KR890010095A - 에폭시수지 조성물 및 그 개량방법 - Google Patents

에폭시수지 조성물 및 그 개량방법 Download PDF

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KR890010095A
KR890010095A KR1019880017466A KR880017466A KR890010095A KR 890010095 A KR890010095 A KR 890010095A KR 1019880017466 A KR1019880017466 A KR 1019880017466A KR 880017466 A KR880017466 A KR 880017466A KR 890010095 A KR890010095 A KR 890010095A
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hydrogen
resin composition
group
polymerization
groups
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KR1019880017466A
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English (en)
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KR0140998B1 (ko
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제이.알머 칼
제이. 슐츠 윌리암
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도날드 밀러 셀
미네소타 마이닝 앤드 매뉴팩츄어링 컴패니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/066—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with chain extension or advancing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/24—Di-epoxy compounds carbocyclic
    • C08G59/245—Di-epoxy compounds carbocyclic aromatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • C08G59/621—Phenols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins

Abstract

내용 없음

Description

에폭시수지 조성물 및 그 개량방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. (a) 하기 일반식(Ⅴ)에 의한 유닛을 약 2 내지 약 90중량%를 포함하고, (b) 경우에 따라 유효량의 인성화제를 포함하는 수지 조성물:
    상기식중, R0은 각각 수소 및 에폭시드기 함유 화합물의 중합에 대략 불활성인 다른기로부터 선택되고 R1은 각각 수소 및 에폭시드기 함유 화합물의 중합에 대락 불활성인 다른기로부터 선택된다.
  2. 제1항에 있어서, R0가 H, 할로겐, C1-6의 알킬기, 페닐, 니트로, 아세틸 및 트리메틸실릴로 이루어지는 군에서 각각 선택되고, R1이 수소, 페닐, 할로겐, 및 C1-6의 알킬기로 이루어지는 군에서 각각 선택되는 수지 조성물.
  3. (a) 하기 일반식(Ⅴ)에 의한 플루오렌 디-에폭시드 조성물을 약 5 내지 97중량% 포함하고, (b) 유효량의 인성화제를 포함하고, (c) 유효량의 경화제를 포함하는 전구체 조성물로부터 형성된 경화수지를 포함하는 결합필름 :
    상기식중, R0및 R1은 각각 수소 및 에폭시드기 함유 화합물의 중합에 대락 불활성인 다른기로부터 선택되고, R2는 에폭시기를 통해 반응하여 에폭시 수지를 형성할 수 있는 에폭시 작용성 알킬기이다.
  4. 하기 성분들을 포함하는 수지 조성물 : (a) 폴리에폭시수지, (b) 약 0.05 내지 0.9 히드록시 당량의 9,9-비스(히드록시페닐)플루오렌 조성물, (c) 경우에 따라서, 에폭시 경화제, 및 (d) 경우에 따라서, 적어도 하나의 인성화제.
  5. 제4항에 있어서, 상기 인성화제가 아크릴핵/쉘 중합체, 스티렌-부타디엔/메타크릴레이트핵/쉘중합체, 폴리에테르 중합체, 카르복실화 아클릴로니트릴/부타디엔, 카르복실화 부타디엔, 및 이들의 혼합물로 이루어지는 군에서 선택되는 수지조성물.
  6. 제4항에 있어서, 상기 9,9-비스(히드록시페닐)플루오렌 조성물이 적어도 하나의 하기일반식(Ⅰ)화합물을 포함하는 수지조성물 :
    상기식중, R0은 각각 수소 및 에폭시드기 함유 화합물의 중합에 대락 불활성인 다른기로부터 선택되고, R1는 각각 수소 및 에폭시드기 함유화합물의 중합에 대략 불활성인 다른기로부터 선택된다.
  7. 제1항의 조성물을 경화시키는 단계를 포함하는 개량된 경화수지의 제조방법.
  8. 제1기판과 제2기판간에 배열된 제1항의 수지조성물의 경화필름을 포함하는 접착제 결합필름/기판.
  9. 제8항에 있어서, 상기 수지조성물이 적어도 하나의 하기 일반식(Ⅰ)화합물을 포함하는 접착제 결합 필름/기판.
    상기식중, R0는 각각 수소 및 에폭시드기 함유 화합물의 중합에 대락 불활성인 다른기로부터 선택되고, R1은 각각 수소 및 에폭시드기 함유화합물의 중합에 대략 불활성인 다른기로부터 선택된다.
  10. 제8항에 있어서, 상기 수지조성물이 적어도 하나의 하기 일반식(Ⅰ)화합물을 포함하는 접착제 결합 필름/기판.
    상기식중, R0및 R1은 각각 수소 및 에폭시드기 함유화합물의 중합에 대락 불활성인 다른기로부터 선택되고, R2는 에폭시기를 통해 반응하여 에폭시수지를 형성할 수 있는 에폭시 작용성 알킬기이다.
    ※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880017466A 1987-12-23 1988-12-23 에폭시수지조성물 및 그 개량방법 KR0140998B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US137.453 1987-12-23
US07/137,453 US4983672A (en) 1987-12-23 1987-12-23 Epoxide resin compositions and method
US137,453 1987-12-23

Publications (2)

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KR890010095A true KR890010095A (ko) 1989-08-05
KR0140998B1 KR0140998B1 (ko) 1998-07-01

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US (1) US4983672A (ko)
EP (1) EP0325058B1 (ko)
JP (1) JP2806478B2 (ko)
KR (1) KR0140998B1 (ko)
AT (1) ATE122696T1 (ko)
AU (1) AU619513B2 (ko)
CA (1) CA1336525C (ko)
DE (1) DE3853816T2 (ko)
ES (1) ES2072265T3 (ko)
HK (1) HK1007565A1 (ko)

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ES2072265T3 (es) 1995-07-16
HK1007565A1 (en) 1999-04-16
EP0325058B1 (en) 1995-05-17
DE3853816D1 (de) 1995-06-22
KR0140998B1 (ko) 1998-07-01
JP2806478B2 (ja) 1998-09-30
CA1336525C (en) 1995-08-01
ATE122696T1 (de) 1995-06-15
DE3853816T2 (de) 1995-12-14
AU2754788A (en) 1989-06-29
EP0325058A1 (en) 1989-07-26
US4983672A (en) 1991-01-08
AU619513B2 (en) 1992-01-30
JPH021790A (ja) 1990-01-08

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