KR870007334A - 세라믹 미소구를 함유하는 도로표지 - Google Patents

세라믹 미소구를 함유하는 도로표지 Download PDF

Info

Publication number
KR870007334A
KR870007334A KR870000160A KR870000160A KR870007334A KR 870007334 A KR870007334 A KR 870007334A KR 870000160 A KR870000160 A KR 870000160A KR 870000160 A KR870000160 A KR 870000160A KR 870007334 A KR870007334 A KR 870007334A
Authority
KR
South Korea
Prior art keywords
ceramic microspheres
pavement
microspheres
particle size
transparent
Prior art date
Application number
KR870000160A
Other languages
English (en)
Other versions
KR940002037B1 (ko
Inventor
로져웨인렌지
Original Assignee
도날드밀러셀
미네소타마이닝 앤드 매뉴팩츄어링 컴패니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 도날드밀러셀, 미네소타마이닝 앤드 매뉴팩츄어링 컴패니 filed Critical 도날드밀러셀
Publication of KR870007334A publication Critical patent/KR870007334A/ko
Application granted granted Critical
Publication of KR940002037B1 publication Critical patent/KR940002037B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/16—Solid spheres
    • C08K7/18—Solid spheres inorganic
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/30—Oxides other than silica
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
    • E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
    • E01F9/50—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
    • E01F9/506—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users characterised by the road surface marking material, e.g. comprising additives for improving friction or reflectivity; Methods of forming, installing or applying markings in, on or to road surfaces
    • E01F9/524—Reflecting elements specially adapted for incorporation in or application to road surface markings
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
    • E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
    • E01F9/50—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
    • E01F9/576—Traffic lines
    • E01F9/578—Traffic lines consisting of preformed elements, e.g. tapes, block-type elements specially designed or arranged to make up a traffic line
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/259—Silicic material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Architecture (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Road Signs Or Road Markings (AREA)
  • Road Paving Structures (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Silicon Compounds (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

내용 없음

Description

세라믹 미소구를 함유하는 도로표지
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
세라믹 미소구의 표면층을 갖는 무늬진 중합성 시이트로 구성된 본 발명의 포장도로 표지의 횡-단면도.

Claims (14)

  1. 이산화티타늄이 소량 존재하기는 하지만 티타늄이 아닌 최소한 하나의 금속 산화물로 구성되었으며 평균 입자크기가 125마이크로미터까지인 최소한 하나의 결정체상으로 구성된 고체이며 투명하고 비-유리질인 세라믹 미소구와 이를 지지하는 결합제로 구성된 포장도로 표지.
  2. 제1항에 있어서, 그외의 미소구의 입자기가 125마이크로 미터이상인 것을 제외하고는 세라믹 미소구에 대한 서술과 똑같으며 세라믹 미소구사이에 그외의 미소구가 혼합되어 있는 포장도로 표지.
  3. 제1항에 있어서, 세라믹 미소구의 입자크기가 1000옹스트롬보다 크지 않는 포장도로 표지.
  4. 제1항에 있어서, 세라믹 미소구가 최소한 하나의 폴리 결정체와 최소한 하나의 무정형상으로 구성된 포장도로 표지.
  5. 제4항에 있어서, 무정형상이 실리카로 구성된 포장도로 표지.
  6. 제5항에 있어서, 폴리결정체상이 질코니아로 구성된 포장도로 표지.
  7. 제6항에 있어서, 질코니아가 주로 정방형결정구조인 포장도로 표지.
  8. 제1항에 있어서, 결합제가 페인트와 열가소성 수지에서 선택된 포장도로 표지.
  9. 제1항에 있어서, 결합제가 결합제의 바디와 노출된 시이트 표면 모두에 세라믹 미소구를 함유하는 열가소성 수지인 포장도로 표지.
  10. 제1항에 있어서,
    A. 알루미늄 포일과 중합성 시이트 물질로 구성된 군에서 선택된 베이스 시이트 ;
    B. 베이스 시이트의 한면에 접착된 결합층 ;
    C. 결합층에 투명한 세라믹 미소구의 최소한일부가 내장된 층으로 구성된 사이트 물질로 구성된 포장도로 표지.
  11. 제1항에 있어서,
    i) 다수의 돌출부를 갖는 점탄성, 중합성 베이스 시이트 ;
    ii) 돌출부의 돌출된 표면에 지지되며 그 위에 위치한 다수의 투명한 세라믹 미소구로 구성된 시이트 물질인 포장도로 표지.
  12. 충분히 농밀하며 평균 입자 크기가 125마이크로미터까지이고 실질적으로 실리카로 구성된, 고체이며 투명하고 비-유리질인 미소구와 이를 지지하는 결합제로 구성된 포장도로 표지.
  13. 이산화 티타늄이 소량존재하기는 하지만 티타늄이 아닌 최소한 하나의 금속 산화물로 구성되었으며 평균 입자 크기가 125마이크로 미터까지인 최소한 하나의 결정체상으로 구성된 고체이며 투명하고 비-유리질인 세라믹 미소구와 결합제 물질의 혼합물로 구성된 피복 조성물.
  14. 평균 입자크기가 125마이크로 미터까지인 고체이며 투명하고 비-유리질인 세라믹미소구이며 실질적으로 실리카로 구성된 세라믹 미소구와 결합물질의 혼합물로 구성된 피복 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870000160A 1986-01-13 1987-01-12 세라믹 미소구를 함유하는 도로 표지 KR940002037B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US81820286A 1986-01-13 1986-01-13
US818202 1986-01-13
US818.202 1986-01-13

