KR850700251A - 트리아진 그룹 또는 트리아진 그룹과 옥사졸린 그룹 모두를 함유하는 비닐 에스 테르 수지의 제조방법 - Google Patents

트리아진 그룹 또는 트리아진 그룹과 옥사졸린 그룹 모두를 함유하는 비닐 에스 테르 수지의 제조방법

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Publication number
KR850700251A
KR850700251A KR1019850700307A KR850700307A KR850700251A KR 850700251 A KR850700251 A KR 850700251A KR 1019850700307 A KR1019850700307 A KR 1019850700307A KR 850700307 A KR850700307 A KR 850700307A KR 850700251 A KR850700251 A KR 850700251A
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South Korea
Prior art keywords
group
component
triazine
temperature
polyepoxide
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KR1019850700307A
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English (en)
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이. 헤프너. 2세 로버트
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리챠드 지. 워터맨
더 다우 케미칼 캄파니
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Publication of KR850700251A publication Critical patent/KR850700251A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/026—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from the reaction products of polyepoxides and unsaturated monocarboxylic acids, their anhydrides, halogenides or esters with low molecular weight
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/063—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with epihalohydrins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
    • C08G59/1455—Monocarboxylic acids, anhydrides, halides, or low-molecular-weight esters thereof
    • C08G59/1461—Unsaturated monoacids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/3236—Heterocylic compounds
    • C08G59/3245—Heterocylic compounds containing only nitrogen as a heteroatom

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Emergency Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Epoxy Resins (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Fertilizers (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Catalysts (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

내용 없음

Description

트리아진 그룹 또는 트리아진 그룹과 옥사졸린 그룹 모두를 함유하는 비닐 에스테르 수지의 제조방법.
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. (a) 트리아진 그룹-함유 폴리에폭사이드, (b) 트리아진 그룹과 옥사졸린 그룹 모두를 함유하는 폴리에폭사이드, 및 (c)(a)와 (b)의 혼합물중에서 선택된 폴리에폭사이드를, 유효량의 적당한 촉매존재하에, 에폭사이드 그룹당 0.75 내지 1몰의 모노불포화 모노카복실산 또는 모노불포화 모노카복실산의 혼합물과 반응시킴을 특징으로 하는, 트리아진 그룹 또는 트리아진 그룹과 옥사졸린 그룹 모두를 함유하는 비닐에스테르 수지의 제조방법.
  2. 제1항에 있어서, 언급된 트리아진 그룹-함유폴리에폭사이드가, (I)분자당 평균 1개 이상의 방향족 히드록실 그룹을 갖는 물질 1종 이상(A)을, 방향족 히드록실 그룹당 약 0.01 내지 약 1.1몰의 적당한 염기(C)의 존재하에, 반응을 거의 완결시키기에 충분한 온도 및 반응시간동안, 방향족 히드록실 그룹당 0.01 내지 0.95몰의 시아노겐 할라이드 또는 시아노겐 할라이드의 혼합물(B)과 반응시킨 다음, 생성된 시아네이트 혼합물을 회수하고, (II) 단계(I)의 생성물을 적당한 삼량체와 촉매의 존재하에 삼량체와 반응을 거의완결시키기에 충분한 온도 및 반응시간동안 삼량체화 시키고, (III) 단계(II)의 삼량체화 생성물을, 에피클로로히드린과 반응시킨 다음, 염기성-작용물질로 탈-할로겐화 수소화 반응을 시키는 통상의 방법으로 에폭사이드화시킨 다음, 생성된 글리시딜 에테르 생성물을 회수하는 공정에 의해 제조되는 생성물이며, 언급된 트리아진 그룹과 옥사졸린 그룹 모두를 함유하는 폴리에폭사이드가, (1) 분자당 평균 1개 이상의 방향족 히드록실 그룹을 갖는 물질 1종이상(A)을, 반응을 거의 완결시키기에 충분한 온도 및 반응시간동안, 방향족 히드록실 그룹당 0.01 내지 1.1몰의 적당한 염기(C)의 존재하에, 방향족 히드록실 그룹당 0.01 내지 0.95몰의 시아노겐할라이드 또는 시아노겐할라이드의 혼합물(B)과 반응시킨 다음, 생성된 시아네이트 혼합물을 회수하고, (2) 단계 (1)의 생성물을, 코올리그머화 반응을 거의 완결시키기에 충분한 온도 및 반응시간동안, 적당한 코올리고머화 촉매의 존재하에, 에폭시 그룹 대 니트릴 그룹의 몰비가 1:10 내지 1:100인 에폭시 수지(D)와 코올리고머화시켜 제조되는 생성물임을 특징으로 하는 방법.
  3. 제2항에 있어서, 성분(A)중에 함유된 방향족 히드록실그룹:성분(B)의 몰수: 성분(C)의 몰수의 비가 1:0.05:0.05 내지 1:0.55:0.6이고:단계(I) 및 (1)은 10 내지 120분동안 -40° 내지 60℃의 온도에서 수행되며:단계(II)가 15 내지 120분동안 70°내지 350℃의 온도에서 수행되고:에폭시 그룹 대 니트릴 그룹의 몰비가 1:10 내지 1:40임을 특징으로 하는 방법.
  4. 제3항에 있어서, 단계(I) 및 (1)이 10 내지 60분동안 -20℃ 내지 25℃의 온도에서 수행되며:단계(II)가 30 내지 75분동안 70°내지 200℃의 온도에서 수행됨을 특징으로 하는 방법.
  5. 제4항에 있어서, 성분(A)가 명세서에서 일반식(I), (II), (III) 또는 (IV)로 표시되는 화합물이고 성분(B)는 시아노겐클로라이드, 시아노겐브로마이드 또는 이의 혼합물이며:성분(C)는 트리알킬아민이고:성분(D)는 명세서에서 일반식(V), (VI), (VII) 또는 (VIII)에 의해 표시되는 화합물이며, 언급된 삼량체화 또는 코올리고머화 촉매는 카복실산의 금속염이고:언급된 에피할로히드린은 에피클로로히드린이며:언급된 염기성-작용물질이 알칼리 금속 수산화물임을 특징으로 하는 방법.
  6. 제5항에 있어서, 성분(A)는 일반식(II)로 표시되는 화합물이고:성분(C)는 트리에틸아민이며:성분(D)는 일반식(VI)로 표시되는 에폭시수지이고:언급된 삼량체화 또는 코올리고머화 촉매는 나프텐산 코발트이며:언급된 염기성-작용물질이 수산화 나트륨임을 특징으로 하는 방법.
  7. 제6항에 있어서, 성분(A)에서, A는 탄소수 1 내지 12의 2가 탄화수소 그룹이고, n은 1이며:성분(D)에서, A는 각각 독립적으로 탄소수 1 내지 12의 2가 탄화수소그룹이고, n은 1이며, m″는 0 내지 40의 평균값을 가짐을 특징으로하는 방법.
  8. 제7항에 있어서, 성분(A)에서, A는 이소프로필리딘 그룹이고:성분(D)에서, A는 이소프로필리딘 그룹이며, m″는 0.1 내지 20의 평균값을 가짐을 특징으로 하는 방법.
  9. 제1항의 방법에 의해 제조된 비닐에스테르 수지 1 내지 99중량%와 공중합성 에틸렌성 불포화모노머 99 내지 1중량%로 이루어진 조성물.
    ※참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019850700307A 1984-03-19 1984-10-25 트리아진 그룹 또는 트리아진 그룹과 옥사졸린 그룹 모두를 함유하는 비닐 에스 테르 수지의 제조방법 KR850700251A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US06/590,819 US4515934A (en) 1984-03-19 1984-03-19 Vinyl ester resins containing triazine or both triazine and oxazoline groups
US590,819 1984-03-19
PCT/US1984/001725 WO1985004176A1 (en) 1984-03-19 1984-10-25 A process for preparaing vinyl ester resins containing triazine or both triazine and oxazoline groups

