KR880004129A - 유기 금속 화합물 - Google Patents
유기 금속 화합물 Download PDFInfo
- Publication number
- KR880004129A KR880004129A KR870010130A KR870010130A KR880004129A KR 880004129 A KR880004129 A KR 880004129A KR 870010130 A KR870010130 A KR 870010130A KR 870010130 A KR870010130 A KR 870010130A KR 880004129 A KR880004129 A KR 880004129A
- Authority
- KR
- South Korea
- Prior art keywords
- organometallic compound
- group
- compound
- carbon atoms
- substrate
- Prior art date
Links
- 150000002902 organometallic compounds Chemical class 0.000 title claims 5
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 238000000151 deposition Methods 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- 125000002373 5 membered heterocyclic group Chemical group 0.000 claims 1
- 125000004070 6 membered heterocyclic group Chemical group 0.000 claims 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical group [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 claims 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 1
- 229910052785 arsenic Inorganic materials 0.000 claims 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims 1
- 125000000392 cycloalkenyl group Chemical group 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 230000008021 deposition Effects 0.000 claims 1
- 238000005137 deposition process Methods 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 229910052733 gallium Chemical group 0.000 claims 1
- 125000005842 heteroatom Chemical group 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical group [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 150000003018 phosphorus compounds Chemical class 0.000 claims 1
- 239000004065 semiconductor Substances 0.000 claims 1
- 239000010409 thin film Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B25/00—Single-crystal growth by chemical reaction of reactive gases, e.g. chemical vapour-deposition growth
- C30B25/02—Epitaxial-layer growth
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
- C23C16/18—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material from metallo-organic compounds
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/02—Elements
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/40—AIIIBV compounds wherein A is B, Al, Ga, In or Tl and B is N, P, As, Sb or Bi
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Vapour Deposition (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (4)
- 금속을 기재상에 가스상 증착시키는데 있어서의 일반식(Ⅰ)의 유기금속 화합물의 용도.상기식에서, M은 알루미늄, 인듐 또는 갈륨이고, X는 -(CHR5)n-(여기에서 n은 2,3,4 또는 5), -2-C6H4-(CH2)m-, -(CH2)m-2-C6H4-2-C6H10-(CH2)m-, -(CH2)m-2-C6H16-(여기에서 m은 1 또는 2)이고, R5는 각기 H 또는 탄소수 1 내지 4의 알킬기이고, Y는 5족의 헤테로원자를 갖는 5- 또는 6-원 헤테로시클릭고리 또는 -NR3R4, -PR3R4, -AsR3R4또는 -SbR3R4이고, R1, R2, R3및 R4는 각기 서로 독립하여 H, 일부 또는 전부가 플루오로화 될 수 있는 직쇄 또는 분지된 알킬기, 각기 탄소수 3 내지 8의 시클로알킬, 알케닐 또는 시클로알케닐기 또는 비치환 또는 치환된 페닐기이다.
- 적층을 증착하는데 있어서의 특허청구의 범위 제1항에 따른 유기금속 화합물의 용도.
- 유기금속 화합물로부터 금속을 가스상 증착하여 기재상에 박막을 형성시키는 방법에 있어서, 유기 금속 화합물로서 일반식(Ⅰ)의 화합물을 사용함을 특징으로 하는 방법.여기에서 R1, R2, M, X 및 Y는 특허청구의 범위 제1항에서 정의한 바와 같다.