Publications (2)

Publication Number Publication Date
KR870007334A true KR870007334A (ko) 1987-08-18
KR940002037B1 KR940002037B1 (ko) 1994-03-14

Family

ID=25224944

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019870000160A KR940002037B1 (ko) 1986-01-13 1987-01-12 세라믹 미소구를 함유하는 도로 표지

Country Status (12)

Country Link
US (1) US4758469A (ko)
EP (1) EP0232980B1 (ko)
JP (1) JPH0784726B2 (ko)
KR (1) KR940002037B1 (ko)
CN (1) CN1010959B (ko)
AT (1) ATE66508T1 (ko)
AU (1) AU586300B2 (ko)
BR (1) BR8700017A (ko)
CA (1) CA1308845C (ko)
DE (1) DE3772217D1 (ko)
ES (1) ES2023886B3 (ko)
MX (1) MX160846A (ko)

Families Citing this family (113)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4772511A (en) * 1985-11-22 1988-09-20 Minnesota Mining And Manufacturing Company Transparent non-vitreous zirconia microspheres
US4837069A (en) * 1987-01-07 1989-06-06 Minnesota Mining And Manufacturing Company Transparent alumina microspheres
US4988555A (en) * 1988-06-09 1991-01-29 Minnesota Mining And Manufacturing Company Patterned pavement marking
CA1307971C (en) 1988-06-09 1992-09-29 Thomas Peter Hedblom Patterned pavement marking
US4988541A (en) * 1988-06-09 1991-01-29 Minnesota Mining And Manufacturing Company Process for making retroreflector sheet
US5227221A (en) * 1988-06-09 1993-07-13 Minnesota Mining And Manufacturing Company Patterned skid preventative sheet
US4937127A (en) * 1988-09-07 1990-06-26 Minnesota Mining And Manufacturing Company Skid-resistant pavement markings
US4969713A (en) * 1988-12-12 1990-11-13 Brite Line Corporation Marker strip surface for roadways and the like
US5062993A (en) * 1990-08-29 1991-11-05 Cooper Power Systems, Inc. Process for fabricating doped zinc oxide microsphere gel
US5269972A (en) * 1990-08-29 1993-12-14 Cooper Industries, Inc. Doped zinc oxide microspheres
US5103608A (en) * 1991-02-22 1992-04-14 Balco, Inc. Non-slip luminescent device for surfaces such as stair treads
US5168082A (en) * 1991-08-12 1992-12-01 Nalco Chemical Company Functionalized colloidal silica sol as a ceramics additive
DE69224480T2 (de) * 1991-11-14 1998-08-06 Hemant A Naik Epoxyd- und urethankomponenten enthaltende beschichtungszusammensetzungen und damit beschichtete gegenstände
US5286682A (en) * 1992-02-19 1994-02-15 Minnesota Mining And Manufacturing Company Yellow retroreflective pavement markings
JP3462562B2 (ja) * 1994-04-14 2003-11-05 日本原子力研究所 ゲル粒子製造方法及び装置
US5385770B1 (en) * 1994-05-17 1999-01-19 Jon N Julnes Method for producing detectible warnings on surfaces and products thereof
CA2147711C (en) * 1994-05-20 2005-08-16 James H. C. Harper Retroreflective article with non-continuous top coat
US5750191A (en) * 1994-05-20 1998-05-12 Minnesota Mining And Manufacturing Company Retroreflective elements
US5593246A (en) * 1994-08-26 1997-01-14 Minnesota Mining And Manufacturing Company Patterned chalk-resistant pavement marking and method of making
US5674616A (en) * 1995-02-06 1997-10-07 Conversion Technologies International, Inc. Glass beads having improved fracture toughness
US5576097A (en) * 1995-04-24 1996-11-19 Brite-Line Industries, Inc. High brightness durable retro-reflecting microspheres and method of making the same
US5676488A (en) * 1995-06-29 1997-10-14 Minnesota Mining And Manufacturing Company Pavement marking with multiple topcoats
US5674605A (en) * 1995-09-15 1997-10-07 Minnesota Mining And Manufacturing Company Retroreflective transfer sheet and applique
US5631064A (en) * 1995-09-15 1997-05-20 Minnesota Mining And Manufacturing Company Retroreflective transfer sheet and applique
