KR840009336A - Ivb족 금속이온과 폴리알케닐폐놀 유도체로 금속을 처리하는 방법 - Google Patents
Ivb족 금속이온과 폴리알케닐폐놀 유도체로 금속을 처리하는 방법 Download PDFInfo
- Publication number
- KR840009336A KR840009336A KR1019840002499A KR840002499A KR840009336A KR 840009336 A KR840009336 A KR 840009336A KR 1019840002499 A KR1019840002499 A KR 1019840002499A KR 840002499 A KR840002499 A KR 840002499A KR 840009336 A KR840009336 A KR 840009336A
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- South Korea
- Prior art keywords
- solution
- alkyl
- compound
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- mixtures
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- 229910052751 metal Inorganic materials 0.000 title claims 4
- 239000002184 metal Substances 0.000 title claims 4
- 229910021645 metal ion Inorganic materials 0.000 title claims 3
- 150000002739 metals Chemical class 0.000 title 1
- 150000002989 phenols Chemical class 0.000 title 1
- 239000000243 solution Substances 0.000 claims 18
- 150000001875 compounds Chemical class 0.000 claims 12
- 229910052739 hydrogen Inorganic materials 0.000 claims 6
- 239000001257 hydrogen Substances 0.000 claims 6
- 239000000203 mixture Substances 0.000 claims 6
- 125000000217 alkyl group Chemical group 0.000 claims 5
- 239000007864 aqueous solution Substances 0.000 claims 5
- 125000003118 aryl group Chemical group 0.000 claims 4
- 229920000642 polymer Polymers 0.000 claims 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims 3
- 150000002431 hydrogen Chemical group 0.000 claims 3
- 239000000178 monomer Substances 0.000 claims 3
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- 239000001263 FEMA 3042 Substances 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Penta-digallate-beta-D-glucose Natural products OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 claims 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 125000004103 aminoalkyl group Chemical group 0.000 claims 2
- 229910052735 hafnium Inorganic materials 0.000 claims 2
- -1 hafnium ions Chemical class 0.000 claims 2
- 229910052698 phosphorus Inorganic materials 0.000 claims 2
- 239000011574 phosphorus Substances 0.000 claims 2
- 239000000049 pigment Substances 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 claims 2
- 229940033123 tannic acid Drugs 0.000 claims 2
- 235000015523 tannic acid Nutrition 0.000 claims 2
- 229920002258 tannic acid Polymers 0.000 claims 2
- 229920001864 tannin Polymers 0.000 claims 2
- 239000001648 tannin Substances 0.000 claims 2
- 235000018553 tannin Nutrition 0.000 claims 2
- 150000003585 thioureas Chemical class 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- 235000013311 vegetables Nutrition 0.000 claims 2
- 229910052726 zirconium Inorganic materials 0.000 claims 2
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims 1
- 229920001665 Poly-4-vinylphenol Polymers 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims 1
- 239000003973 paint Substances 0.000 claims 1
- 150000003335 secondary amines Chemical class 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Treatment Of Metals (AREA)
- Paints Or Removers (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (20)
- 티탄, 질코늄 및 하프늄 이온과 그의 혼합물로 구성된 군으로부터 선택된 금속 이온 약 0.001-1.0%와 하기 일반식의 중합체, 그의 산성염 및 그 혼합물로 구성된 군으로부터 선택된 가용성 또는 분산성 화합물 유효량으로 구성된 수용액.상기식에서 R1-R3는 수소 또는 C1-5알킬기이며 ; Y는 각기 수소, Z, CR|4R5OR6, CH2Cl 또는 C1-18의 알킬이나 아릴기이며 ; Z은이며 ; R4-R10은 수소, 알킬, 아릴, 하이드록시알킬, 아미노-알킬, 메르캅로-알킬 또는 포스포-알킬이며, 여기서 R4-R10은 탄소쇄 길이가 화합물이 용해되거나 분산되지 않는 길이까지이며, n은 숫자 2부터 중합체가 용해되거나 분산되지 않는 수까지이다.
