KR870008920A - 계면 활성 폴리카보디이미드 및 그의 분산액 - Google Patents

계면 활성 폴리카보디이미드 및 그의 분산액 Download PDF

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KR870008920A
KR870008920A KR870003149A KR870003149A KR870008920A KR 870008920 A KR870008920 A KR 870008920A KR 870003149 A KR870003149 A KR 870003149A KR 870003149 A KR870003149 A KR 870003149A KR 870008920 A KR870008920 A KR 870008920A
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polycarbodiimide
residue
surfactant
carbodiimide
alkylene oxide
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웨인 테일러 제임스
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티모시 엔. 비숍
유니온 카바이드 코포레이션
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Abstract

내용 없음

Description

계면 활성폴리가보이디미드 및 그의 분산액
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 카보디이미드를 제조하는 반응과정을 나타내는 반응도식이다.

Claims (22)

  1. 하기 일반식의 계면 활성 폴리카보디이미드.
    R-X-R′
    상기 식에서,
    R은 2개 이상의 카보디이미드 그룹을 함유하는 소수성 유기 화합물의 잔기이고 ;R'는 친구성 부분 및 카보디이미드 그룹과 반응할 수 있는 하나 이상의 작용성 그룹을 갖는 유기화합물의 잔기이며;
    X는 상기 카보디이미드 그룹과 상기 작용성 그룹과의 반응에 의해 형성되는 그룹이다.
  2. 제1항에 있어서, X가 우레티딘은, 디아제티딘 티은, N-아실 우레아, 구아니딘, 이소우레아, 이소티오우레아 및 카보디이미드로 이루어진 그룹중에서 선택된 게면 활성 폴리카보디이미드.
  3. 제1항에 있어서, R′가 하이드록실-함유 폴리(알킬렌 옥사이드)-기본 게면활성제의 잔기인 계면활성 폴리카보디이미드.
  4. 제3항에 있어서, 폴리(알킬렌 옥사이드)-기본 계면활성제가 알콕시-말단화된 계면 활성 폴리카보디이미드.
  5. 제4항에 있어서, 폴리(알킬렌 옥사이드)-기본 계면활성제가 메톡 시폴리에틸렌 글리콜인 계면 활성 폴리카보디이미드.
  6. 제4항에 있어서, 알킬렌 옥사이드 반복 단위의 수(n)가 약 15 내지 약 120인 계면 활성 폴리카보디이미드.
  7. 제1항에 있어서, R이 단일 분산 측쇄 폴리카보디이미드의 잔기인 계면 활성 폴리카보디이미드.
  8. 제7항에 있어서, 단일 분산 측쇄 폴리카보디이미드가 하기 일반식을 갖는 계면 활성 폴리카보디이미드.
    M-[(R″dN(N-R)n]-m-[(R″dN(N-R′)p-Q]q
    상기 식에서,
    M 및Q는 동일하거나 상이할 수 있으며, 각기 측쇄를 형성시키기 위한 부위로서, 작용하는 화합물의 잔기를 나타내고 ;
    R 및 R′는 동일하거나 상이할 수 있으며, 알킬(사이클로알킬 포함) 또는 아릴 ;
    시아노, 니트로, 할로, 알킬 설피이드, 디알-킬아미노알킬, 치환된 실란, 알콕시 및 아릴옥시 잔기일 수 있거나 이들을 함유하는 라디칼 또는 디라디칼 및 기타 치환된 상기 그룹들이고 ;
    R″는 시아노, 니트로, 할로, 알킬설차이드, 이알킬아미조, 치환된 실란, 알콕시 및 아릴옥시 잔기를 함유할 수 있는 동일하거나 상이한 알킬(사이클로알킬 포함) 또는 아릴 디라디칼 및 기타 치환된 상기 그룹들이며 ;
    d는 0 내지 약 12이고;
    n는 0 내지 약 6이며;
    m은 3 내지 약 5이고;
    p는 1내지 약 6이며;
    q는 0 내지 약 4이다.
  9. 제8항에 있어서, 단일분산 측쇄 폴리카보디이미드가 하기 일반식을 갖는 계면 활성 폴리카보디이미드.
    상기 식에서,
    R1,R2,R3, 및 R4는 동일하거나 상이할 수 있으며, 다직용성 카보디이미드를 의도된 목적으로 거의 방해 하지 않는 유기 잔기를 나타내고 ;
    D는 유기 잔기이며 ;
    r, s, t, x 및 y는 1 내지 약 6이다.
  10. 제8항에 있어서, 단일분산 측쇄 폴리카보디이미드가 하기 일반식을 갖는 계면 활성 폴리카보디이미드.
    상기 식에서,