BE1009847A3 (fr) * 1995-12-29 1997-10-07 Ucb Sa Composition a base de microspheres et de charges.
CA2243999C (en) * 1996-02-05 2006-08-01 Minnesota Mining And Manufacturing Company Durable retroreflective elements
US5822120A (en) * 1996-02-05 1998-10-13 Palazzotto; Michael C. Layered retroreflective elements
US5777791A (en) * 1996-11-26 1998-07-07 Minnesota Mining And Manufacturing Company Wet retroreflective pavement marking articles
WO1998047830A1 (en) 1997-04-18 1998-10-29 Minnesota Mining And Manufacturing Company Transparent beads and their production method
JP3993269B2 (ja) 1997-04-18 2007-10-17 スリーエム カンパニー 透明ビーズおよびその製造方法
US6194486B1 (en) * 1997-05-28 2001-02-27 Trw Inc. Enhanced paint for microwave/millimeter wave radiometric detection applications and method of road marker detection
WO1999004099A1 (en) 1997-07-16 1999-01-28 Minnesota Mining And Manufacturing Company Pavement marking having raised protuberances and method of making
US5941655A (en) * 1997-07-16 1999-08-24 3M Innovative Properties Company Direction-indicating pavement marking having raised protuberances and method of making
US5913539A (en) * 1997-08-12 1999-06-22 William Exline, Inc. Wallet size card book
US5942280A (en) * 1997-09-16 1999-08-24 3M Innovative Properties Company Method of making retroreflective elements
CN1071721C (zh) * 1997-09-18 2001-09-26 中国科学院感光化学研究所 高折射率透明陶瓷微珠及制造方法和用途
US5929160A (en) * 1997-09-25 1999-07-27 Minnesota Mining And Manufacturing Company Method for reducing water uptake in silyl terminated sulfopoly(ester-urethanes)
CA2309976A1 (en) 1997-11-19 1999-05-27 Minnesota Mining And Manufacturing Company Wear resistant pavement marking
US5959775A (en) * 1997-12-23 1999-09-28 3M Innovative Properties Company Urethane/acrylate bead bond for retroreflective articles
JP4225599B2 (ja) * 1998-03-09 2009-02-18 スリーエム カンパニー イメージ表示シートおよびイメージ表示システム
US6089608A (en) * 1998-04-22 2000-07-18 William Exline, Inc. Booklet
US6217252B1 (en) 1998-08-11 2001-04-17 3M Innovative Properties Company Wear-resistant transportation surface marking method and materials
US6350823B1 (en) 1998-10-05 2002-02-26 3M Innovative Properties Company Pavement marking composition
US6107436A (en) * 1998-10-05 2000-08-22 3M Innovative Properties Company Polyfunctional polymer
US6247818B1 (en) 1998-10-20 2001-06-19 3M Innovative Properties Company Method for making retroreflective elements having enhanced retroreflectivity under dry and/or wet conditions
US6365262B1 (en) 1998-10-20 2002-04-02 3M Innovative Properties Company Pavement marking articles having enhanced retroreflectivity under dry or wet conditions and method for making same
JP4530443B2 (ja) * 1999-03-26 2010-08-25 スリーエム カンパニー 路面標示体の製造方法
US6245700B1 (en) 1999-07-27 2001-06-12 3M Innovative Properties Company Transparent microspheres
US6696126B1 (en) 1999-08-12 2004-02-24 The United States Of America As Represented By The Secretary Of The Navy Visual-tactile signage
US6966660B1 (en) 1999-10-15 2005-11-22 3M Innovative Properties Company Article exhibiting dry and wet retroreflectivity
US6735789B2 (en) 2000-07-31 2004-05-18 Southern Mills, Inc. Reflective printing on flame resistant fabrics
US20020110682A1 (en) * 2000-12-12 2002-08-15 Brogan Jeffrey A. Non-skid coating and method of forming the same
US20040191481A1 (en) * 2001-05-31 2004-09-30 Volker Erb Reflective sheet treated with fluorosilane
US6841223B2 (en) 2001-08-14 2005-01-11 3M Innovative Properties Company Composite pavement markings
