KR910002832A - 플루오르화 티오펜, 이들 티오펜에서 유도된 전도성 중합체, 이들의 제조방법과 이들 중 합체를 함유하는 장치 - Google Patents

플루오르화 티오펜, 이들 티오펜에서 유도된 전도성 중합체, 이들의 제조방법과 이들 중 합체를 함유하는 장치 Download PDF

Info

Publication number
KR910002832A
KR910002832A KR1019900010343A KR900010343A KR910002832A KR 910002832 A KR910002832 A KR 910002832A KR 1019900010343 A KR1019900010343 A KR 1019900010343A KR 900010343 A KR900010343 A KR 900010343A KR 910002832 A KR910002832 A KR 910002832A
Authority
KR
South Korea
Prior art keywords
integer
hydrogen atom
thiophenes
represent
polymer according
Prior art date
Application number
KR1019900010343A
Other languages
English (en)
Inventor
버크너 베르너
롱칼리 장
가르니에르 프랑시스
르메이어 마르크
가레오 로버트
하네카트 에티엔
Original Assignee
진-피에르 헤르만스
솔베이 앤드 시에(소시에떼 아노님)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 진-피에르 헤르만스, 솔베이 앤드 시에(소시에떼 아노님) filed Critical 진-피에르 헤르만스
Publication of KR910002832A publication Critical patent/KR910002832A/ko

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
    • C07D333/12—Radicals substituted by halogen atoms or nitro or nitroso radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Abstract

내용 없음.

Description

플루오르화 티오펜, 이들 티오펜에서 유도된 전도성 중합체, 이들의 제조방법과 이들 중합체를 함유하는 장치
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
생성된 볼트 암모그램을 나타낸 그래프.

Claims (10)

  1. 다음 일반식(I)으로 표시됨을 특징으로 하는 치환 티오펜:
    상기식에서 -R은 수소원자 또는 1-4개의 탄소원자를 함유하는 지방족기를 나타내고, -X와 Z는 같거나 다르고 수소원자 또는 불소 원자를 나타내며, -Y는 최소한 부분적으로 플루오로화된 지방족 또는 방향족 기를 나타내고, -m는 1이거나 그 이상인 정수를 나타내고, -n은 ≤n≤;12와 같은 정수를 나타낸다.
  2. 제1항에 있어서, -R은 수소원자를 나타내고, -X와 Z는 불소 원자를 나타내며, -Y는 p가 2,3또는 4의 정수를 나타내는 일반식-(CH2)p-CF3의 지방족기를 나타내고, -m은 3이고, -n이 1임을 특징으로 하는 치환티오펜.
  3. 다음 일반식(Ⅱ)의 중합체;
    상기식에서, -q은 정수지고, -R은 수소원자 또는 1-4개의 탄소 원자를 함유하는 지방족기를 나타내며, -X와 Z는 같거나 다르고 수소원자 또는 불소 원자를 나타내며, -Y는 최소한 부분적으로 플루오르화된 지방족 또는 방향족기를 나타내며, -m는 1이거나 그 이상을 나타내며, -n는 0≤n≤12와 같은 정수를 나타낸다.
  4. 제3항에 있어서, -q가 2-500의 정수이고, -R이 수소원자이며, -X와 Z가 불소원자를 나타내며, -Y는 p가 2,3 또는 4의 정수인 일반식-(CH2)p-CF3의 지방족기를 나타내며, -m은 3이고, -n이 1임을 특징으로 하는 중합체.
  5. 제3항과 제4항에 따른 중합체와 도우핑제를 함유하는 전기 전도성 중합체.
  6. 제1항 또는 제2항에 따른 치환 티오펜에서 선택한 단량체를 극성 용매에서와 적당한 전해질의 존재하에서 양극 산화하므로서 전기 화학적으로 중합시킴을 특징으로 하는 제5항에 따른 전기 전도성 중합체의 제조방법.
  7. 제5항에 따른 전기 전도성 중합체를 함유하는 전기 전도성 장치.
  8. 양극(또는 음극)이 음이온(또는 양이온)으로 도우프된 제3항 또는 제4항에 따른 중합체의 막으로 피복된 전극으로 구성되는 에너지 저장용 전기화학 장치.
  9. 양극(또는 음극)을 제5항에 따른 중합체의 막으로 피복한 전기크롬장치.
  10. 제5항에 따른 중합체를 주재로한 근적외선과 고주파 방사선의 흡수용 장치.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900010343A 1989-07-10 1990-07-09 플루오르화 티오펜, 이들 티오펜에서 유도된 전도성 중합체, 이들의 제조방법과 이들 중 합체를 함유하는 장치 KR910002832A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR89.09368 1989-07-10
FR898909368A FR2649396B1 (fr) 1989-07-10 1989-07-10 Thiophenes fluores, polymeres conducteurs derives de ces thiophenes, procede pour leur obtention et dispositifs contenant ces polymeres

Publications (1)

Publication Number Publication Date
KR910002832A true KR910002832A (ko) 1991-02-26

Family

ID=9383710

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900010343A KR910002832A (ko) 1989-07-10 1990-07-09 플루오르화 티오펜, 이들 티오펜에서 유도된 전도성 중합체, 이들의 제조방법과 이들 중 합체를 함유하는 장치

Country Status (6)

Country Link
EP (1) EP0408105B1 (ko)
JP (1) JP2892784B2 (ko)
KR (1) KR910002832A (ko)
AT (1) ATE116981T1 (ko)
DE (1) DE69015906T2 (ko)
FR (1) FR2649396B1 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100580620B1 (ko) * 2002-03-09 2006-05-16 삼성전자주식회사 신규한 전도성 고분자, 이를 이용한 센서 및 표적 물질검출 방법