- 제1항에 있어서 상기 용액이 수용액이며 단량체당 Z의 몰퍼센트가 약 10-200%인 용액.
- 제2항에 있어서 단량체당 Z의 몰퍼센트가 약 50-150%인 용액.
- 제2항에 있어서 PH가 약 0.5-12인 용액.
- 제4항에 있어서 PH가 약 2.0-8.0인 용액.
- 제5항에 있어서 상기 화합물이 약 0.01%-5%양으로 존재하는 용액.
- 제6항에 있어서 상기 화합물이 약 0.025-1%양으로 존재하는 용액.
- 제2항에 있어서 Z이인 용액.
- 제2항에 있어서 Z이인 용액.
- 제2항에 있어서 상기 화합물이 폴리-4-비닐페놀, 포름알데히드 및 2급 아민의 반응생성물인 용액.
- 제2항에 있어서 티오우레아, 티오우레아유도체, 탄닌산, 식물성탄닌 및 그의 혼합물로 구성된 군으로부터 선택된 화합물 약 0.01-4.0%를 더 함유하는 수용액.
- 제1항에 있어서 안료를 더 함유하는 용액.
- 제12항에 있어서 상기 용액이 페인트인 용액.
- 금속표면을 티탄, 질코늄 및 하프늄이온과 그의 혼합물로 구성된 군으로부터 선택된 금속이온 약 0.001-1.0%와 하기 일반식의 중합체, 그의 산성염 및 그 혼합물로 구성된 군으로부터 선택된 가용성 또는 분산성 화합물 유효량으로 구성된 수용액과 접촉시키는 것으로 구성된 금속표면을 처리하는 방법.상기식에서 R1-R3는 수소 또는 C1-5알킬기이며 ; Y는 각기 수소 Z, CR4R5OR6, CH2Cl 또는 C1-18의 알킬이나 아릴기이며 ; Z은이며 ; R4-R10은 수소, 알킬, 아릴, 하이드로시알킬, 아미노-알킬, 메르캅로-알킬 또는 포스포-알킬이며, 여기서 R4-R10은 탄소쇄 길이가 화합물이 용해되거나 분산되지 않는 길이까지이며, n은 숫자 2부터 중합체가 용해되거나 분산되지 않는 수까지이다.
- 제14항에 있어서 용액이 수용액이며 단량체당 Z의 몰퍼센트가 약 10-20%인 방법.
- 제15항에 있어서 용액의 Z가 약 0.5-12인 방법.
- 제16항에 있어서 화합물이 용액중에 약 0.01-5%양으로 존재하는 방법.
- 제15항에 있어서 용액이 티오우레아, 티오우레아 유도체, 탄닌산, 식물성탄닌 및 그의 혼합물로 구성된 군으로부터 선택된 화합물 약 0.01-4.0%를 더 함유하는 방법.
- 제14항에 있어서 용액이 안료를 더 함유하는 방법.