WO2003020226A2 (en) * 2001-08-31 2003-03-13 L'oreal S.A. Cosmetic compositions comprising nanoparticles and processes for using the same
US7169831B2 (en) 2001-09-27 2007-01-30 3M Innovative Properties Company Pavement marking composition comprising ceramic fibers
US20030123930A1 (en) 2001-12-31 2003-07-03 Jacobs Gregory F. Matrix element magnetic pavement marker and method of making same
US20030123931A1 (en) 2001-12-31 2003-07-03 Khieu Sithya S. Matrix element pavement marker and method of making same
US7036944B2 (en) 2002-04-11 2006-05-02 3M Innovative Properties Company Retrochromic articles
US6978896B2 (en) * 2002-04-11 2005-12-27 3M Innovative Properties Company Method of making retrochromic beads and kit thereof
US20040259713A1 (en) * 2003-06-11 2004-12-23 3M Innovative Properties Company Microspheres comprising titania and bismuth oxide
KR20060126487A (ko) * 2003-11-06 2006-12-07 쓰리엠 이노베이티브 프로퍼티즈 캄파니 결합 수지 코어를 포함하는 재귀반사 요소 및 포장도로마킹
JP2005154672A (ja) * 2003-11-28 2005-06-16 Three M Innovative Properties Co 仮設用マーキング材及び路面標示体
US7247386B2 (en) 2003-12-23 2007-07-24 3M Innovative Properties Company Composition of an oligomeric fluorosilane and surface treatment of retroreflective sheet
EP1700142A1 (en) * 2003-12-30 2006-09-13 3M Innovative Properties Company Color shifting retroreflector and method of making same
EP1709252B1 (en) 2004-01-21 2014-03-26 3M Innovative Properties Company Retroreflective elements and articles
US20050158461A1 (en) * 2004-01-21 2005-07-21 3M Innovative Properties Company Methods of making reflective elements
US20060257205A1 (en) * 2004-04-28 2006-11-16 Jordan Wesley B Long life intelligent illuminated road markers
US20060040575A1 (en) * 2004-08-18 2006-02-23 Kelleher Karen A Reflective printing on flame resistant fabrics
US7252396B2 (en) * 2004-11-16 2007-08-07 3M Innovative Properties Company Retroreflective article having at least one valve and method of making same
US8268435B2 (en) * 2005-09-26 2012-09-18 Avery Dennison Corporation Retroreflective sheeting
US7513941B2 (en) 2005-11-14 2009-04-07 3M Innovative Properties Company Pavement marking, reflective elements, and methods of making micospheres
KR100727717B1 (ko) * 2006-02-24 2007-06-13 (주)아해 폴리아미드수지를 이용한 재용융형 도로표지용 도료조성물
KR100773200B1 (ko) * 2006-02-24 2007-11-02 (주)아해 폴리아미드 수지를 이용한 재용융형 특수구역 표시용도료조성물
US20080280034A1 (en) 2007-05-11 2008-11-13 3M Innovative Properties Company Pavement marking and reflective elements having microspheres comprising lanthanum oxide and aluminum oxide with zirconia, titania, or mixtures thereof
US8496340B2 (en) * 2007-12-21 2013-07-30 3M Innovative Properties Company Retroreflective articles and retroreflective elements comprising a spherical core and two concentric optical interference layers
WO2009105142A2 (en) * 2007-12-21 2009-08-27 3M Innovative Properties Company Retroreflective security articles
EP2232310A1 (en) * 2007-12-21 2010-09-29 3M Innovative Properties Company Retroreflective artcles in the form of garments, fibers and filaments
US7820083B2 (en) * 2008-02-11 2010-10-26 Fortson-Peek Company, Inc. Wet reflective pavement marking and method
US20100055374A1 (en) * 2008-09-02 2010-03-04 Greer Robert W Retroflective pavement markers for wet weather
US20100221513A1 (en) * 2008-09-05 2010-09-02 Wisconsin Alumni Research Foundation Self sintering transparent nanoporous thin-films for use in self-cleaning, anti-fogging, anti-corrosion, anti-erosion electronic and optical applications
