KR880011252A - Epdm 및/또는 epr-실리콘 조성물 - Google Patents

Epdm 및/또는 epr-실리콘 조성물 Download PDF

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KR880011252A
KR880011252A KR1019880003535A KR880003535A KR880011252A KR 880011252 A KR880011252 A KR 880011252A KR 1019880003535 A KR1019880003535 A KR 1019880003535A KR 880003535 A KR880003535 A KR 880003535A KR 880011252 A KR880011252 A KR 880011252A
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parts
radicals
methyl
composition
phenyl
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르므완느 기
뤼까 로베
소리아 메이에
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롱 쁠랑 쉬미
원본미기재
프랑스공화국 드 라피나쥬 에 드 디스트리비시옹 토탈 프랑스
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    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
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    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
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    • C08G77/04—Polysiloxanes
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Abstract

내용없음

Description

EPDM 및/또는 EPR-실리콘 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. (A) (A1) 에틸렌-프로필렌-디엔터폴리더 및 에틸렌-프로필렌 공중합체 중에서 선택된 중합체 95 내지 30부, 및 (A2) 25℃에서 106mPa 이상의 점도를 갖는 디오가노폴리실옥산수지 5 내지 70부의 혼합물 100부.
    (B) 하기 일반식(Ⅰ)의 화합물 0.5 내지 10부,
    (C) 2급 아민 작용기를 함유한 방향족 화합물 0.1내지 10부,
    (D) 무기 충전재 6 내지 200부,
    (E) 유기 라디칼이 메틸, 비닐, 페닐 및 3,3,3-트리플루오로프로필 라디칼 중에서 선택되고 그 유기 라다칼의 50몰％이상의 메틸 라디칼이며, 25℃에서 10 내지 5000mmPa의 점도를 갖는 디오가노폴리실옥산오일 0.1 내지 30부 및
    (F) 유기 과산화물 0.1 내지 7부를 함유하는 고무 조성물.
    상기식에서, b는 0 또는 1이고, x는 금속 양이온 및 수소원자 중에서 선택되며, f는 1 내지 3의 정수고 양이온에 의해 제공된 양전하의 수와 동일하며, x가 수소원자인 경우 f는 1이다.
  2. 제1항에 있어서, (C)가 적어도 부분적으로 중합된 2,2,4-트리메틸-1,2-디하이드로-퀴놀린 및 파라-페닐렌디아민 중에서 선택됨을 특징으로 하는 조성물.
  3. 제1항에 있어서, 성분 (B)의 일반식(1)에서의 x가 아연이고 f가 2임을 특징으로 하는 조성물.
  4. 제1 내지 3항 중 어느 한 항에 있어서, 오일(E)가 하기 일반식에 상응함을 특징으로 하는 조성물.
    R3 3.5(HO)gSIO(R3 2SIO)mSI(OH)gR3 3.g
    상기식에서, 라디칼 R은 동일하거나 상이할 수 있으며, 메틸, 비닐, 페닐 및 3,3,3-트리플루오로플로필 라디칼 중에서 선택되고, g는 0 또는 1이며, m은 중합체(E)에 10 내지 5000mPa(25℃)의 점도를 제공하기에 충분한 값을 갖는 정수이다.
  5. 제4항에 있어서, 라디칼 R이 메틸 및 페닐 라디칼중에서 선택됨을 특징으로 하는 조성물.
  6. 제1 내지 5항중 어느 한 항에 있어서, 혼합물(A) 100부에 대해 하기 일반식(4)의 실란(G) 0.05 내지 5부, 바람직하게는 0.1 내지 2부를 추가로 함유함을 특징으로 하는 조성물.
    (CH2=CH)SI(CH3)c(X)3-C
    상기식에서, X는 메톡시, 에톡시, 2-메톡시에톡시 및 2 에톡시에톡시 라디칼 중에서 선택되며, c는 1 또는 0이다.
  7. 제1 내지 6항중 어느 한 항에 있어서 혼합물(A) 100부에 대해 하기 일반식(5)의 실란(H) 0.05 내지 5부, 바람직하게는 0.1 내지 2부를 추가로 함유함을 특징으로 하는 조성물
    CH2=C(R4)COO(CH2)dSi(Y)e(X)3-e
    상기식에서, R4는 H 또는 메틸이고, d는 1내지 5의 정수이며, Y는 메틸 또는 페닐이고, X는 메톡시, 에톡시, 2-메톡시에톡시 및 2-에톡시에톡시 라디칼 중에서 선택되며, e는 1 또는 0이다.
  8. 제1 내지 7항증 어느 한 항에 있어서, 충전제(D)가 연소 및 침강 실리카중에서 선택됨을 특징으로 하는 조성물.
  9. 한편으로 (A1)과 1부 1이상의 (D)를 혼합하여 제1의 마스터뱃치(masterbatch)를 다른 한편으로는 (A2), 나머지 충전제(D),(E) 및 , 경우에 따라 (G) 및 (H)를 혼합하여 제2의 마스터뱃치를 각각 별도로 제조한 다음, (B) 및 (C)를 가하고 최종적으로 (F)를 가하면서 상기 두 마스터뱃치를 균질화시켜, 제1 내지 8항 중 어느 한 항에 정의된 조성물을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880003535A 1987-03-30 1988-03-30 Epdm 및 또는 epr-실리콘 조성물 KR920001592B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8704591A FR2613374B1 (fr) 1987-03-30 1987-03-30 Compositions de caoutchouc epdm et/ou epr et de silicones
FR87/04591 1987-03-30

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KR880011252A true KR880011252A (ko) 1988-10-27
KR920001592B1 KR920001592B1 (ko) 1992-02-20

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US (1) US4808643A (ko)
EP (1) EP0286551B1 (ko)
JP (1) JPS63304040A (ko)
KR (1) KR920001592B1 (ko)
AT (1) ATE63933T1 (ko)
AU (1) AU607980B2 (ko)
BR (1) BR8801407A (ko)
CA (1) CA1301982C (ko)
DE (1) DE3862987D1 (ko)
ES (1) ES2021865B3 (ko)
FR (1) FR2613374B1 (ko)
GR (1) GR3002345T3 (ko)

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KR102103953B1 (ko) * 2019-04-09 2020-04-23 한국신발피혁연구원 내열성과 영구압축줄음율이 우수한 epdm 고무 조성물

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AU1379188A (en) 1988-09-29
ES2021865B3 (es) 1991-11-16
KR920001592B1 (ko) 1992-02-20
EP0286551A1 (fr) 1988-10-12
FR2613374B1 (fr) 1989-08-18
BR8801407A (pt) 1988-11-01
FR2613374A1 (fr) 1988-10-07
CA1301982C (fr) 1992-05-26
US4808643A (en) 1989-02-28
ATE63933T1 (de) 1991-06-15
GR3002345T3 (en) 1992-12-30
JPS63304040A (ja) 1988-12-12
DE3862987D1 (de) 1991-07-04
EP0286551B1 (fr) 1991-05-29
AU607980B2 (en) 1991-03-21

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