KR850004660A - 감-방사선 조성물 - Google Patents

감-방사선 조성물 Download PDF

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KR850004660A
KR850004660A KR1019840008116A KR840008116A KR850004660A KR 850004660 A KR850004660 A KR 850004660A KR 1019840008116 A KR1019840008116 A KR 1019840008116A KR 840008116 A KR840008116 A KR 840008116A KR 850004660 A KR850004660 A KR 850004660A
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onium salt
composition
group
phenolic resin
radiation
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KR1019840008116A
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KR910008778B1 (ko
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뉴우만 스테펜
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도날드 밀러 셀
미네소타 마이닝 앤드 매뉴팩츄어링 컴페니
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    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/027Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • G03F7/028Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
    • G03F7/029Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C1/00Forme preparation
    • B41C1/10Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme
    • B41C1/1008Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by removal or destruction of lithographic material on the lithographic support, e.g. by laser or spark ablation; by the use of materials rendered soluble or insoluble by heat exposure, e.g. by heat produced from a light to heat transforming system; by on-the-press exposure or on-the-press development, e.g. by the fountain of photolithographic materials
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/0045Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C2210/00Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
    • B41C2210/02Positive working, i.e. the exposed (imaged) areas are removed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C2210/00Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
    • B41C2210/04Negative working, i.e. the non-exposed (non-imaged) areas are removed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C2210/00Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
    • B41C2210/06Developable by an alkaline solution
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C2210/00Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
    • B41C2210/22Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation characterised by organic non-macromolecular additives, e.g. dyes, UV-absorbers, plasticisers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C2210/00Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
    • B41C2210/26Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation characterised by a macromolecular compound or binder obtained by reactions not involving carbon-to-carbon unsaturated bonds
    • B41C2210/262Phenolic condensation polymers, e.g. novolacs, resols

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Optics & Photonics (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials For Photolithography (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)
  • Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Printing Plates And Materials Therefor (AREA)

Abstract

내용 없음

Description

감-방사선 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 따른 조성물에 있어서 비노출 영역과 노출 영역간의 용해도 차이를 나타낸 그라프.

Claims (17)

