KR910020038A - 폴리우레탄의 3차 아민 촉매 - Google Patents

폴리우레탄의 3차 아민 촉매 Download PDF

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Publication number
KR910020038A
KR910020038A KR1019910007278A KR910007278A KR910020038A KR 910020038 A KR910020038 A KR 910020038A KR 1019910007278 A KR1019910007278 A KR 1019910007278A KR 910007278 A KR910007278 A KR 910007278A KR 910020038 A KR910020038 A KR 910020038A
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South Korea
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tertiary amine
amine catalyst
alkyl
alkylene
polyurethane composition
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KR1019910007278A
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KR940009021B1 (ko
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패트릭 케이시 제레미아
반 코트 카아 리처드
제임스 와실칙 조지
가브리엘 패트렐라 로버트
Original Assignee
윌리암 에프. 마쉬
에어 프로덕츠 앤드 케미칼스, 인코오포레이티드
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Publication of KR910020038A publication Critical patent/KR910020038A/ko
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Publication of KR940009021B1 publication Critical patent/KR940009021B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/08—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms
    • C07D295/084—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings
    • C07D295/088—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by singly bound oxygen or sulfur atoms with the ring nitrogen atoms and the oxygen or sulfur atoms attached to the same carbon chain, which is not interrupted by carbocyclic rings to an acyclic saturated chain
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C07C217/02—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C217/04—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C217/06—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted
    • C07C217/08—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having etherified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having only one etherified hydroxy group and one amino group bound to the carbon skeleton, which is not further substituted the oxygen atom of the etherified hydroxy group being further bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/1833—Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
    • C08G18/20—Heterocyclic amines; Salts thereof
    • C08G18/2009—Heterocyclic amines; Salts thereof containing one heterocyclic ring

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

내용 없음

Description

폴리우레탄의 3차 아민 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (19)

  1. 하기 일반식의 3차 아민 촉매;
    상기식중, Ra은 n이 1일때 C1-3알킬렌이거나, n이 0이고 p가 1일때 C1-3알킬 또는 C1-3히드록시알킬이고; Rb는 p가 1일때 C1-3알킬렌이거나 n이 1이고 p가 0일때 C1-3알킬 또는 C1-3히드록시알킬이고; R1은 C3-5알킬렌이고; R2는 C1-4저급알킬, C5-10 시클로 지방족이거나 두개의 R2기가 결합하여 5내지 6원 고리를 형성하고; n은 0또는 1이고; m은 0또는 1이고; p는 0또는 1이고; 이때 n, m 또는 p중 적어도 하나는 1이어야 한다.
  2. 제1항에 있어서, n이 1이고 m은 0이고 p는 0인 3차 아민 촉매.
  3. 제2항에 있어서, Ra는 C1알킬렌이고 R1은 C3알킬인 삼차 아민 촉매.
  4. 제3항에 있어서, Rb는 C2알킬인 삼차 아민 촉매.
  5. 제4항에 있어서, R2는 C1-4알킬인 삼차 아민 촉매.
  6. 제4항에 있어서, R2는 C1알킬인 삼차 아민 촉매.
  7. 제4항에 있어서, 두개의 R2기가 6원고리로 결합되어 모르폴린을 나타내는 삼차 아민 촉매.
  8. 제4항에 있어서, R2가 N-메틸피라진인 삼차 아민 촉매.
  9. 제1항에 있어서, n은 1, m은 0이고 p는 1인 삼차 아민 촉매.
  10. 제9항에 있어서, Ra는 C1알킬렌, Rb는 C1알킬렌이고 R1은 C3알킬렌인 삼차 아민 촉매.
  11. 제10항에 있어서, R2는 C1-4알킬인 삼차 아민 촉매.
  12. 제1항에 있어서, R2가 N-메틸피라진인 삼차아민 촉매.
  13. 제12항에 있어서, R2는 C1알킬인 삼차아민 촉매.
  14. 제12항에 있어서, 두개의 R2기가 6원 고리로 결합되어 모르폴린을 나타내는 삼차 아민 촉매.
  15. 삼차아민 촉매의 존재하에 폴리이소시아네이트를 폴리올과 반응시켜 생성된 폴리우레탄 조성물에 있어서, 제1항에 의한 상기 삼차아민촉매를 상기 폴리올 100중량부에 대해 약 0.5내지 2.5중량부의 양으로 사용한 것을 특징으로 하는 폴리 우레탄 조성물.
  16. 제15항에 있어서, 상기 삼차 아민 촉매가 1-(3-디알킬아미노프로폭시)-2-부탄올인 폴리우레탄 조성물.
  17. 제16항에 있어서, 상기 삼차아민 촉매가 1-(3-디메틸아미노프로폭시)-2-부탄올인 폴리우레탄 조성물.
  18. 제15항에있어서, 상기 삼차아민 촉매가 1-(3-(N-메틸피페라지노)-프로폭시)-2-부탄올인 폴리우레탄 조성물.
  19. 제15항에 있어서, 상기 삼차아민 촉매가 1-(모르폴리노프로폭시)-2-부탄올인 폴리우레탄 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910007278A 1990-05-07 1991-05-24 폴리우레탄의 3차 아민 촉매 KR940009021B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/519,711 US5071809A (en) 1990-05-07 1990-05-07 Tertiary amine catalysts for polyurethanes
US07/519711 1990-05-07

