KR850700035A - 트리아진그룹 함유 하이드록시방향족 올리고머의 제조방법 및 이 올리고머로부터 에폭시수지의 제조방법 - Google Patents

트리아진그룹 함유 하이드록시방향족 올리고머의 제조방법 및 이 올리고머로부터 에폭시수지의 제조방법

Info

Publication number
KR850700035A
KR850700035A KR1019850700101A KR850700101A KR850700035A KR 850700035 A KR850700035 A KR 850700035A KR 1019850700101 A KR1019850700101 A KR 1019850700101A KR 850700101 A KR850700101 A KR 850700101A KR 850700035 A KR850700035 A KR 850700035A
Authority
KR
South Korea
Prior art keywords
mentioned
hydroxyl group
aromatic hydroxyl
minutes
trimerization
Prior art date
Application number
KR1019850700101A
Other languages
English (en)
Other versions
KR870001412B1 (ko
Inventor
이.헤프너2세 로버트
Original Assignee
리챠드 지. 워터맨
더 다우 케미칼 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 리챠드 지. 워터맨, 더 다우 케미칼 캄파니 filed Critical 리챠드 지. 워터맨
Publication of KR850700035A publication Critical patent/KR850700035A/ko
Application granted granted Critical
Publication of KR870001412B1 publication Critical patent/KR870001412B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/3236—Heterocylic compounds
    • C08G59/3245—Heterocylic compounds containing only nitrogen as a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C261/00—Derivatives of cyanic acid
    • C07C261/02—Cyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/063—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with epihalohydrins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Epoxy Resins (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

내용 없음

Description

트리아진그룹 함유 하이드록시방향족 올리고머의 제조방법 및 이 올리고머로부터 에폭시수지의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. (I) 분자당 평균 1개이상의 방향족 하이드록실그룹을 갖는 물질 1종이상(A)을, 방향족 하이드록실그룹당 0.01 내지 1.1몰량의 적당한 염기(C)의 존재하에, 반응완결에 충분한 시간 및 온도에서, 방향족하이드록실그룹당 0.01 내지 0.95몰의 시아노겐 할라이드 또는 시아노겐 할라이드 혼합물과 반응시킨 다음, 생성된 시아네이트 혼합물을 회수하고; (Ⅱ)(Ⅰ)로부터 수득된 생성물을, 심량체화 반응의 완결에 충분한 시간 및 온도에서, 적당한 삼량체화 반응촉매의 존재하에 삼량체화 반응시킴을 특징으로 하는, 트리아진그룹 함유 하이드록시방향족 올리고머의 제조방법.
  2. 제1항에 있어서, (A)중에 함유된 방향족 하이드록그룹: (B)의 몰수: (C)의 몰수의 비율이 1 : 0.05 내지 1 : 0.55 : 0.60이고, 단계(Ⅰ)을 -40 내지 60℃에서 10내지 120분간 수행하며, 단계(Ⅱ)를 70° 내지 350℃에서 15 내지 120분간 수행함을 특징으로 하는 방법.
  3. 제2항에 있어서, 단계(I)을 -20° 내지 25℃에서 10 내지 60분간 수행하고, 단계(Ⅱ)를 70° 내지 200℃에서 30 내지 75분간 수행함을 특징으로 하는 방법.
  4. 제1항에 있어서, 언급된 시아노겐 할라이드가 시아노겐 브로마이드이고, 언급된 분자당 평균 1개이상의 방향족 하이드록실그룹을 갖는 물질이 비스페놀이며, 언급된 적당한 염기가 3급아민이고, 언급된 삼량체화 반응촉매가 키복실산의 급속염임을 특징으로 하는 방법.
  5. 제4항에 있어서, 언급된 분자당 평균 1개이상의 방향족 하이드록실그룹을 갖는 물질이 비스페놀 A이고, 언급된 적당한 염기가 트리에틸아민이며, 언급된 삼량체화 반응촉매가 코발트 나프테네이트임을 특징으로 하는 방법.
  6. 하이드록시 방향족 물질을 통상의 방법에 따라 에피할로히드린과 반응시켜 에폭시화시키고, 이어서 염기성 작용물질로 탈-하이드로할로겐화반응시킨 다음, 최종적으로 생성된 글리시딜 에테르 생성물을 회수하는 에폭수지의 제조방법에 있어서, 언급된 하이드록시방향족 물질이 제1항의 방법중 단계(Ⅱ)로 부터의 삼량체화된 하이드록시방향족 올리고머임을 특징으로 하는 방법.
  7. 제6항에 있어서, 언급된 에피할로히드린이 에피클로로 히드린이고, 언급된 염기성 작용물질이 알카리금속 하이드록사이드임을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850700101A 1983-10-31 1984-10-25 트리아진그룹 함유 하이드록시 방향족 올리고머의 제조방법 KR870001412B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US06/547,537 US4489202A (en) 1983-10-31 1983-10-31 Process for preparing epoxy resins containing triazine groups
US547,537 1983-10-31
US547537 1983-10-31
PCT/US1984/001723 WO1985001943A1 (en) 1983-10-31 1984-10-25 Processes for preparing hydroxyaromatic oligomers containing triazine groups and for preparing epoxy resins from the oligomers