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6515649B1 (en) 1995-07-20 2003-02-04 E Ink Corporation Suspended particle displays and materials for making the same
US6727881B1 (en) 1995-07-20 2004-04-27 E Ink Corporation Encapsulated electrophoretic displays and methods and materials for making the same
US7109968B2 (en) 1995-07-20 2006-09-19 E Ink Corporation Non-spherical cavity electrophoretic displays and methods and materials for making the same
US6067185A (en) 1997-08-28 2000-05-23 E Ink Corporation Process for creating an encapsulated electrophoretic display
US6445489B1 (en) * 1998-03-18 2002-09-03 E Ink Corporation Electrophoretic displays and systems for addressing such displays
CA2323879C (en) 1998-04-10 2007-01-16 E Ink Corporation Electronic displays using organic-based field effect transistors
JP4651193B2 (ja) 1998-05-12 2011-03-16 イー インク コーポレイション ドローイングデバイス用途のためのマイクロカプセル化した電気泳動性の静電的にアドレスした媒体
US6376828B1 (en) 1998-10-07 2002-04-23 E Ink Corporation Illumination system for nonemissive electronic displays
JP4582914B2 (ja) 1999-04-06 2010-11-17 イー インク コーポレイション カプセルベースの起電ディスプレイにおける使用のための液滴を作製するための方法
US6498114B1 (en) 1999-04-09 2002-12-24 E Ink Corporation Method for forming a patterned semiconductor film
WO2001017040A1 (en) 1999-08-31 2001-03-08 E Ink Corporation A solvent annealing process for forming a thin semiconductor film with advantageous properties
US6545291B1 (en) 1999-08-31 2003-04-08 E Ink Corporation Transistor design for use in the construction of an electronically driven display

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3052691A (en) * 1959-04-24 1962-09-04 Du Pont Polyfluorinated heterocyclic sulfides
US3197480A (en) * 1962-12-12 1965-07-27 Du Pont 2 and 2, 4-(alpha hydroxypolyperhalocycloalkyl)-thiophenes, pyrroles, and furans; 2 and 2, 4-[(alpha hydroxyalpha, alpha dipolyperhalo hydrocarbon) methyl]-thiophenes, pyrroles and furans and process for making them
FR2624126B1 (fr) * 1987-12-07 1992-06-19 Solvay Polymeres conducteurs derives d'heterocycles aromatiques substitues par un groupement de type ether, procede pour leur obtention et dispositifs contenant ces polymeres

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100580620B1 (ko) * 2002-03-09 2006-05-16 삼성전자주식회사 신규한 전도성 고분자, 이를 이용한 센서 및 표적 물질검출 방법

Also Published As

Publication number Publication date
JPH03103428A (ja) 1991-04-30
ATE116981T1 (de) 1995-01-15
FR2649396B1 (fr) 1994-07-29
FR2649396A1 (fr) 1991-01-11
DE69015906T2 (de) 1995-06-22
EP0408105B1 (fr) 1995-01-11
DE69015906D1 (de) 1995-02-23
JP2892784B2 (ja) 1999-05-17
EP0408105A1 (fr) 1991-01-16

Similar Documents

Publication Publication Date Title
CA2080047C (en) Solid electrolyte
KR910002832A (ko) 플루오르화 티오펜, 이들 티오펜에서 유도된 전도성 중합체, 이들의 제조방법과 이들 중 합체를 함유하는 장치
JP3223978B2 (ja) ポリエーテル共重合体および高分子固体電解質
KR890009998A (ko) 에테르형기에 의하여 치환된 방향족 헤테로 고리 화합물에서 유도한 전도성 중합체 및 이의 제조 방법, 이 중합체를 함유하는 장치와 이러한 중합체를 얻을 수 있는 단량체
JP3301378B2 (ja) ポリエーテル共重合体および架橋高分子固体電解質
Watanabe et al. Effect of molecular weight of polymeric solvent on ion conductive behavior in poly (propylene oxide) solution of LiClO4
US6727024B2 (en) Polyalkylene oxide polymer composition for solid polymer electrolytes
KR880701254A (ko) 자기도우프성 중합체
KR870010566A (ko) 3- 알킬티오펜에서 유도된 전도성 중합체 및 이의 제조방법과 이를 함유하는 전기 전도성 장치
GB9125840D0 (en) Solid electrolytes
JPH05198303A (ja) 電 池
JP3234638B2 (ja) フッ素化チオフェン、これらのチオフェンから誘導されたポリマー及びこれらのポリマーを含む導電性ポリマー
JP3282565B2 (ja) 架橋高分子固体電解質及びその用途
KR910008176A (ko) 이온 도전성 중합체 전해질
US5433877A (en) Ion-conductive polymer electrolyte
Naitoh et al. Electrochemical synthesis of a copolymer of thiophene and pyrrole: poly (thienylpyrrole)
KR101720049B1 (ko) 탄닌산 유도체로 가교된 고분자를 포함하는 리튬 이차전지용 고체상 고분자 전해질
US5501921A (en) Fabrication of alkane polymer electrolyte
US4835076A (en) Electrically conductive polymer films
DE3510031A1 (de) Verfahren zur herstellung von elektrisch leitfaehigen schaumstoffen
EP0638950B1 (en) Process for preparing a solid, polymeric electrolyte based on polyvinyl ethers
DE3410494A1 (de) Verfahren zur herstellung von polypyrrol-pfropfpolymerisaten
US6299790B1 (en) Electric double layer capacitor
US5552510A (en) Oxirane and dioxolane copolymers, process for their preparation and ionic conduction materials containing same
Roncali et al. Recent developments in the synthesis and functionalization of conducting poly (thiophenes)

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid