KR850700250A - 트리아진 및 옥사졸린의 양 그룹을 함유하는 하이드록시 방향족 올리고머의 제조방법 및 상기 올리고머로부터 에폭시 수지를 제조하는 방법 - Google Patents

트리아진 및 옥사졸린의 양 그룹을 함유하는 하이드록시 방향족 올리고머의 제조방법 및 상기 올리고머로부터 에폭시 수지를 제조하는 방법

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Publication number
KR850700250A
KR850700250A KR1019850700240A KR850700240A KR850700250A KR 850700250 A KR850700250 A KR 850700250A KR 1019850700240 A KR1019850700240 A KR 1019850700240A KR 850700240 A KR850700240 A KR 850700240A KR 850700250 A KR850700250 A KR 850700250A
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component
groups
group
epoxy resin
cyanogen
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KR1019850700240A
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KR890001621B1 (ko
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쥬니어 로버트 이 헤프너
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리차드 지. 워터맨
더 다우 케미칼 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014—Nitrogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C261/00—Derivatives of cyanic acid
    • C07C261/02—Cyanates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
    • C07D251/30—Only oxygen atoms
    • C07D251/34—Cyanuric or isocyanuric esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/066—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with chain extension or advancing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/26—Di-epoxy compounds heterocyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/3236—Heterocylic compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Epoxy Resins (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Adornments (AREA)
  • Steroid Compounds (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Phenolic Resins Or Amino Resins (AREA)

Abstract

내용 없음

Description

트리아진 및 옥사졸린의 양 그룹을 함유하는 하이드록시 방향족 올리고머의 제조방법 및 상기 올리고머로부터 에폭시 수지를 제조하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. ( I )( A ) 분자당 평균 하나 이상의 방향족 하이드록실 그룹을 갖는 물질 최소한 1종을 ( B ) 방향족 하이드록실 그룹당 최소한 0.01 내지 0.95몰의 시아노겐 할라이드 또는 시아노겐 할라이드의 혼합물과 (C ) 방향족 하이드실 그룹당 0.01 내지 1.1몰의 적절한 염기 존재하에 반응을 거의 완결시키는데 충분한 온도 및 시간에서 반응시킨 후, 수득되는 시아네이트 혼합물을 회수하고;. ( II ) 단계 ( I )로부터 수득된 생성물을 ( D ) 에폭시 수지와(에폭시 그룹 대 시아네이트 그룹의 몰비가 1 : 1 내지 1: 100이다), 적절한 공올리고머화 촉매 존재하에 공올리고머화반응을 거의 완결시키는 온도 및 시간에서 공올리고머화시킴을 특징으로 하여, 트리아진 및 옥사졸린의 양 그룹을 함유하는 하이드록시방향족 올리고머를 제조하는 방법.
  2. 제1항에 있어서, 성분( A ) 및 ( B )가 방향족 하이드록실그룹당 0.05 내지 0.55몰의 시아노겐 할라이드 또는 시아노겐 할라이드의 혼합물을 제공하는 량으로 존재하고, 성분( C )가 방향족 하이드록실 그룹의 몰당 0.05내지 0.6몰의 염기를 제공하는 량으로 존재하고, 에폭시그룹 대 시아네이트 그룹의 몰비가 1 : 10내지 1 : 40인 방법.
  3. 제2항에 있어서, 성분( A )가 명세서내의 일반식( I ),( II ) 또는 ( III )의 화합물이고, 성분( B )가 시아노겐 클로라이드, 시아노겐 브로마이드 또는 이의 혼합물이고, 성분( C )가 트리알킬아민이고, 성분( D )가 명세서내의 일반식( IV ) 또는 ( V )의 화합물인 방법.
  4. 제3항에 있어서, 성분(A)가 일반식( II )의 화합물이고, 성분( C )가 트리에틸아민이고, 성분( D )가 일반식( IV ) 의 에폭시 수지인 방법.
  5. 제4항에 있어서, 성분( A )에서 A는 탄소수 1내지 12의 2가 탄화수소 그룹이고, n은 1이며, 성분( D )에서 A는 각기 독립적으로 탄소수 1 내지 12의 2가 탄화수소 그룹이고, n은 1이며 m2는 0 내지 40의 평균값을 갖는 방법.
  6. 제5항에 있어서, 성분(A)에서 A는 이소프필리덴 그룹이고, 성분(D)에서 A는 이소프로필리덴그룹이고 m2는 0.1내지 20의 평균값을 갖는 방법.
  7. 하이드록시방향족 물질을 에피할로히드린과 반응시키고, 염기성-작용물질과 계속하여 탈할로겐화수소화 반응시키고, 최종적으로 수득되는 글리시딜 에테르생성물을 회수함으로써 통상적 방법으로 에폭시화하여 에폭시수지를 제조하는 방법에 있어서, 하이드록시 방향족 물질이 제1항의 단계 ( II )로부터 수득되는 공올리고머화 생성물인 방법.
  8. 제7항에 있어서, 에피할로히드린이 에피클로로히드린이고 염기성-작용 물질이 알칼리 금속 수산화물인 방법.
    ※참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019850700240A 1984-02-02 1984-10-25 트리아진 및 옥사졸린 그룹을 함유하는 하이드록시방향족 올리고머의 제조방법 KR890001621B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US06/576,304 US4487915A (en) 1984-02-02 1984-02-02 Hydroxy aromatic oligomers containing triazine and oxazoline groups and epoxy resins prepared therefrom
US576,304 1984-02-02
PCT/US1984/001724 WO1985003514A1 (en) 1984-02-02 1984-10-25 Processes for preparing hydroxyaromatic oligomers containing both triazine and oxazoline groups and for preparing epoxy resins from the oligomers
US576304 1990-08-31