US8840956B2 (en) * 2008-10-31 2014-09-23 Potters Industries, Llc Retroreflective coating and method for applying a retroreflective coating on a structure
US8425144B2 (en) * 2009-01-30 2013-04-23 Fortson-Peek Company, Inc. Pavement marker, method and apparatus
US20100272962A1 (en) * 2009-04-22 2010-10-28 Potters Industries Inc. Reflective substrate surface system, reflective assembly, and methods of improving the visibility of a substrate surface
CN102574729A (zh) 2009-08-21 2012-07-11 3M创新有限公司 路面标记、反射元件以及制备微球的方法
CN102574730A (zh) 2009-08-21 2012-07-11 3M创新有限公司 路面标记、反射元件以及制备微球的方法
US8647013B2 (en) * 2010-02-09 2014-02-11 Potters Industries, Llc Reflective substrate surface system, reflective assembly, and methods of improving the visibility of a substrate surface
EP2577365B1 (en) 2010-05-25 2021-02-17 3M Innovative Properties Company Exposed lens retroreflective article
CN103842591B (zh) 2011-09-01 2016-03-16 3M创新有限公司 道路标记材料和方法
CN102515777B (zh) * 2011-11-25 2013-05-01 东北大学 一种光学透明陶瓷微球及其制备方法
CN103792604B (zh) 2012-10-26 2016-12-21 3M创新有限公司 回归反射制品和附饰物
CN103792603B (zh) 2012-10-26 2016-07-06 3M创新有限公司 回归反射材料及制品
WO2014070229A1 (en) 2012-10-29 2014-05-08 3M Innovative Properties Company Pavement marking compositions
CN104884943B (zh) 2012-12-21 2019-02-12 3M创新有限公司 用于确定表面的清洁度的系统和方法
WO2015061065A1 (en) 2013-10-24 2015-04-30 3M Innovative Properties Company Retroreflective articles with anti-staining properties
CN105940325A (zh) 2014-01-31 2016-09-14 3M创新有限公司 彩色回射制品
EP3126414B1 (en) 2014-04-04 2018-06-06 3M Innovative Properties Company Primer composition for wet or damp surface preparation
US10138367B2 (en) 2014-04-29 2018-11-27 3M Innovative Properties Company Copolymers of poly(ethylene-co-acrylic acid) and polydiorganosiloxanes
WO2015167947A1 (en) 2014-04-30 2015-11-05 3M Innovative Properties Company Stain resistant retroreflective articles
US10197714B2 (en) 2014-05-09 2019-02-05 3M Innovative Properties Company Colored retroreflective articles
WO2015171405A1 (en) 2014-05-09 2015-11-12 3M Innovative Properties Company Retroreflective articles
US10261222B2 (en) 2014-06-16 2019-04-16 3M Innovative Properties Company Retroreflective articles with wash durable bead bond layers
EP3191879A1 (en) 2014-09-10 2017-07-19 3M Innovative Properties Company Exposed lens retroreflective articles comprising a self-assembled dielectric mirror
US10845514B2 (en) 2014-09-30 2020-11-24 3M Innovative Properties Company Retroreflective colored articles
US10345495B2 (en) 2014-12-30 2019-07-09 3M Innovative Properties Company Stain resistant retroreflective articles
WO2016205443A1 (en) 2015-06-18 2016-12-22 3M Innovative Properties Company Thermoplastic pavement marking tapes
US11413846B2 (en) 2016-03-30 2022-08-16 3M Innovative Properties Company Article featuring a predetermined pattern of randomly distributed microspheres and methods of making the same
WO2019003158A1 (en) 2017-06-30 2019-01-03 3M Innovative Properties Company ARTICLES HAVING ADHESIVE LAYERS COMPRISING URETHANE ACRYLATE POLYMERS OR ACRYLATE COPOLYMER
JP2019044497A (ja) * 2017-09-04 2019-03-22 大崎工業株式会社 標示シート、標示シートの製造方法、標示体シート、標示体シートの製造方法、及び標示体設置方法
WO2019084295A1 (en) 2017-10-27 2019-05-02 3M Innovative Properties Company RETROREFLECTIVE ARTICLE COMPRISING LOCALLY LAMINATED REFLECTIVE LAYERS
CN111344606A (zh) 2017-10-27 2020-06-26 3M创新有限公司 包括含有主反射层和次反射层的回射元件的回射制品
EP3701300A4 (en) 2017-10-27 2021-08-25 3M Innovative Properties Company REFLECTIVE ITEM INCLUDING EMBEDDED REFLECTIVE LAYERS
CN107942424B (zh) * 2017-11-27 2020-07-07 复旦大学 一种可变色逆反射材料的制备方法

