KR890009998A - 에테르형기에 의하여 치환된 방향족 헤테로 고리 화합물에서 유도한 전도성 중합체 및 이의 제조 방법, 이 중합체를 함유하는 장치와 이러한 중합체를 얻을 수 있는 단량체 - Google Patents

에테르형기에 의하여 치환된 방향족 헤테로 고리 화합물에서 유도한 전도성 중합체 및 이의 제조 방법, 이 중합체를 함유하는 장치와 이러한 중합체를 얻을 수 있는 단량체 Download PDF

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Publication number
KR890009998A
KR890009998A KR1019880016227A KR880016227A KR890009998A KR 890009998 A KR890009998 A KR 890009998A KR 1019880016227 A KR1019880016227 A KR 1019880016227A KR 880016227 A KR880016227 A KR 880016227A KR 890009998 A KR890009998 A KR 890009998A
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South Korea
Prior art keywords
aromatic heterocyclic
polymers
polymer
monomer
conductive polymer
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KR1019880016227A
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English (en)
Inventor
론칼리 장
가리우 로버트
델라보그리스 디디에르
레마일 마르크
가니에 프랑소와
한네카트 에티엔
Original Assignee
진-피에르 헤르만스
솔베이 앤드 시에(소시에떼 아노님)
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Priority claimed from FR8717117A external-priority patent/FR2624126B1/fr
Priority claimed from FR8811572A external-priority patent/FR2635907B3/fr
Application filed by 진-피에르 헤르만스, 솔베이 앤드 시에(소시에떼 아노님) filed Critical 진-피에르 헤르만스
Publication of KR890009998A publication Critical patent/KR890009998A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F34/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/33—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/333—Radicals substituted by oxygen or sulfur atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/42—Singly bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
    • C07D333/14—Radicals substituted by singly bound hetero atoms other than halogen
    • C07D333/16—Radicals substituted by singly bound hetero atoms other than halogen by oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes

Abstract

내용 없음

Description

에테르형기에 의하여 치환된 방향족 헤테로 고리 화합물에서 유도한 전도성 중합체 및 이의제조방법, 이 중합체를 함유하는 장치와 이러한 중합체를 얻을 수 있는 단량체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 최소한 두개의 탄소원자를 함유하는 알킬렌기에 의하여 헤테로 고리에 결합된 에테르-형 치환기로 헤테로 원자에 관한 3위치에서, 치환된 5원환 방향족 헤테로고리 단량체에서 유도된 반복 단위를 함유하는 전기전도성 중합체.
  2. 제1항에 있어서, 다음 일반식(Ⅰ)으로 표시되는 방향족 헤테로 고리 단량체에서 유도함을 특징으로 하는 전도성 중합체.
    (상기식에서 X는 황 및 산소 원자와-NH기에서 선택한 원자 또는 기를 나타내고, m는 2이상의 정수이고, n은 0 n 7의 정수이고, p는 0 p 2의 정수이고, n와 p의 합은 최소한 1이다)
  3. 제1항에 있어서, 제2항에 있어서, 중합체를 유도하는 방향족 헤테로고리 단량체가 3위치에서 치환된 티오펜임을 특징으로 하는 전도성 중합체.
  4. 제1항에 내지 제3항중 어느 한 항에 있어서, 중합체를 유도하는 방향족 헤테로고리 단량체가 3-(3',6'-디옥사헵틸)티오펜임을 특징으로 하는 전도성 중합체.
  5. 최소한 두개의 탄소원자를 함유하는 알킬렌기에 의하여 헤테로고리에 결합된 에테르-형 치환기에의하여, 헤테로 원자에 관한 3위치에서 치환된 5원환 방향족 헤테로고리 화합물에서 선택한 단량체를 적당한 전해질의 존재하에서와 극성 용매에서 음극 산화에 의하여 전기화학적으로 중합함을 특징으로 하는 전기 전도성 중합체의 제조방법.
  6. 제5항에 있어서, 단량체가 3-(3',6'-디옥사헵틸)티오펜임을 특징으로 하는 제조방법.
  7. 제1항 내지 제4항중 어느 한 항에 따른 중합체를 함유하는 전기 전도성 장치.
  8. 양극(또는 음극)이 음이온(또는 양이온)으로 도우프된, 제1항 내지 제4항중 어느 한 항의 중합체의 막으로 피복된 전극으로 구성되는 전기 화학적 에너지 저장 장치.
  9. 양극(또는 음극)이 제1항 내지 제4항중 어느 한 항에 따른 중합체 막으로 피복된 엘렉트로크로믹 장치.
  10. 제1항 내지 제4항중 어느 한 항에 따른 중합체를 주재로 한 근적외선과 고주파 방사선을 흡수하기 위한 장치.
  11. 다음 일반식(Ⅱ)에 해당함을 특징으로 하는, 제3항에 따른 전도성 중합체를 얻는데 사용할 수 있는 단량체;
    (상기식에서, m'는 2 또는 3이고, p'는 0 또는 1이다)
  12. 2'-(3-티에닐)에탄올 또는 대응하는 3'-치환 1-프로판올을 옥시알킬할로겐화물과 반응시킴을 특징으로 하는 제11항에 따른 단량체의 제조방법.
    ※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880016227A 1987-12-07 1988-12-06 에테르형기에 의하여 치환된 방향족 헤테로 고리 화합물에서 유도한 전도성 중합체 및 이의 제조 방법, 이 중합체를 함유하는 장치와 이러한 중합체를 얻을 수 있는 단량체 KR890009998A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR8717117 1987-12-07
FR8717117A FR2624126B1 (fr) 1987-12-07 1987-12-07 Polymeres conducteurs derives d'heterocycles aromatiques substitues par un groupement de type ether, procede pour leur obtention et dispositifs contenant ces polymeres
FR8811572A FR2635907B3 (fr) 1988-09-01 1988-09-01 Polymeres conducteurs derives d'heterocycles aromatiques substitues par un groupement de type ether, procede pour leur obtention, dispositifs contenant ces polymeres et monomeres permettant d'obtenir de tels polymeres
FR8811572 1988-09-01

Publications (1)

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KR890009998A true KR890009998A (ko) 1989-08-05

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KR1019880016227A KR890009998A (ko) 1987-12-07 1988-12-06 에테르형기에 의하여 치환된 방향족 헤테로 고리 화합물에서 유도한 전도성 중합체 및 이의 제조 방법, 이 중합체를 함유하는 장치와 이러한 중합체를 얻을 수 있는 단량체

Country Status (6)

Country Link
US (1) US5204424A (ko)
EP (1) EP0323656B1 (ko)
JP (1) JP2647705B2 (ko)
KR (1) KR890009998A (ko)
DE (1) DE3880120T2 (ko)
IL (1) IL88541A (ko)

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EP0323656B1 (fr) 1993-04-07
US5204424A (en) 1993-04-20
IL88541A (en) 1992-02-16
DE3880120D1 (de) 1993-05-13
EP0323656A1 (fr) 1989-07-12
IL88541A0 (en) 1989-06-30
JP2647705B2 (ja) 1997-08-27
DE3880120T2 (de) 1993-10-14
JPH0222325A (ja) 1990-01-25

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