ получения альфа-кетокислот и их эфиров

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US4257973A (en) * 1971-11-05 1981-03-24 E. I. Du Pont De Nemours And Company Process of making acids or esters from unsaturated compounds
DE2646792C2 (de) * 1975-10-23 1985-05-09 Mitsubishi Petrochemical Co., Ltd., Tokio/Tokyo Verfahren zur Herstellung einer α-(arylsubstituierten)-Propionsäure und/oder eines Esters derselben
US4172087A (en) * 1978-02-13 1979-10-23 Texaco Development Corporation Process for preparing unsaturated aliphatic esters from aliphatic dienes
IT8123391A0 (it) * 1981-08-08 1981-08-08 Montedison Spa Processo per la preparazione di esteri di acidi arilpropionici otticamente attivi.
CA1194284A (en) * 1982-09-16 1985-10-01 Atsushi Sato Electrical insulating oil and oil-filled electrical appliances
CA1211761A (en) * 1982-12-25 1986-09-23 Atsushi Sato Electrical insulating substance and oil-filled electrical appliances containing the same
JPS59216849A (ja) * 1983-05-24 1984-12-06 Nissan Chem Ind Ltd α−フエニルプロピオン酸エステルの製造方法
JPS60189108A (ja) * 1984-03-08 1985-09-26 日本石油化学株式会社 電気絶縁油
US4694100A (en) * 1984-07-14 1987-09-15 Nippon Petrochemicals Company, Ltd. Method for producing α-(p-isobutylphenyl)propionic acid or its alkyl esters
JPS6222732A (ja) * 1985-07-24 1987-01-30 Nippon Petrochem Co Ltd １，１−（３−エチルフエニル）フエニルエチレン
GB8705699D0 (en) * 1987-03-11 1987-04-15 Shell Int Research Carbonylation of olefinically unsaturated compounds
JPH05170745A (ja) * 1991-12-25 1993-07-09 Kanebo Ltd ベンズイミダゾール誘導体、その製造法、それを有効成分とする制吐剤およびその製造用中間体

Also Published As

Publication number Publication date
KR950014220B1 (ko) 1995-11-23
EP0304495A1 (en) 1989-03-01
WO1988007034A1 (en) 1988-09-22
EP0282063B1 (en) 1991-10-16
EP0304495A4 (en) 1989-12-19
EP0304495B1 (en) 1992-05-27
EP0282065A3 (en) 1990-03-28
US4908473A (en) 1990-03-13
EP0282063A1 (en) 1988-09-14
KR950014219B1 (ko) 1995-11-23
KR880011066A (ko) 1988-10-26
US4937375A (en) 1990-06-26
JPH07100679B2 (ja) 1995-11-01
CA1299189C (en) 1992-04-21
EP0282065B1 (en) 1992-05-27
KR930006077B1 (ko) 1993-07-07
KR880011055A (ko) 1988-10-26
DE3865464D1 (de) 1991-11-21
DE3871409D1 (de) 1992-07-02
DE3871461D1 (de) 1992-07-02
JPS63225335A (ja) 1988-09-20
EP0282065A2 (en) 1988-09-14
US4822934A (en) 1989-04-18

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