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2218909A (en) * 1937-03-30 1940-10-22 Prismo Holding Corp Method of making reflecting devices
US2326634A (en) * 1941-12-26 1943-08-10 Minnesota Mining & Mfg Reflex light reflector
US2963378A (en) * 1955-04-25 1960-12-06 Minnesota Mining & Mfg Ass beads hemispherically reflectorled with metallic coating and compositions thereof
US3355311A (en) * 1963-10-22 1967-11-28 Pittsburgh Plate Glass Co Reflective coatings
US3709706A (en) * 1969-05-16 1973-01-09 Minnesota Mining & Mfg Refractory fibers and other articles of zirconia and silica mixtures
DE2103243C3 (de) * 1971-01-25 1979-01-11 Basf Ag, 6700 Ludwigshafen Verfahren und Vorrichtung zur Herstellung von weitgehend kugelförmigen, Kieselsäure enthaltenden Hydrogelen
US3795524A (en) * 1971-03-01 1974-03-05 Minnesota Mining & Mfg Aluminum borate and aluminum borosilicate articles
US3849351A (en) * 1971-09-16 1974-11-19 Minnesota Mining & Mfg Pavement marking material containing a polyamide modified by a diphenolic acid
US4166147A (en) * 1973-04-16 1979-08-28 Minnesota Mining And Manufacturing Company Shaped and fired articles of tio2
US3900605A (en) * 1973-09-05 1975-08-19 Jr Robert W Norris Method of forming traffic markers having short track-free times
IT1022451B (it) * 1974-09-30 1978-03-20 Eigenmann Ludwig Striscia prefabbricata per segnale tica stradale orizzontale e metodo per la sua prefabbricazione
US4117192A (en) * 1976-02-17 1978-09-26 Minnesota Mining And Manufacturing Company Deformable retroreflective pavement-marking sheet material
US4116866A (en) * 1977-07-01 1978-09-26 N L Industries, Inc. Organophilic clay gellant
US4092081A (en) * 1977-07-05 1978-05-30 Hpc, Inc. Roadway/traffic delineator
US4145112A (en) * 1977-07-14 1979-03-20 Minnesota Mining And Manufacturing Company Low-profile raised retroreflective sheeting
US4367919A (en) * 1977-08-01 1983-01-11 Minnesota Mining And Manufacturing Company Durable glass elements
CS196794B1 (en) * 1977-09-23 1980-04-30 Dusan Berek Method of preparation of spherical microelements
AU510544B2 (en) * 1977-10-19 1980-07-03 Ferro Corporation Retroreflector
US4138336A (en) * 1977-12-02 1979-02-06 Minnesota Mining And Manufacturing Company Thin layer chromatographic plates
CH618755A5 (en) * 1978-04-18 1980-08-15 Agostino Casari Reflective road marking surfacing
US4292035A (en) * 1978-11-13 1981-09-29 The Procter & Gamble Company Fabric softening compositions
US4248932A (en) * 1979-06-14 1981-02-03 Minnesota Mining And Manufacturing Company Extended-life pavement-marking sheet material
US4299874A (en) * 1980-03-31 1981-11-10 Minnesota Mining And Manufacturing Company Removable pavement-marking sheet material
US4434076A (en) * 1981-10-19 1984-02-28 Nl Industries, Inc. Clay cation complexes and their use to increase viscosity of liquid organic systems
US4412018A (en) * 1980-11-17 1983-10-25 Nl Industries, Inc. Organophilic clay complexes, their preparation and compositions comprising said complexes
US4490432A (en) * 1982-04-23 1984-12-25 Minnesota Mining And Manufacturing Company Reinforced pavement-marking sheet material
US4388359A (en) * 1982-04-23 1983-06-14 Minnesota Mining And Manufacturing Company Embossed pavement-marking sheet material
US4564556A (en) * 1984-09-24 1986-01-14 Minnesota Mining And Manufacturing Company Transparent non-vitreous ceramic particulate