Publications (1)

Publication Number Publication Date
KR850700251A true KR850700251A (ko) 1985-12-26

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Application Number Title Priority Date Filing Date
KR1019850700307A KR850700251A (ko) 1984-03-19 1984-10-25 트리아진 그룹 또는 트리아진 그룹과 옥사졸린 그룹 모두를 함유하는 비닐 에스 테르 수지의 제조방법
KR1019850700307A KR870001878B1 (ko) 1984-03-19 1984-10-25 트리아진 그룹 또는 트리아진 그룹과 옥사졸린 그룹 모두를 함유하는 비닐 에스테르 수지의 제조방법

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Country Status (17)

Country Link
US (1) US4515934A (ko)
EP (1) EP0156959B1 (ko)
JP (1) JPS61501396A (ko)
KR (2) KR850700251A (ko)
AT (1) ATE40391T1 (ko)
AU (1) AU555851B2 (ko)
BR (1) BR8407303A (ko)
CA (1) CA1235845A (ko)
DE (1) DE3476408D1 (ko)
DK (1) DK533985A (ko)
ES (1) ES8608003A1 (ko)
FI (1) FI81108C (ko)
IL (1) IL73357A (ko)
NO (1) NO162245C (ko)
NZ (1) NZ210042A (ko)
WO (1) WO1985004176A1 (ko)
ZA (1) ZA848471B (ko)

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DK533985D0 (da) 1985-11-19
ZA848471B (en) 1986-06-25
NO162245B (no) 1989-08-21
BR8407303A (pt) 1986-03-25
FI81108C (fi) 1990-09-10
ATE40391T1 (de) 1989-02-15
FI854184A0 (fi) 1985-10-25
NO854596L (no) 1985-11-18
IL73357A (en) 1988-05-31
AU3556784A (en) 1985-10-11
IL73357A0 (en) 1985-01-31
ES8608003A1 (es) 1986-06-01
DK533985A (da) 1985-11-19
CA1235845A (en) 1988-04-26
NO162245C (no) 1989-11-29
US4515934A (en) 1985-05-07
EP0156959A1 (en) 1985-10-09
ES537222A0 (es) 1986-06-01
EP0156959B1 (en) 1989-01-25
FI854184L (fi) 1985-10-25
DE3476408D1 (en) 1989-03-02
WO1985004176A1 (en) 1985-09-26
JPS61501396A (ja) 1986-07-10
FI81108B (fi) 1990-05-31
KR870001878B1 (ko) 1987-10-20
NZ210042A (en) 1988-07-28
AU555851B2 (en) 1986-10-09

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