KR870005693A - 알칸올 아민류의 기상 분자내 탈수반응용 촉매 - Google Patents

알칸올 아민류의 기상 분자내 탈수반응용 촉매 Download PDF

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KR870005693A
KR870005693A KR860011391A KR860011391A KR870005693A KR 870005693 A KR870005693 A KR 870005693A KR 860011391 A KR860011391 A KR 860011391A KR 860011391 A KR860011391 A KR 860011391A KR 870005693 A KR870005693 A KR 870005693A
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South Korea
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catalyst
dehydration
represented
alumina
carrier
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KR860011391A
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KR910004073B1 (ko
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요오이찌 히노
유우지 시마사끼
미찌오 우에시마
히데아끼 쓰네끼
히또시 야노
Original Assignee
나까지마 미쯔루
닛뽕 쇼꾸 바이 가가꾸 고오교 가부시끼 가이샤
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Priority claimed from JP60292541A external-priority patent/JPS62152543A/ja
Priority claimed from JP61266587A external-priority patent/JPS63123443A/ja
Priority claimed from JP61266585A external-priority patent/JPS63123441A/ja
Priority claimed from JP61266586A external-priority patent/JPS63123442A/ja
Application filed by 나까지마 미쯔루, 닛뽕 쇼꾸 바이 가가꾸 고오교 가부시끼 가이샤 filed Critical 나까지마 미쯔루
Publication of KR870005693A publication Critical patent/KR870005693A/ko
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Publication of KR910004073B1 publication Critical patent/KR910004073B1/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D203/00—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom
    • C07D203/04—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D203/06—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D203/08—Heterocyclic compounds containing three-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring nitrogen atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B01J27/1802—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates
    • B01J27/1804—Salts or mixtures of anhydrides with compounds of other metals than V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, e.g. phosphates, thiophosphates with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/182—Phosphorus; Compounds thereof with silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D205/00—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom
    • C07D205/02—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings
    • C07D205/04—Heterocyclic compounds containing four-membered rings with one nitrogen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/02—Preparation by ring-closure or hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/023—Preparation; Separation; Stabilisation; Use of additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

알칸올아민류의 기상 분자내 탈수반응용 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 하기 일반식(I)로 표시되는 알칸올아민을 하기 일반식(II)로 표시되는 고리형 아민으로 전환시키는 촉매가 하기식(III)으로 표시되는 조성물임을 특징으로 하는 기상분자내 탈수반응용 촉매.
    상기식에서, R 및 R'는 수소, 메틸기 및 에틸기에서 선택되고, n은 2내지 5의 정수이고, X는 알칼리금속 및 알칼리토금속에서 선택된 하나 이상의 원소이고, P는 포스포러스이고, Y는 B, Al, Si, S, Sc, Ti, Cu, Y, Zr, Nb, Mo, Sn, Sb, La, Ce, Ta, W, Tl, Pb, Bi 및 Th에서 선택된 하나 이상의 원소이고, O는 산소이고, a, b, c 및 d는 원소 X, P, Y 및 O의 원자비이고, a=1일 때, b=0.01∼3이고 c는 0∼100이고, d는 a, b 및 c와 성분원소의 결합상태에 따라 결정된다.
  2. 제 1 항에 있어서, 산화 조성물이 담체상의 최종촉매의 전체 중량에 대하여 1 내지 60%로 증착되는 촉매.
  3. 제 2 항에 있어서, 담체가 규조토, 실리카겔, 알루미나, 실리카 - 알루미나, 실리콘 카바이드, 실리콘니트리드, 지르코니아, 클레이 무기물 또는 칼슘 히드록시아파타이트인 촉매.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860011391A 1985-12-27 1986-12-27 알칸올아민류의 기상 분자내 탈수반응용 촉매 KR910004073B1 (ko)

Applications Claiming Priority (12)

Application Number Priority Date Filing Date Title
JP60292541A JPS62152543A (ja) 1985-12-27 1985-12-27 アルカノ−ルアミン類の気相分子内脱水反応用触媒
JP292,541/85 1985-12-27
JP85-292,541 1985-12-27
JP266,586/86 1986-11-11
JP86-266,586 1986-11-11
JP61266587A JPS63123443A (ja) 1986-11-11 1986-11-11 アルカノ−ルアミン類の気相分子内脱水反応用触媒
JP61266585A JPS63123441A (ja) 1986-11-11 1986-11-11 アルカノ−ルアミン類の気相分子内脱水反応用触媒
JP61266586A JPS63123442A (ja) 1986-11-11 1986-11-11 アルカノ−ルアミン類の気相分子内脱水反応用触媒
JP86-266,585 1986-11-11
JP266,587/86 1986-11-11
JP86-266,587 1986-11-11
JP266,585/86 1986-11-11

Publications (2)

Publication Number Publication Date
KR870005693A true KR870005693A (ko) 1987-07-06
KR910004073B1 KR910004073B1 (ko) 1991-06-22

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KR1019860011391A KR910004073B1 (ko) 1985-12-27 1986-12-27 알칸올아민류의 기상 분자내 탈수반응용 촉매

Country Status (7)

Country Link
US (2) US4774218A (ko)
EP (1) EP0228898B1 (ko)
KR (1) KR910004073B1 (ko)
CN (1) CN1009644B (ko)
AU (1) AU590039B2 (ko)
CA (1) CA1276616C (ko)
DE (1) DE3677929D1 (ko)

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US5650544A (en) * 1994-09-19 1997-07-22 Nippon Shokubai Co., Ltd. Process for production of unsaturated ether and catalyst used for production of unsaturated ether
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JP3784878B2 (ja) * 1996-03-12 2006-06-14 株式会社日本触媒 ビニルエーテルの製造法
JP4109893B2 (ja) * 2002-04-24 2008-07-02 株式会社日本触媒 アジリジン類およびｎ−ビニルアミド類の製造方法
DE102008001262B4 (de) 2007-04-20 2022-01-27 Basf Se Kontinuierliches Verfahren zur Herstellung von Ethylenimin
CN103819381B (zh) * 2013-12-18 2015-05-13 西安近代化学研究所 氮丙啶、哌嗪和三乙烯二胺的联合生产方法及装置
CN104437570A (zh) * 2014-11-28 2015-03-25 西安近代化学研究所 一种氨基醇类化合物分子内脱水用催化剂的制备方法
CN105126882B (zh) * 2015-08-31 2018-06-12 西安近代化学研究所 一种单乙醇胺分子内脱水催化剂
CN105107534B (zh) * 2015-08-31 2017-09-29 西安近代化学研究所 酸活化蒙脱土载铯催化剂及其在催化单乙醇胺合成氮丙啶中的应用
CN113042026B (zh) * 2021-03-30 2023-03-03 盐城工学院 一种用于乙醇胺催化脱水制备氮丙啶的催化剂及其制备方法

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Publication number Publication date
DE3677929D1 (de) 1991-04-11
US4774218A (en) 1988-09-27
EP0228898B1 (en) 1991-03-06
EP0228898A2 (en) 1987-07-15
EP0228898A3 (en) 1988-01-07
KR910004073B1 (ko) 1991-06-22
AU590039B2 (en) 1989-10-26
CA1276616C (en) 1990-11-20
US4833248A (en) 1989-05-23
AU6688186A (en) 1987-07-02
CN1009644B (zh) 1990-09-19
CN86108963A (zh) 1987-08-05

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