- 제14항에 있어서 처리된 금속표면이 알루미늄 금속표면인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US490,580 | 1983-05-09 | ||
US06/490,580 US4457790A (en) | 1983-05-09 | 1983-05-09 | Treatment of metal with group IV B metal ion and derivative of polyalkenylphenol |
US490580 | 1983-05-09 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR840009336A true KR840009336A (ko) | 1984-12-26 |
KR910006787B1 KR910006787B1 (ko) | 1991-09-02 |
Family
ID=23948650
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019840002499A KR910006787B1 (ko) | 1983-05-09 | 1984-05-09 | Ivb족 금속이온과 폴리-알케닐페놀 유도체로 금속을 처리하는 방법 |
Country Status (11)
Country | Link |
---|---|
US (1) | US4457790A (ko) |
JP (1) | JPH0742423B2 (ko) |
KR (1) | KR910006787B1 (ko) |
AR (1) | AR247585A1 (ko) |
AU (1) | AU575563B2 (ko) |
BR (1) | BR8402194A (ko) |
CA (1) | CA1214036A (ko) |
MX (1) | MX164875B (ko) |
NZ (1) | NZ208079A (ko) |
PH (1) | PH21626A (ko) |
ZA (1) | ZA843491B (ko) |
Families Citing this family (87)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59197575A (ja) * | 1983-04-19 | 1984-11-09 | Nippon Paint Co Ltd | 耐食性金属表面処理用組成物 |
US4579927A (en) * | 1983-09-26 | 1986-04-01 | Dresser Industries, Inc. | Copolymers of flavanoid tannins and acrylic monomers |
US4496404A (en) * | 1984-05-18 | 1985-01-29 | Parker Chemical Company | Composition and process for treatment of ferrous substrates |
US4617068A (en) * | 1984-05-18 | 1986-10-14 | Parker Chemical Company | Composition and process for treatment of ferrous substrates |
AU4751885A (en) * | 1984-10-09 | 1986-04-17 | Parker Chemical Company | Treating extruded aluminium metal surfaces |
US4795506A (en) * | 1986-07-26 | 1989-01-03 | Detrex Corporation | Process for after-treatment of metals using 2,2-bis(4-hydroxyphenyl)alkyl poly derivatives |
US5039770A (en) * | 1987-12-04 | 1991-08-13 | Henkel Corporation | Treatment and after-treatment of metal with polyphenol compounds |
US4963596A (en) * | 1987-12-04 | 1990-10-16 | Henkel Corporation | Treatment and after-treatment of metal with carbohydrate-modified polyphenol compounds |
US4970264A (en) * | 1987-12-04 | 1990-11-13 | Henkel Corporation | Treatment and after-treatment of metal with amine oxide-containing polyphenol compounds |
US4978399A (en) * | 1988-01-04 | 1990-12-18 | Kao Corporation | Metal surface treatment with an aqueous solution |
US5246507A (en) * | 1988-01-04 | 1993-09-21 | Kao Corporation | Metal surface treatment and aqueous solution therefor |
US4872960A (en) * | 1988-07-18 | 1989-10-10 | Hoechst Celanese Corporation | Protective coatings of a cured hydroxystyrene mannich base and blocked polyisocyantes |
US4877502A (en) * | 1988-07-18 | 1989-10-31 | Hoechst Celanese Corporation | Poly(epoxide) coatings containing a mannich base of a hydroxystyrene containing polymer |
US4944812A (en) * | 1988-11-16 | 1990-07-31 | Henkel Corporation | Tannin mannich adducts for improving corrosion resistance of metals |
US5252391A (en) * | 1988-12-01 | 1993-10-12 | Nippon Seiko Kabushiki Kaisha | Surface treated sliding or rolling contact element and rolling bearing |
US5009962A (en) * | 1989-01-04 | 1991-04-23 | Nippon Paint Co., Ltd. | Surface treatment chemical and bath for forming hydrophilic coatings and method of surface-treating aluminum members |
US4973359A (en) * | 1989-01-04 | 1990-11-27 | Nippon Paint Co., Ltd. | Surface treatment chemical and bath for forming hydrophilic coatings and method of surface-treating aluminum members |
