KR890014660A - 방염성 올래핀계 수지 조성물 - Google Patents

방염성 올래핀계 수지 조성물 Download PDF

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KR890014660A
KR890014660A KR1019890003683A KR890003683A KR890014660A KR 890014660 A KR890014660 A KR 890014660A KR 1019890003683 A KR1019890003683 A KR 1019890003683A KR 890003683 A KR890003683 A KR 890003683A KR 890014660 A KR890014660 A KR 890014660A
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ethylene
resin composition
copolymer
olefin resin
weight
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노부아끼 오꾸다
야스오 나까가와
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노무라 마사오
스미또모베이크라이트 가부시끼가이샤
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Priority claimed from JP63081190A external-priority patent/JPH06102743B2/ja
Priority claimed from JP63081189A external-priority patent/JPH06102742B2/ja
Application filed by 노무라 마사오, 스미또모베이크라이트 가부시끼가이샤 filed Critical 노무라 마사오
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C08F255/026—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethylene-vinylester copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869—Acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Medicinal Chemistry (AREA)
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  • Compositions Of Macromolecular Compounds (AREA)
  • Compounds Of Unknown Constitution (AREA)
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  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
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Abstract

내용 없음.

Description

방염성 올래핀계 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. (a) 에틸렌-α-올레핀 공중합체류, 에틸렌-에틸렌아크릴레이트 공중합체 및 에틸렌-메틸 메타크릴레이트 공중합체로 구성된 군에서 선택되는 적어도 1종의 에틸렌 공중합체, (b) 실란을 올레핀계 수치에 그래프트화시켜 수득된 실란-그래프화 중합체, (c) 폴리에틸렌, 에틸렌-비닐아세테이트 공중합체 또는 에틸렌-α-올레핀 공중합체의 말레산 또는 말레산 무수물 유도체(d) (i) 에틸렌-에틸 아크릴레이트-말레산 무수물 공중합체 또는 에틸렌-메틸 메타크릴레이트-말레산 무수물 공중합체, 또는 (d)(ii) 반응성 폴리오르가노실록산을 열가소성 수지에 그래프트-중합시켜서 수득된 실리코운-개질 중합체, 또는(d) (iii) (d) (i) 및 (d) (ii)의 혼합물, 및 (e) 함수금속 화합물로 구성되며, 성분(a) 및 (b)의 100중량부를 모두 기준으로 하는여 성분(c)를 0.1∼30중량부로, 성분 (d) (i)를 사용할때는 0.1∼30중량부로, 성 분 (d) (ii)를 사용할때는 0.1 ∼30중량부로, 및 성분(e)를 50-300중량부로 혼입시킴을 특징으로 하는 방염성 올레핀계 수지 조성물.
  2. 제1항에 있어서, 에틸렌-α-올레핀 공중합체류의 α-올레핀의 프로필렌, 부텐-1, 펜텐-1, 헥센-1, 헵텐-1, 옥텐-1,4-메틸펜텐-1,4-메틸헥센-1,4,4-디메틸펜텐-1, 노넨-1, 데켄-1, 운덴켄-1 및 도데켄-1로 구성된 군에서 선택됨을 특징으로 하는 방염성 올레핀계 수지 조성물.
  3. 제1항에 있어서, 실란으로 그래프화되는 에틸렌계 수지는 저밀도 폴리에틸렌, 고밀도 폴리에틸렌, 고밀도 폴리에틸렌, 에틸렌-α-폴레핀 공중합체류, 에틸렌-비닐 아세테이트 공중합체, 에틸렌-에틸 아크릴레이트 공중합체, 에틸렌-메틸 마타크릴레이트 공중합체, 에틸렌-프로필렌 고무, 및 에틸렌-프로필렌-디엔 고무류로 구성된 군에서 선택됨을 특징으로 하는 방염성 올레핀계 수지 조성물.
