KR880008965A - 알켄 또는 알킨을 카르보닐화하는 연속적 방법 - Google Patents

알켄 또는 알킨을 카르보닐화하는 연속적 방법 Download PDF

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Publication number
KR880008965A
KR880008965A KR1019880000541A KR880000541A KR880008965A KR 880008965 A KR880008965 A KR 880008965A KR 1019880000541 A KR1019880000541 A KR 1019880000541A KR 880000541 A KR880000541 A KR 880000541A KR 880008965 A KR880008965 A KR 880008965A
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KR
South Korea
Prior art keywords
ligand
added
carbonylating
alkynes
alkenes
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KR1019880000541A
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English (en)
Inventor
페트루스 레오나르두스
Original Assignee
오노 알버어스
셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이
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Application filed by 오노 알버어스, 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 filed Critical 오노 알버어스
Publication of KR880008965A publication Critical patent/KR880008965A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B41/00—Formation or introduction of functional groups containing oxygen
    • C07B41/06—Formation or introduction of functional groups containing oxygen of carbonyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

내용 없음.

Description

알켄 또는 알킨을 카르보닐화하는 연속적 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기 a)-c)를 포함하는 촉매시스템 존재하에 알켄 또는 알킨을 일산화탄소 및 히드록실기 함유 화합물과 반응시키는 것을 포함하는, 알켄 또는 알킨을 카르보닐화하는 연속적 방법.
    a) 팔라듐 또는 파라듐화합물. b) 리간드 c) 산
    여기서 리간드와 산은 연속적으로 혹은 간헐적으로 각각 반응에 첨가된다.
  2. 제1항에 있어서, 알켄이 출발물질로서 사용되는 방법.
  3. 제1항 또는 제2항에 있어서, 에텐, 아세틸렌, 프로펜 또는 프로핀이 카르보닐화되는 방법.
  4. 제1항 또는 제2항에 있어서 히드록실기 함유 화합물이 분자당 1 내지 6개의 탄소원자를 갖는 알콜인 방법.
  5. 제1항 내지 제4항중 어느 한 한에 있어서, 리간드가 인, 비소 또는 안티몬 원자를 포함한 리간드인 방법.
  6. 제4항에 있어서, 리간드가 포스핀인 방법.
  7. 제1항 내지 제6항중 어느 한 항에 있어서, 첨가되는 리간드와 첨가되는 산의 몰 비율이 0.75 내지 1.25 범위인 방법.
  8. 제6항에 있어서, 반응하는 동안에 등몰의 리간드와 산이 첨가되는 방법.
  9. 제1항 내지 제8항중 어느 한 항에 있어서, 반응 혼합물이 증류 장치에 도입되고 카르보닐화 생성물이 위쪽에서 증류되고 촉매 성분을 포함한 바닥에 남은 모든 생성물의 부분이 반응기로 재순환되는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880000541A 1987-01-29 1988-01-25 알켄 또는 알킨을 카르보닐화하는 연속적 방법 KR880008965A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB878701966A GB8701966D0 (en) 1987-01-29 1987-01-29 Carbonylation process
GB8701966 1987-01-29

Publications (1)

Publication Number Publication Date
KR880008965A true KR880008965A (ko) 1988-09-13

Family

ID=10611397

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880000541A KR880008965A (ko) 1987-01-29 1988-01-25 알켄 또는 알킨을 카르보닐화하는 연속적 방법

Country Status (7)

Country Link
EP (1) EP0279477B1 (ko)
JP (1) JP2573857B2 (ko)
KR (1) KR880008965A (ko)
CA (1) CA1312877C (ko)
DE (1) DE3870652D1 (ko)
ES (1) ES2032941T3 (ko)
GB (1) GB8701966D0 (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8917579D0 (en) * 1989-08-01 1989-09-13 Shell Int Research Preparation of alkyl propionates
US5166411A (en) * 1990-02-05 1992-11-24 Shell Oil Company Carbonylation catalyst system
GB9002521D0 (en) * 1990-02-05 1990-04-04 Shell Int Research Carbonylation catalyst system
BE1008018A3 (nl) * 1994-01-06 1995-12-12 Dsm Nv Werkwijze voor de bereiding van een ester.
DE10048874A1 (de) 2000-09-29 2002-04-11 Basf Ag Katalysatorsystem und Verfahren zur Carbonylierung
JP2006522801A (ja) * 2003-04-11 2006-10-05 サソル テクノロジー （ピーティーワイ）リミテッド カルボニル化方法
JP6099182B2 (ja) * 2014-05-29 2017-03-22 塩野義製薬株式会社 アルキニルケトン誘導体の製造方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4292437A (en) * 1979-06-27 1981-09-29 E. I. Du Pont De Nemours And Company Preparation of isobutyric acid and esters
DE3175174D1 (en) * 1981-01-06 1986-09-25 Shell Int Research Process for the carbonylation of olefins
US4414409A (en) * 1981-12-21 1983-11-08 E. I. Du Pont De Nemours & Company Palladium sulfonate catalyst systems for carbonylation of olefins
GB8432376D0 (en) * 1984-12-21 1985-02-06 Shell Int Research Carbonylation of acetylenically unsaturated compounds

Also Published As

Publication number Publication date
GB8701966D0 (en) 1987-03-04
EP0279477B1 (en) 1992-05-06
EP0279477A1 (en) 1988-08-24
JP2573857B2 (ja) 1997-01-22
DE3870652D1 (en) 1992-06-11
JPS63192738A (ja) 1988-08-10
ES2032941T3 (es) 1993-03-01
CA1312877C (en) 1993-01-19

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