Also Published As

Publication number Publication date
BR8700017A (pt) 1987-12-01
EP0232980A1 (en) 1987-08-19
KR940002037B1 (ko) 1994-03-14
JPS62164905A (ja) 1987-07-21
CA1308845C (en) 1992-10-13
CN1010959B (zh) 1990-12-26
AU586300B2 (en) 1989-07-06
JPH0784726B2 (ja) 1995-09-13
US4758469A (en) 1988-07-19
MX160846A (es) 1990-06-05
CN87100121A (zh) 1987-08-05
AU6583286A (en) 1987-07-16
ES2023886B3 (es) 1992-02-16
EP0232980B1 (en) 1991-08-21
DE3772217D1 (de) 1991-09-26
ATE66508T1 (de) 1991-09-15

Similar Documents

Publication Publication Date Title
KR870007334A (ko) 세라믹 미소구를 함유하는 도로표지
KR900005021A (ko) 미끄럼방지성 포장도로 표지
ATE114342T1 (de) Fahrbahnmarkierungsmaterial.
KR950016805A (ko) 코팅된 골프공(coated golf ball)
PT94248A (pt) Composto estratificado com estruturas difractivas
GB1463681A (en) Road surface marking tape material
KR830007774A (ko) 논스틱 피복강 물질
KR920018106A (ko) 폴리에스테르 필름
CA1268016C (en) RETROREFLECTIVE PARTICLES, AND THEIR MANUFACTURE
DE69505388D1 (de) Polysiloxanharz und ton enthaltender polymerfilm
DE59708397D1 (de) Folie zur Beschichtung von nachbearbeitbaren Substraten
KR880004172A (ko) 노면의 간이 포장법
KR970061952A (ko) 축전기에 사용하기 위한 거친 이축 배향된 폴리에스테르 필름
ATE50734T1 (de) Sicherheitsdokument.
KR890700851A (ko) 수소다리 형성 조성물
AU3516989A (en) New medium and its application
KR920007840A (ko) 언더코트층용 도공액 조성물 및 이를 도공한 감열기록체
IE33487B1 (en) Improvements in and relating to self-adhesive transfers
DE69938637D1 (de) Wiederverwendbares Aufzeichnungsmaterial, das Mikropartikel enthält
JPH10274856A (ja) 静電記録シート
AU779775B2 (en) Destination aid
JPS63291086A (ja) 再帰反射物とその製造法
JPS646959A (en) Electrostatic recording sheet
KR910010373A (ko) 자동부착용 스티커지
JPS6238170U (ko)

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20010308

Year of fee payment: 8

LAPS Lapse due to unpaid annual fee