  4. 제 1항에 있어서, 실란-그래프트화 중합체는 올레핀계 수지를 자유-라디칼 발생 화합물의 존재하에 일반식 RR′SiY2로 표현되는 유기실란(식중에서, R은 1가 올레핀계 불포화 탄화수소기 ; Y는 가수분해 가능한 유기기 ; 및 R′는 불포화 지방족 탄화수소기 이외의 1가 탄화수소기이거나 또는 Y와 동일함)과 반응시켜 수득됨을 특징으로 하는 방염성 올레핀계 수지 조성물.
  5. 제1항에 있어서, 실란-그래프트화 중합체를 성분(a) 및 (b)의 100중량부당 적어도 2중량부의 양으로 혼입함을 특징으로 하는 방염성 올레핀계 수지 조성물.
  6. 제1항에 있어서, 실란-그래프트화 중합체의 교차 결합도는 크실렌 불용분으로 정의되는 겔 분류분의 항으로 20~80중량%임을 특징으로 하는 방염성 올레핀계 수지 조성물.
  7. 제 1항에 있어서, 반응성 폴리오르가노실록산이 그래프트-중합되어지는 열가소성 수지는 폴리에틸렌, 폴리프로필렌, 에틸렌-α-올레핀 공중합체류, 에틸렌-비닐 아세테이트 공중합체, 에틸렌-에틸 아크릴레이트 공중합체, 에틸렌-메틸 마타크릴레이트 공중합체, 폴리스티렌 및 아크릴로니트릴-부타디엔-스티렌 공중합체로 구성된 군에서 선택됨을 특징으로 하는 방염성 올레핀계 수지 조성물.
  8. 제1항에 있어서, 함수 금속 화합물은 150~450℃의 분해-출발 온도를 가지며 일반식 MmOn·XH2O(식중 M은 금속 ; m 및 n은 각각은 급속의 공유가에 의해 결정되는 1이상의 정수 ; 및 X는 결합수의 분자수임)으로 표현되는 화합물이거나 또는 전술한 화합물을 함유하는 이중염 임을 특징으로 하는 방염성 올레핀계 수지 조성물.
  9. 제8항에 있어서, M은 주기율표 IA, IIA, IIB, IIIA, IVA 및 IVB족의 금속에서 선택됨을 특징으로 하는 방염성 올레핀계 수지 조성물.
  10. 제9항에 있어서, M은 주기율표의 IIA족의 금속에서 선택됨을 특징으로 하는 방염성 올레핀계 수지 조성물.
  11. 제9항에 있어서, M은 주기율표의 IIIA족의 금속에서 선택됨을 특징으로 하는 방염성 올레핀계 수지 조성물.
  12. 제8항에 있어서, 함수 금속 화합물은 산화마그네슘 1수화물임을 특징으로 하는 방염성 올레핀계 수지 조성물.
  13. 제8항에 있어서, 함수 금속 화합물은 산화 알루미늄 3수화물임을 특징으로 하는 방염성 올레핀계 수지 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890003683A 1988-03-24 1989-03-23 방염성 올레핀계 수지조성물 KR0127310B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP63-68238 1988-03-24
JP6823888A JPH06102741B2 (ja) 1988-03-24 1988-03-24 難燃オレフィン系樹脂組成物
JP63-81190 1988-04-04
JP63081190A JPH06102743B2 (ja) 1988-04-04 1988-04-04 難燃オレフィン系樹脂組成物
JP63081189A JPH06102742B2 (ja) 1988-04-04 1988-04-04 難燃オレフィン系樹脂組成物
JP63-81189 1988-04-04

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KR890014660A true KR890014660A (ko) 1989-10-25
KR0127310B1 KR0127310B1 (ko) 1998-04-01

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US (1) US5002996A (ko)
EP (1) EP0334205B1 (ko)
KR (1) KR0127310B1 (ko)
AT (1) ATE115608T1 (ko)
AU (1) AU614036B2 (ko)
CA (1) CA1332016C (ko)
DE (1) DE68919879T2 (ko)
FI (1) FI891395A (ko)
NO (1) NO306069B1 (ko)

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AU614036B2 (en) 1991-08-15
CA1332016C (en) 1994-09-13
KR0127310B1 (ko) 1998-04-01
US5002996A (en) 1991-03-26
FI891395A (fi) 1989-09-25
DE68919879D1 (de) 1995-01-26
NO891146L (no) 1989-09-25
AU3117089A (en) 1989-09-28
NO306069B1 (no) 1999-09-13
EP0334205B1 (en) 1994-12-14
EP0334205A2 (en) 1989-09-27
NO891146D0 (no) 1989-03-16
FI891395A0 (fi) 1989-03-23
EP0334205A3 (en) 1991-09-25
ATE115608T1 (de) 1994-12-15
DE68919879T2 (de) 1995-05-18

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