Related Child Applications (1)

Application Number Title Priority Date Filing Date
KR1019890700111A Division KR890005041B1 (ko) 1984-02-02 1984-10-25 하이드록시 방향족 올리고머로부터 에폭시수지를 제조하는 방법

Publications (2)

Publication Number Publication Date
KR850700250A true KR850700250A (ko) 1985-12-26
KR890001621B1 KR890001621B1 (ko) 1989-05-11

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ID=24303859

Family Applications (2)

Application Number Title Priority Date Filing Date
KR1019890700111A KR890005041B1 (ko) 1984-02-02 1984-10-25 하이드록시 방향족 올리고머로부터 에폭시수지를 제조하는 방법
KR1019850700240A KR890001621B1 (ko) 1984-02-02 1984-10-25 트리아진 및 옥사졸린 그룹을 함유하는 하이드록시방향족 올리고머의 제조방법

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KR1019890700111A KR890005041B1 (ko) 1984-02-02 1984-10-25 하이드록시 방향족 올리고머로부터 에폭시수지를 제조하는 방법

Country Status (17)

Country Link
US (1) US4487915A (ko)
EP (1) EP0150278B1 (ko)
JP (2) JPS61500317A (ko)
KR (2) KR890005041B1 (ko)
AT (1) ATE40390T1 (ko)
AU (1) AU553539B2 (ko)
BR (1) BR8407285A (ko)
CA (1) CA1259993A (ko)
DE (1) DE3476407D1 (ko)
DK (1) DK445785D0 (ko)
ES (1) ES537220A0 (ko)
FI (1) FI72328C (ko)
IL (1) IL73359A (ko)
NO (1) NO161622C (ko)
NZ (1) NZ210040A (ko)
WO (1) WO1985003514A1 (ko)
ZA (1) ZA848470B (ko)

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US4555554A (en) * 1985-02-15 1985-11-26 The Dow Chemical Company Oligomeric vinyl ester resin compositions containing triazine groups and imino carbamate linkages
US4555553A (en) * 1985-02-15 1985-11-26 The Dow Chemical Company Hydroxyaromatic oligomers of a mixed cyanate and aromatic polyamine and epoxy resins thereof
US4611022A (en) * 1985-06-24 1986-09-09 The Dow Chemical Company Polymer modified polyphenol compositions and thermosettable resins thereof
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US4978727A (en) * 1986-01-23 1990-12-18 Allied-Signal Cyanato group containing phenolic resins, phenolic triazines derived therefrom
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GB9318872D0 (en) * 1993-09-11 1993-10-27 Unisersity Fo Leeds The Polymer resin
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CN110330445A (zh) * 2019-07-18 2019-10-15 扬州天启新材料股份有限公司 一种三酚a型氰酸酯及其制备方法

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Also Published As

Publication number Publication date
BR8407285A (pt) 1986-02-18
NO161622B (no) 1989-05-29
DE3476407D1 (en) 1989-03-02
FI853711L (fi) 1985-09-26
EP0150278A2 (en) 1985-08-07
NO853873L (no) 1985-10-01
ZA848470B (en) 1986-06-25
KR890005041B1 (ko) 1989-12-08
IL73359A0 (en) 1985-01-31
EP0150278A3 (en) 1986-02-12
ES8607348A1 (es) 1985-12-16
IL73359A (en) 1988-07-31
DK445785A (da) 1985-10-01
AU3552784A (en) 1985-08-27
US4487915A (en) 1984-12-11
ES537220A0 (es) 1985-12-16
JPH0571046B2 (ko) 1993-10-06
NO161622C (no) 1989-09-06
JPS63118318A (ja) 1988-05-23
CA1259993A (en) 1989-09-26
ATE40390T1 (de) 1989-02-15
DK445785D0 (da) 1985-10-01
EP0150278B1 (en) 1989-01-25
NZ210040A (en) 1988-07-28
AU553539B2 (en) 1986-07-17
FI72328B (fi) 1987-01-30
JPS6261210B2 (ko) 1987-12-21
KR890001621B1 (ko) 1989-05-11
FI853711A0 (fi) 1985-09-26
JPS61500317A (ja) 1986-02-27
KR890702423A (ko) 1989-12-23
FI72328C (fi) 1987-05-11
WO1985003514A1 (en) 1985-08-15

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