- 제3항에 있어서, 반도체 화합물이 생성되도록 적용한 반응조건하에서 가스상태의 하나 또는 그 이상의 비소, 안티몬 또는 인 화합물을 증착공정 동안에 공급하는 것을 특징으로 하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19863631469 DE3631469A1 (de) | 1986-09-16 | 1986-09-16 | Metallorganische verbindungen |
DE3631469.2 | 1986-09-16 | ||
DEP3631469.2 | 1986-09-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR880004129A true KR880004129A (ko) | 1988-06-01 |
KR950001217B1 KR950001217B1 (ko) | 1995-02-14 |
Family
ID=6309677
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019870010130A KR950001217B1 (ko) | 1986-09-16 | 1987-09-12 | 박막형성방법 |
Country Status (6)
Country | Link |
---|---|
US (2) | US4880492A (ko) |
EP (1) | EP0260534B1 (ko) |
JP (1) | JP2579169B2 (ko) |
KR (1) | KR950001217B1 (ko) |
DD (1) | DD264029A5 (ko) |
DE (2) | DE3631469A1 (ko) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3631469A1 (de) * | 1986-09-16 | 1988-03-17 | Merck Patent Gmbh | Metallorganische verbindungen |
DE3726485A1 (de) * | 1987-08-08 | 1989-02-16 | Merck Patent Gmbh | Metallorganische verbindungen |
US5156884A (en) * | 1987-10-23 | 1992-10-20 | Tokyo Ohka Kogyo Co., Ltd. | Method for forming a film of oxidized metal |
DE3817090A1 (de) * | 1988-05-19 | 1989-11-30 | Merck Patent Gmbh | Cyclische metallorganische verbindungen |
DE3841643C2 (de) * | 1988-12-10 | 1999-07-01 | Merck Patent Gmbh | Metallorganische Verbindungen und deren Verwendung |
DE3913165C2 (de) * | 1989-04-21 | 2000-05-18 | Merck Patent Gmbh | Metallorganische Verbindungen sowie deren Verwendung zur Herstellung dünner Schichten |
US5089643A (en) * | 1990-06-08 | 1992-02-18 | The United States Of America As Represented By The Secretary Of The Navy | Method of preparing monomeric organometallic compounds |
US5075466A (en) * | 1990-06-08 | 1991-12-24 | The United States Of America As Represented By The Secretary Of The Navy | Method of monomeric organometallic compounds |
US5171610A (en) * | 1990-08-28 | 1992-12-15 | The Regents Of The University Of Calif. | Low temperature photochemical vapor deposition of alloy and mixed metal oxide films |
DE4293092D2 (de) * | 1991-10-09 | 1994-10-20 | Aixtron Gmbh | Verfahren zum Beschichten von Substraten |
GB9315771D0 (en) * | 1993-07-30 | 1993-09-15 | Epichem Ltd | Method of depositing thin metal films |
US6130160A (en) * | 1996-10-02 | 2000-10-10 | Micron Technology, Inc. | Methods, complexes and system for forming metal-containing films |
US5924012A (en) | 1996-10-02 | 1999-07-13 | Micron Technology, Inc. | Methods, complexes, and system for forming metal-containing films |
KR100266965B1 (ko) * | 1997-12-02 | 2000-09-15 | 김충섭 | 리튬과 13 족 금속의 알킬산알킬헤테로금속 화합물을 사용한 리튬과 13 족 금속의 복합 산화물의 제조방법 |
US6214729B1 (en) * | 1998-09-01 | 2001-04-10 | Micron Technology, Inc. | Metal complexes with chelating C-, N-donor ligands for forming metal-containing films |
US6281124B1 (en) | 1998-09-02 | 2001-08-28 | Micron Technology, Inc. | Methods and systems for forming metal-containing films on substrates |
GB9919071D0 (en) | 1999-08-12 | 1999-10-13 | Isis Innovation | Deposition compounds |
US7309359B2 (en) * | 2003-08-21 | 2007-12-18 | Warsaw Orthopedic, Inc. | Allogenic/xenogenic implants and methods for augmenting or repairing intervertebral discs |
WO2004026190A2 (en) * | 2002-09-18 | 2004-04-01 | Sdgi Holdings, Inc. | Natural tissue devices and methods of implantation |
US20040054414A1 (en) * | 2002-09-18 | 2004-03-18 | Trieu Hai H. | Collagen-based materials and methods for augmenting intervertebral discs |
US7744651B2 (en) | 2002-09-18 | 2010-06-29 | Warsaw Orthopedic, Inc | Compositions and methods for treating intervertebral discs with collagen-based materials |
JP2006515765A (ja) | 2002-11-15 | 2006-06-08 | エスディージーアイ・ホールディングス・インコーポレーテッド | 滑膜性関節を治療するためのコラーゲンベース材料および方法 |
US8118779B2 (en) | 2006-06-30 | 2012-02-21 | Warsaw Orthopedic, Inc. | Collagen delivery device |
US8399619B2 (en) | 2006-06-30 | 2013-03-19 | Warsaw Orthopedic, Inc. | Injectable collagen material |
KR20130087354A (ko) * | 2012-01-27 | 2013-08-06 | 주식회사 유피케미칼 | 인듐을 포함한 산화막 및 이의 제조 방법 |
JP6541657B2 (ja) * | 2013-08-22 | 2019-07-10 | ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフトUmicore AG & Co.KG | アルキルインジウム化合物の製造方法及びその使用 |