Publications (2)

Publication Number Publication Date
KR910020038A true KR910020038A (ko) 1991-12-19
KR940009021B1 KR940009021B1 (ko) 1994-09-29

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KR1019910007278A KR940009021B1 (ko) 1990-05-07 1991-05-24 폴리우레탄의 3차 아민 촉매

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US (1) US5071809A (ko)
EP (1) EP0456194A3 (ko)
JP (1) JPH04227715A (ko)
KR (1) KR940009021B1 (ko)
AU (1) AU7610091A (ko)
BR (1) BR9101794A (ko)
CA (1) CA2041480A1 (ko)
NO (1) NO911779L (ko)

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JP3329049B2 (ja) * 1994-01-24 2002-09-30 日本油脂ビーエーエスエフコーティングス株式会社 自動車用上塗塗料のクリヤーコート用熱硬化被覆組成物
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US5512603A (en) * 1994-02-22 1996-04-30 Air Products And Chemicals, Inc. Hydroxy and amino functional pyrrolizidine catalyst compositions for the production of polyurethanes
US5710191A (en) * 1995-06-05 1998-01-20 Air Products And Chemicals, Inc. Hydroxymethyl quinuclidine catalyst compositions for making polyurethane foams
US5633293A (en) 1995-11-30 1997-05-27 Air Products And Chemicals, Inc. Hydroxy-functional triamine catalyst compositions for polyurethane production
JP3701138B2 (ja) * 1999-04-23 2005-09-28 松下電器産業株式会社 電子部品の製造方法
KR101721267B1 (ko) 2008-05-30 2017-03-29 도소 가부시키가이샤 하이드록시알킬트리에틸렌디아민류의 제조 방법, 및 그것을 사용한 폴리우레탄 수지 제조용의 촉매 조성물
JP6626674B2 (ja) * 2014-10-08 2019-12-25 積水ソフランウイズ株式会社 硬質ポリウレタンフォーム用ポリオール組成物、及び硬質ポリウレタンフォームの製造方法
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EP0456194A3 (en) 1992-05-13
AU7610091A (en) 1991-11-07
JPH04227715A (ja) 1992-08-17
NO911779L (no) 1991-11-08
KR940009021B1 (ko) 1994-09-29
NO911779D0 (no) 1991-05-06
US5071809A (en) 1991-12-10
BR9101794A (pt) 1991-12-17
EP0456194A2 (en) 1991-11-13
CA2041480A1 (en) 1991-11-08

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