    R1,R2, 및 R4는 동일하거나 상이할 수 잇으며, 탄소수 1내진 약 12의 알킬 그룹이고;
    R5및 R6는 동일하거나 상이 할 수 있으며, 수소, 알킬(사이클로알킬 포함, 아릴, 아르알킬,알크아릴,헤테로사이클릭, 시아노, 니트로, 할로, 알킬 설파이드, 디알킬아미노알킬, 실랄,아콕시, 실랄, 알콕시 아릴옥시그룹 및 치화된 상기 그룹들이며;
    Z는 측쇄를 형성하기 위한 부위로서 작용하는 화합물의 잔기이고;
    a,b,및c는 0내지 약 12이다.
  11. 제8항에 있어서, 단일분산, 측쇄 폴리카보디이미드가 1,3,6-트리-(N-이소프로필-N′-메틸렌카보디이미드)헥산인 계면 활성 폴리카보디이미드.
  12. 제8항에 있어서, 단일분산, 측쇄 콜리카보디이미드가 1,3,6-트리-(N-사이클로헥실-N′-메틸렌카보디이미드)헥산인 계면 활성 폴리 카보디이미드.
  13. 제8항에 있어서, 단일분산,측쇄 콜리카보디이미드가 1,3,6-트리-(N-n-부틸-N′-메틸렌카보디이미드)헥산인 계면 활성 폴리 카보디이미드.
  14. 제1항에 있어서, R이 다중분산, 선형 폴리카보디이미드의 잔기인 계면 활성 폴리카보디이미드.
  15. 제14항에 있어서, R이 모노-, 디- 및 트리-지환족 또는 포화 지방족 이소시아네이트 [여기에서 지환족 잔기는 5내지 약 7개의 탄소원자를 함유하며 탄소수 1낸지 약 6의 알킬, 또는 산소에 의해 치환 될 수 잇고, 포화 지방족 잔기는 1내지 약 18개의 탄소원자를 함유하며 모노-및트리이소시아네이트는
    임의적이다[의 반응으로부터 유도된 다가 PCDI의 잔기인 계면 활성 폴리카보디이미드.
  16. 수성 매질 중의 (a) 소수성 폴리카보디이미드 및 b) 일반식 R-X-R′ (여기에서, R은 적어도 2개의 카보디이미드 그룹을 함유하는 소수성 유기 화합물의 잔기이고, R′는 카보디이미드 그룹과 반응할 수 있는 작용성 그룹 적어도 하나와 소수성 부위를 갖는 유기 화합물의 잔기이며, X는 상기 카보디이미드 그룹과 상기 작용성 그룹과의 반응에 의해 형성된 그룹이다)의 계면 활성 폴리카보디임드의 혼합물을 함유하는 에멀젼
  17. 제16항에 있어서, X는가 우레티디논, 디아제티딘 티온, N- 아실우레아, 구아니딘, 이소우레아, 이소티오우레아, 및 카보디이미드로 이루어진 그룹중에서 선택된 에멀젼.
  18. 제16항에 있어서, R′가 하이드록실- 함유 폴리(알킬렌옥사이드)-기본 계면활성제인 에멀젼.
  19. 제18항에 있어서, 폴리(알킬렌 옥사이드)-기본 계면활성제가 알콕시에 의해 말단화된 에멀젼.
  20. 제19항에 있어서, 폴리(알킬렌 옥사이드)-기본 계면활성제가 메톡 시폴리에틸렌글리콜인 에멀젼.
  21. 제19항에 있어서, 알킬렌 옥사이드 반복단위의 수(n)가 약 15내지 약 120인 에멀젼.
  22. 제16항에 있어서, R이 단일분산, 측쇄 폴리카보디이미드인 에멀젼.
    ※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR870003149A 1986-03-31 1987-03-31 계면 활성 폴리카보디이미드 및 그의 분산액 KR870008920A (ko)

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US06/845,982 US4820863A (en) 1986-03-31 1986-03-31 Surface active polycarbodiimides

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US4820863A (en) 1989-04-11
AU591764B2 (en) 1989-12-14
DK162487A (da) 1987-10-01
FI871414A0 (fi) 1987-03-31
SG94891G (en) 1992-01-17
ATE59839T1 (de) 1991-01-15
EP0241805A3 (en) 1988-07-06
NO871341D0 (no) 1987-03-31
EP0241805A2 (en) 1987-10-21
US5081173A (en) 1992-01-14
JPS63264128A (ja) 1988-11-01
US5047588A (en) 1991-09-10
EP0241805B1 (en) 1991-01-09
DK162487D0 (da) 1987-03-31
AU7079687A (en) 1987-10-08
DE3767199D1 (de) 1991-02-14
NO871341L (no) 1987-10-01
ES2020215B3 (es) 1991-08-01
BR8701461A (pt) 1988-01-05
FI871414A (fi) 1987-10-01
JPH0527450B2 (ko) 1993-04-21

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