WO2016108398A1 (ko) * | 2014-12-31 | 2016-07-07 | 주식회사 유진테크 머티리얼즈 | 유기 13족 전구체 및 이를 이용한 박막 증착 방법 |
JPWO2022190877A1 (ko) * | 2021-03-08 | 2022-09-15 | ||
WO2024107593A1 (en) | 2022-11-18 | 2024-05-23 | Merck Patent Gmbh | Intramolecular stabilized group 13 metal complexes with improved thermal stability for vapor phase thin-film deposition techniques |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3154828A (en) * | 1961-07-13 | 1964-11-03 | Accurate Wire Forming Inc | Crate fastener |
FR2403646A1 (fr) * | 1977-09-16 | 1979-04-13 | Anvar | Procede de realisation d'un depot de compose semi-conducteur d'elements iii et v |
US4171235A (en) * | 1977-12-27 | 1979-10-16 | Hughes Aircraft Company | Process for fabricating heterojunction structures utilizing a double chamber vacuum deposition system |
US4247359A (en) * | 1978-10-30 | 1981-01-27 | Honeywell Inc. | Preparation of epitaxial rare earth thin films |
DE3133871A1 (de) * | 1981-08-27 | 1983-03-10 | M.A.N. Maschinenfabrik Augsburg-Nürnberg AG, 8000 München | Verfahren zur herstellung homogener beschichtungen aus zwei oder mehreren metallen und/oder metallverbindungen |
GB2117775A (en) * | 1981-11-25 | 1983-10-19 | Secr Defence | Organometallic adducts and their use in the preparation of compound semiconductor materials |
DE3366927D1 (en) * | 1982-08-13 | 1986-11-20 | Secr Defence Brit | Preparation of organometallic indium and gallium compounds |
EP0106537B1 (en) * | 1982-10-19 | 1989-01-25 | The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and | Organometallic chemical vapour deposition of films |
EP0117051B2 (en) * | 1983-01-19 | 1995-02-08 | BRITISH TELECOMMUNICATIONS public limited company | Growth of semiconductors |
US4588451A (en) * | 1984-04-27 | 1986-05-13 | Advanced Energy Fund Limited Partnership | Metal organic chemical vapor deposition of 111-v compounds on silicon |
US4734514A (en) * | 1984-10-25 | 1988-03-29 | Morton Thiokol, Inc. | Hydrocarbon-substituted analogs of phosphine and arsine, particularly for metal organic chemical vapor deposition |
US4594264A (en) * | 1984-11-20 | 1986-06-10 | Hughes Aircraft Company | Method for forming gallium arsenide from thin solid films of gallium-arsenic complexes |
JPS6217099A (ja) * | 1985-07-16 | 1987-01-26 | Kokusai Denshin Denwa Co Ltd <Kdd> | ビスマス含有酸化物単結晶の製造方法 |
DE3631469A1 (de) * | 1986-09-16 | 1988-03-17 | Merck Patent Gmbh | Metallorganische verbindungen |
US4833103A (en) * | 1987-06-16 | 1989-05-23 | Eastman Kodak Company | Process for depositing a III-V compound layer on a substrate |
US4792467A (en) * | 1987-08-17 | 1988-12-20 | Morton Thiokol, Inc. | Method for vapor phase deposition of gallium nitride film |
US4879397A (en) * | 1987-11-03 | 1989-11-07 | Cornell Research Foundation, Inc. | Novel gallium arsenide precursor and low temperature method of preparing gallium arsenide therefrom |
US4904616A (en) * | 1988-07-25 | 1990-02-27 | Air Products And Chemicals, Inc. | Method of depositing arsine, antimony and phosphine substitutes |
US4975299A (en) * | 1989-11-02 | 1990-12-04 | Eastman Kodak Company | Vapor deposition process for depositing an organo-metallic compound layer on a substrate |
-
1986
- 1986-09-16 DE DE19863631469 patent/DE3631469A1/de not_active Withdrawn
-
1987
- 1987-09-03 EP EP87112843A patent/EP0260534B1/de not_active Expired - Lifetime
- 1987-09-03 DE DE8787112843T patent/DE3775311D1/de not_active Expired - Fee Related
- 1987-09-12 KR KR1019870010130A patent/KR950001217B1/ko not_active IP Right Cessation
- 1987-09-14 DD DD87306951A patent/DD264029A5/de not_active IP Right Cessation
- 1987-09-15 US US07/096,583 patent/US4880492A/en not_active Expired - Lifetime
- 1987-09-16 JP JP62229965A patent/JP2579169B2/ja not_active Expired - Fee Related
-
1989
- 1989-08-03 US US07/389,197 patent/US5112432A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US5112432A (en) | 1992-05-12 |
DE3631469A1 (de) | 1988-03-17 |
JPS6383092A (ja) | 1988-04-13 |
EP0260534B1 (de) | 1991-12-18 |
DD264029A5 (de) | 1989-01-18 |
DE3775311D1 (de) | 1992-01-30 |
US4880492A (en) | 1989-11-14 |
KR950001217B1 (ko) | 1995-02-14 |
JP2579169B2 (ja) | 1997-02-05 |
EP0260534A1 (de) | 1988-03-23 |
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