  1. 알칼리-용해성 페놀계수지 및 방-사선 오늄염으로 이루어져 있으며, 광 용해성임을 특징으로 한 -감방사선 조성.
  2. 제1항에 있어서, 오늄염이 요오드늄, 술포늄, 포스포늄, 브로모늄, 클로로늄, 옥시술폭소늄, 옥시술포늄, 술폭소늄, 셀레노늄, 텔루로늄 밑 아르소늄염 중에서 선택된 조성물.
  3. 제1항 또는 2항에 있어서, 페놀계 수지가 노볼락수지이며 오늄염이 페놀계 수지와 오늄염 총 중량의 1내지 40중량%인 조성물.
  4. 제1항 또는 2항에 있어서, 페놀계 수지가 레롤 수지이며 오늄염이 페놀계 수지와 오늄염 총 중량의 5내지 40중량%인 조성물.
  5. 제1항 내지 4항중의 어느 하나에 있어서, 오늄염이 다음 일반식(I)-(V) 및 중합체(VI)로 표시되는 것중의 하나인 조성물.
    위의 식에서, R1,R2및 R3는 임의로 치환된 방향록 그룹이며, (단, 일반식 (Ⅲ), (IV) 및 (V)에서 이들 각각은 임의로 치환된 지방록 그룹일 수 있다.) : Q는 탄소-결합이거나 O,S, 〉S=O, 〉C=O, O또는N-R6중에서 선택된 연결 그룹이며, R4및 R5는, 독립적으로, H,C1-C4알킬그룹, 및 C2-C4알케닐 그룹중에서 선택되며; R6는 C6-C20아릴그룹이거나 C2-C20아실그룹이며; |는 음이온 이며 : Ar1및 Ar2는, 독립적으로, 임의로 치환된 방향록 그룹을 나타내고 또한 서로 임의로 연결되어 고리구조 내에 요오드 원자를 포함시키는 방향록 그룹을 나타낸다.
  6. 제5항에 있어서, 음이온의 할라이드,(여기서 R8은 임의로 치환된 알킬 또는 페닐그룹임), 및 할로겐-함유 착물이온 중에서 선택된 조성물.
  7. 제1항 내지 6항중의 어느 하나에 있어서, 페놀계 수지, 오늄염 및 스펙트럼 감광제 총 중량의 최고 10중량%에 달하는 스펙트럼 감광제로 추가로 이루어진 조성물.
  8. 제7항에 있어서, 스펙트럼 감광제가 디페닐메탄, 크사텐, 아크리딘, 메틴 및 폴리메틴(옥소놀, 시아닌 및 메로시아닌을 포함) 염료, 티아롤, 티아진, 아진, 아미노케톤, 프로피린, 착색된 방향록 다환 탄화수소, 파라-치환된 아미노스티릴 화합물 아미노트리아질 메탄, 폴리아릴렌, 폴리아릴폴리엔, 2,5-디페닐이소벤조푸란, 2,5-디아릴사이클로펜타디엔, 다아릴푸란, 디아릴티오푸란, 디아릴피롤, 폴리아릴페닐렌, 코우마린 및 폴리아릴-2-피라졸린 중에서 선택된 조성물.
  9. 제7항 또는 8항에 있어서, 스펙트럼 감광제가 다음 일반식 (Ⅶ) 또는 (Ⅷ)로 표시되는 조성물.
    위의 식에서, R7은 C1-C6알킬그룹을 나타내며 : Y는 4-퍼플루오로에틸사이클로 헥실술포네이트 또는를 나타내고, P는 1 또는 2의 수이다.
  10. 제1항 또는 9항중의 어느 하나에 있어서, 페놀계수지, 오늄염 및 아민 총 중량의 최고 25중량 %에 달하는 아민으로 추가로 이루어진 조성물.
  11. 제10항에 있어서, 아민/오늄염의 몰비가 대략 1 : 1인 조성물.
  12. 제10항 또는 11항에 있어서, 아민이 트리 -n-부틸아민 또는 비스 (4-디메틸아미노페닐) 메탄인 조성물
  13. 기판상에 피복된 제1항 내지 12항중의 어느 하나의 조성물 층으로 이루어진 감-방사선 엘레엔트.
  14. 제13항에 있어서, 기판이 종이, 알루미늄, 구리, 구리-에폭시 적층판, 폴리에스테르 필름 또는 실리카인 엘레엔트.
  15. 제13항 또는 14항에 따른 엘레엔트를 화학 방사선에 영상방향 노출 시키고, 인쇄판을 알칼리계 현상액으로 현상시켜 조성물을 조사영역에서 제거해 상기 영상을 형성시키는 석판 영상의 형성 방법.
  16. 제13항 또는 14항에 따른 엘레엔트를 화학 방사선에 영상방향 노출시키고; 엘레엔트를 가열해 조사 영역내의 피복물을 알칼리에 불용성인 형태로 전환시키고; 추가로 모든 엘레엔트를 화학방사선에 노출시켜 사전에 노출되지 않은 영역을 알칼리-용해성으로 만들고; 엘레엔트를 알칼리계 현상액으로 현상시켜 알칼리 용해성인 엘레엔트의 영역에서 피복물을 제거해 영상을 형성시키는 석판 영상의 형성방법.
  17. 제15항 또는 16항에 있어서, 현상액이 수성 나트륨 메타실리게이트인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840008116A 1983-12-20 1984-12-19 감방사선 조성물 KR910008778B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB838333901A GB8333901D0 (en) 1983-12-20 1983-12-20 Radiationsensitive compositions
GB8333901 1983-12-20
GB33901 1983-12-20

Publications (2)

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KR850004660A true KR850004660A (ko) 1985-07-25
KR910008778B1 KR910008778B1 (ko) 1991-10-21

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EP (1) EP0146411B1 (ko)
JP (1) JP2577718B2 (ko)
KR (1) KR910008778B1 (ko)
AR (1) AR244895A1 (ko)
AU (1) AU583485B2 (ko)
BR (1) BR8406563A (ko)
CA (1) CA1262793A (ko)
DE (1) DE3484868D1 (ko)
ES (1) ES8705302A1 (ko)
GB (1) GB8333901D0 (ko)
ZA (1) ZA849517B (ko)

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DE2718254C3 (de) * 1977-04-25 1980-04-10 Hoechst Ag, 6000 Frankfurt Strahlungsempfindliche Kopiermasse
JPS56501064A (ko) * 1979-08-17 1981-07-30
DE3107109A1 (de) * 1981-02-26 1982-09-09 Hoechst Ag, 6000 Frankfurt Lichtempfindliches gemisch und daraus hergestelltes kopiermaterial
US4500629A (en) * 1982-04-08 1985-02-19 Ciba-Geigy Corporation Method of forming images from liquid masses
JPS6071657A (ja) * 1983-09-27 1985-04-23 Agency Of Ind Science & Technol 感光性樹脂組成物

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DE3484868D1 (de) 1991-09-05
GB8333901D0 (en) 1984-02-01
JP2577718B2 (ja) 1997-02-05
CA1262793A (en) 1989-11-07
AR244895A1 (es) 1993-11-30
KR910008778B1 (ko) 1991-10-21
ES8705302A1 (es) 1987-05-01
ES538520A0 (es) 1987-05-01
BR8406563A (pt) 1985-10-15
JPS60175046A (ja) 1985-09-09
EP0146411A3 (en) 1987-02-04
AU583485B2 (en) 1989-05-04
EP0146411B1 (en) 1991-07-31
AU3648184A (en) 1985-06-27
EP0146411A2 (en) 1985-06-26
ZA849517B (en) 1986-07-30

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