Related Child Applications (1)

Application Number Title Priority Date Filing Date
KR1019870700357A Division KR890003290B1 (ko) 1983-10-31 1984-10-25 에폭시수지의 제조방법

Publications (2)

Publication Number Publication Date
KR850700035A true KR850700035A (ko) 1985-10-21
KR870001412B1 KR870001412B1 (ko) 1987-07-30

Family

ID=24185044

Family Applications (2)

Application Number Title Priority Date Filing Date
KR1019850700101A KR870001412B1 (ko) 1983-10-31 1984-10-25 트리아진그룹 함유 하이드록시 방향족 올리고머의 제조방법
KR1019870700357A KR890003290B1 (ko) 1983-10-31 1984-10-25 에폭시수지의 제조방법

Family Applications After (1)

Application Number Title Priority Date Filing Date
KR1019870700357A KR890003290B1 (ko) 1983-10-31 1984-10-25 에폭시수지의 제조방법

Country Status (16)

Country Link
US (1) US4489202A (ko)
EP (1) EP0143988B1 (ko)
JP (2) JPS60501610A (ko)
KR (2) KR870001412B1 (ko)
AT (1) ATE67759T1 (ko)
AU (1) AU550680B2 (ko)
BR (1) BR8407148A (ko)
CA (1) CA1259992A (ko)
DE (1) DE3485113D1 (ko)
DK (1) DK294385A (ko)
ES (1) ES8606891A1 (ko)
FI (1) FI85593C (ko)
IL (1) IL73360A (ko)
NZ (1) NZ210039A (ko)
WO (1) WO1985001943A1 (ko)
ZA (1) ZA848468B (ko)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4546131A (en) * 1985-01-15 1985-10-08 The Dow Chemical Company Polymer modified cyanate mixture and epoxy resins thereof
US4555553A (en) * 1985-02-15 1985-11-26 The Dow Chemical Company Hydroxyaromatic oligomers of a mixed cyanate and aromatic polyamine and epoxy resins thereof
US4555554A (en) * 1985-02-15 1985-11-26 The Dow Chemical Company Oligomeric vinyl ester resin compositions containing triazine groups and imino carbamate linkages
US4612359A (en) * 1985-03-21 1986-09-16 The Dow Chemical Company Esterified polycyanate compositions and thermoset resins thereof
US4629763A (en) * 1985-06-24 1986-12-16 The Dow Chemical Company Polymer modified polyphenol compositions and thermosettable resins thereof
US4611022A (en) * 1985-06-24 1986-09-09 The Dow Chemical Company Polymer modified polyphenol compositions and thermosettable resins thereof
US4629764A (en) * 1985-06-24 1986-12-16 The Dow Chemical Company Polymer modified polyphenol compositions and thermosettable resins thereof
US4629762A (en) * 1985-06-24 1986-12-16 The Dow Chemical Company Polymer modified polyphenol compositions and thermosettable resins thereof
US4699933A (en) * 1985-11-04 1987-10-13 The Dow Chemical Company Polyurethanes containing triazine or both triazine and oxazoline, triazine and imino carbamate or triazine and other N-heterocyclic groups
EP0290458B1 (en) * 1986-01-23 1993-07-21 AlliedSignal Inc. Phenolic cyanate-phenolic triazine copolymers
US4970276A (en) * 1986-01-23 1990-11-13 Allied-Signal Inc. Phenolic triazine copolymers based on pure cyanato novolacs
US4663398A (en) * 1986-02-24 1987-05-05 The Dow Chemical Company Co-oligomerization product of a mixed cyanate and a polymaleimide and epoxy resins thereof
US4661553A (en) * 1986-02-24 1987-04-28 The Dow Chemical Company Vinyl esters of polyepoxides of polyphenol cyanate mixture and polymaleimide co-oligomers
US6190759B1 (en) 1998-02-18 2001-02-20 International Business Machines Corporation High optical contrast resin composition and electronic package utilizing same
US7598926B2 (en) 2004-02-17 2009-10-06 Panasonic Corporation Display panel, control display panel and method for integrally molding insert material
CN111825829B (zh) * 2020-01-07 2022-05-13 大连理工大学 一种含三嗪环结构的生物基环氧树脂及其制备方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2810706A (en) * 1953-07-01 1957-10-22 American Cyanamid Co Oxirane triazine resinous compositions and processes of preparing the same
US2741607A (en) * 1954-02-23 1956-04-10 Shell Dev Triglycidyl cyanurate and polymers thereof
US2809942A (en) * 1955-10-21 1957-10-15 Devoe & Raynolds Co Process for making polyglycidyl cyanurates
US2864805A (en) * 1955-12-05 1958-12-16 Devoe & Raynolds Co Epoxide resins
US2971942A (en) * 1956-10-01 1961-02-14 Devoe & Raynolds Co Epoxide resins
US3053797A (en) * 1959-04-22 1962-09-11 Dal Mon Research Co Polymerizable triazines and polymers thereof
DE1190184B (de) * 1963-06-25 1965-04-01 Bayer Ag Verfahren zur Herstellung von hochmolekularen Polytriazinen
US3708483A (en) * 1968-10-31 1973-01-02 Dow Chemical Co Synthesis of polymers from s-triazines and perfluoro-vinyl ethers
DE2457081A1 (de) * 1974-12-03 1976-06-10 Bayer Ag S-triazin-vorpolymerisate
DE2457154A1 (de) * 1974-12-04 1976-06-10 Bayer Ag S-triazin-vorpolymerisate und ein verfahren zu deren herstellung
DE2509780A1 (de) * 1975-03-06 1976-09-16 Bayer Ag Tris-(2-hydroxyaryl)-cyanursaeureester
US4142034A (en) * 1978-04-10 1979-02-27 Cincinnati Milacron Inc. Epoxy resin compositions containing an amine-cyanic acid ester combination curing agent
JPS5626925A (en) * 1979-08-10 1981-03-16 Sumitomo Chem Co Ltd Production of epoxy resin