US4992116A (en) * | 1989-04-21 | 1991-02-12 | Henkel Corporation | Method and composition for coating aluminum |
US5149382A (en) * | 1989-10-25 | 1992-09-22 | Ppg Industries, Inc. | Method of pretreating metal by means of composition containing S-triazine compound |
JPH0418413A (ja) * | 1990-01-03 | 1992-01-22 | Nippon Parkerizing Co Ltd | プラスチック及び塗装物表面に対する後処理剤 |
JPH03207766A (ja) * | 1990-01-10 | 1991-09-11 | Nippon Parkerizing Co Ltd | ぶりきdi缶の表面処理方法 |
CA2085489C (en) * | 1990-06-19 | 2000-12-12 | Tomoyuki Aoki | Liquid composition and process for treating aluminum or tin cans to impart corrosion resistance and mobility thereto |
US5370909A (en) * | 1990-06-19 | 1994-12-06 | Henkel Corporation | Liquid composition and process for treating aluminum or tin cans to impart corrosion resistance and mobility thereto |
US5089064A (en) * | 1990-11-02 | 1992-02-18 | Henkel Corporation | Process for corrosion resisting treatments for aluminum surfaces |
US5209788A (en) * | 1990-11-21 | 1993-05-11 | Ppg Industries, Inc. | Non-chrome final rinse for phosphated metal |
JPH04187782A (ja) * | 1990-11-21 | 1992-07-06 | Nippon Parkerizing Co Ltd | ぶりきdi缶用表面処理液 |
GB9108222D0 (en) * | 1991-04-17 | 1991-06-05 | Ici Plc | Composition and method |
ATE132484T1 (de) * | 1991-04-18 | 1996-01-15 | Zeneca Ltd | Bisphenolderivate und ihre verwendung als beschichtungsmittel |
US5242714A (en) * | 1991-12-20 | 1993-09-07 | Henkel Corporation | Process for forming protective base coatings on metals |
US5550004A (en) * | 1992-05-06 | 1996-08-27 | Ocg Microelectronic Materials, Inc. | Chemically amplified radiation-sensitive composition |
US5340687A (en) * | 1992-05-06 | 1994-08-23 | Ocg Microelectronic Materials, Inc. | Chemically modified hydroxy styrene polymer resins and their use in photoactive resist compositions wherein the modifying agent is monomethylol phenol |
ZA934846B (en) * | 1992-07-08 | 1994-02-03 | Henkel Corp | Aqueous lubrication and surface conditioning for formed metal surfaces |
DE4317217A1 (de) * | 1993-05-24 | 1994-12-01 | Henkel Kgaa | Chromfreie Konversionsbehandlung von Aluminium |
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-
1983
- 1983-05-09 US US06/490,580 patent/US4457790A/en not_active Expired - Lifetime
-
1984
- 1984-05-04 CA CA000453607A patent/CA1214036A/en not_active Expired
- 1984-05-07 NZ NZ208079A patent/NZ208079A/en unknown
- 1984-05-08 AU AU27796/84A patent/AU575563B2/en not_active Ceased
- 1984-05-08 MX MX201274A patent/MX164875B/es unknown
- 1984-05-09 AR AR84296592A patent/AR247585A1/es active
- 1984-05-09 JP JP59092730A patent/JPH0742423B2/ja not_active Expired - Lifetime
- 1984-05-09 ZA ZA843491A patent/ZA843491B/xx unknown
- 1984-05-09 BR BR8402194A patent/BR8402194A/pt not_active IP Right Cessation
- 1984-05-09 PH PH30661A patent/PH21626A/en unknown
- 1984-05-09 KR KR1019840002499A patent/KR910006787B1/ko not_active IP Right Cessation
Also Published As
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MX164875B (es) | 1992-09-29 |
PH21626A (en) | 1987-12-11 |
ZA843491B (en) | 1984-12-24 |
JPH0742423B2 (ja) | 1995-05-10 |
AU2779684A (en) | 1984-11-15 |
KR910006787B1 (ko) | 1991-09-02 |
NZ208079A (en) | 1987-09-30 |
JPS59207972A (ja) | 1984-11-26 |
CA1214036A (en) | 1986-11-18 |
AR247585A1 (es) | 1995-01-31 |
BR8402194A (pt) | 1984-12-18 |
US4457790A (en) | 1984-07-03 |
AU575563B2 (en) | 1988-08-04 |
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