Also Published As

Publication number Publication date
IL73360A (en) 1988-07-31
FI852358L (fi) 1985-06-13
KR880700629A (ko) 1988-03-15
EP0143988B1 (en) 1991-09-25
JPS60501610A (ja) 1985-09-26
DK294385D0 (da) 1985-06-28
EP0143988A2 (en) 1985-06-12
JPH062796B2 (ja) 1994-01-12
FI85593B (fi) 1992-01-31
FI852358A0 (fi) 1985-06-13
KR870001412B1 (ko) 1987-07-30
ES537219A0 (es) 1985-12-01
DK294385A (da) 1985-06-28
DE3485113D1 (de) 1991-10-31
ZA848468B (en) 1986-06-25
FI85593C (fi) 1992-05-11
US4489202A (en) 1984-12-18
BR8407148A (pt) 1985-10-08
KR890003290B1 (ko) 1989-09-06
ES8606891A1 (es) 1985-12-01
AU3552684A (en) 1985-05-22
JPH0565329A (ja) 1993-03-19
AU550680B2 (en) 1986-03-27
IL73360A0 (en) 1985-01-31
WO1985001943A1 (en) 1985-05-09
EP0143988A3 (en) 1986-01-22
ATE67759T1 (de) 1991-10-15
CA1259992A (en) 1989-09-26
NZ210039A (en) 1988-01-08

Similar Documents

Publication Publication Date Title
KR850700035A (ko) 트리아진그룹 함유 하이드록시방향족 올리고머의 제조방법 및 이 올리고머로부터 에폭시수지의 제조방법
KR850700250A (ko) 트리아진 및 옥사졸린의 양 그룹을 함유하는 하이드록시 방향족 올리고머의 제조방법 및 상기 올리고머로부터 에폭시 수지를 제조하는 방법
KR840008659A (ko) 지방족 하이드록실-함유 화합물로 부터 에폭시 수지를 제조하는 방법
ES8704991A1 (es) Un procedimiento para preparar un material resinoso epoxidico
US2712001A (en) Sulfonamide-epoxide compositions
KR870007956A (ko) 에폭시 수지 및 그의 제조방법
GB918405A (en) Process for the production of hardened, ester-modified epoxy resins
EP0273368A3 (en) Process for producing thermoset resin
KR850700251A (ko) 트리아진 그룹 또는 트리아진 그룹과 옥사졸린 그룹 모두를 함유하는 비닐 에스 테르 수지의 제조방법
KR860009057A (ko) 에폭시 수지의 제조방법
GB813188A (en) Improvements in epoxide products e.g. resins
KR900004887A (ko) 음극 침착성 피복 조성물용 안료 페이스트 수지의 제조방법
KR840007236A (ko) 에폭시수지의 경화성, 양이온성 개질 생성물의 제조방법
US4555553A (en) Hydroxyaromatic oligomers of a mixed cyanate and aromatic polyamine and epoxy resins thereof
US3033819A (en) Production of dihydric phenols and epoxide resins
US3351674A (en) Mixed glycidyl derivatives of cyanuric acid and phenols
KR890701659A (ko) 에폭시 수지 및 그 제조방법과 에폭시 포옴 제조방법
KR920006324A (ko) 5-(4-히드록시페닐) 히단토인의 제조방법
KR850001243A (ko) 포스포늄 트리플루오로아세테이트 촉매를 사용한 에폭시수지의 제조방법

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 19920604

Year of fee payment: 6

LAPS Lapse due to unpaid annual fee