KR840004707A - 사이클로헥사놀 및 사이클로헥사논의 제조방법 - Google Patents

사이클로헥사놀 및 사이클로헥사논의 제조방법 Download PDF

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KR840004707A
KR840004707A KR1019830001703A KR830001703A KR840004707A KR 840004707 A KR840004707 A KR 840004707A KR 1019830001703 A KR1019830001703 A KR 1019830001703A KR 830001703 A KR830001703 A KR 830001703A KR 840004707 A KR840004707 A KR 840004707A
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mixture
oxidizing mixture
water phase
oxidation
treatment
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KR1019830001703A
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KR870000056B1 (ko
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게라르두스 후베르투스 마리아 후스만(외 2) 요하네스
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하. 브로카데스 짜알베르크, 하. 베. 반 리우벤
스태미카본 베. 뷔
하. 베. 반 리우벤
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Application filed by 하. 브로카데스 짜알베르크, 하. 베. 반 리우벤, 스태미카본 베. 뷔, 하. 베. 반 리우벤 filed Critical 하. 브로카데스 짜알베르크, 하. 베. 반 리우벤
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
    • C07C35/08—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

사이클로헥사놀 및 사이클로헥사논의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 산소분자 포함가스로 사이클로헥산을 산화하여 사이클로헥실하이드로퍼록사이드가 함유된 산화 혼합물을 생성하고, 이 산화 혼합물을 알칼리에탈하이드록사이드 수용액 존재하에서 금속염으로 처리하여 사이클로헥실 하이드로 퍼록사이드를 분해함으로써 사이클로헥사놀과 사이클로헥사논을 제조하는 방법에 있어서, 산화 혼합물의 처리가 70°∼115℃의 온도에서 이루어짐을 특징으로 하는 사이클로헥사놀및 사이클로헥사논의 제조방법.
  2. 상기의 산화반응이 역류 컬럼에서 일어남을 특징으로 하는 특허청구범위 제1항에 따른 방법.
  3. 상기 산화 혼합물의 처리에 쓰이는 알칼리 메탈하이드록사이드의 양은 상기 분해 즉 수상안의 OH+농도가 0.01N이하로 되도록함을 특징으로 하는 특허청구범위 제2항에 따른 방법.
  4. 교반 탱크 반응기 내의 산화 혼합물 처리에 쓰이는 알칼리에탈하이드록사이드의 양은 분해 후 수상안의 OH-농도가 1∼1.8N이 되도록 함을 특징으로 하는 특허청구의 제1항에 따른 방법.
  5. 산화 혼합물 처리에 쓰이는 금속염은 코발트 또는 크롬염임을 특징으로 하는 특허청구 제1∼4항에 따른 방법.
  6. 사용되는 금속염의 양이 수상에 관한 금속환산으로 중량의 1∼200ppm임을 특징으로 하는 특허청구범의 제1∼5항에 따른 방법.
  7. 산화 혼합물의 처리시 냉각환유 또는 산화 혼합물의 냉각에 의해 바람직한 온도가 유지됨을 특징으로 하는 특허청구범위 제1∼6항에 따른 방법.
  8. 생성된 유기상 1ℓ당 0.01∼0.5ℓ의 수상이 적용됨으로써 산화 혼합물의 처리가 이루어짐을 특징으로 하는 특허청구범위 제1∼7항에 따른 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830001703A 1982-04-23 1983-04-22 사이클로 헥사놀 및 사이클로 헥사논의 제조방법 KR870000056B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL8201695A NL8201695A (nl) 1982-04-23 1982-04-23 Werkwijze voor de bereiding van cyclohexanol en cyclohexanon.
NL8201695 1982-04-23

Publications (2)

Publication Number Publication Date
KR840004707A true KR840004707A (ko) 1984-10-24
KR870000056B1 KR870000056B1 (ko) 1987-02-09

Family

ID=19839643

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019830001703A KR870000056B1 (ko) 1982-04-23 1983-04-22 사이클로 헥사놀 및 사이클로 헥사논의 제조방법

Country Status (9)

Country Link
EP (1) EP0092867B1 (ko)
JP (1) JPH0615484B2 (ko)
KR (1) KR870000056B1 (ko)
BR (1) BR8302088A (ko)
CA (1) CA1244475A (ko)
DE (1) DE3364495D1 (ko)
ES (1) ES8402249A1 (ko)
NL (1) NL8201695A (ko)
PT (1) PT76592B (ko)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3513568A1 (de) * 1985-04-16 1986-10-16 Basf Ag, 6700 Ludwigshafen Verfahren zur aufarbeitung von cyclohexanol, cyclohexanon sowie cyclohexylhydroperoxid enthaltenden reaktionsgemischen
DE3601218A1 (de) * 1986-01-17 1987-07-23 Basf Ag Verfahren zur aufarbeitung von cyclohexylhydroperoxid, cyclohexanol und cyclohexanon enthaltenden reaktionsgemischen
JP2562150B2 (ja) * 1986-10-23 1996-12-11 バスフ アクチェンゲゼルシャフト シクロヘキシルヒドロペルオキシドを含有する反応混合物の後処理法
DE4104419A1 (de) * 1991-02-14 1992-08-20 Basf Ag Kreislaufverfahren zur herstellung von cyclohexenoxid sowie cyclohexanol und cyclohexanon
BE1007904A3 (nl) * 1993-12-23 1995-11-14 Dsm Nv Werkwijze voor de bereiding van een alkanol en/of een alkanon.
BE1009662A3 (nl) * 1995-10-13 1997-06-03 Dsm Nv Werkwijze voor het ontleden van cycloalkylhydroperoxide.
BE1011041A3 (nl) * 1997-03-12 1999-04-06 Dsm Nv Werkwijze voor het ontleden van cycloalkylhydroperoxide.
US5892122A (en) * 1997-08-25 1999-04-06 E. I. Du Pont De Nemours And Company Method for making cyclohexanol and cyclohexanone
US6700022B2 (en) * 2002-06-05 2004-03-02 E. I. Du Pont De Nemours And Company High yield cyclohexyl hydroperoxide decompostition process
CN101087747B (zh) * 2004-12-22 2011-06-08 帝斯曼知识产权资产管理有限公司 分解环己基过氧化氢的方法
DE602006005898D1 (de) 2005-01-25 2009-05-07 Dsm Ip Assets Bv Verfahren zur herstellung von cyclohexanon und cyclohexanol
TW200944497A (en) * 2008-04-17 2009-11-01 China Petrochemical Dev Corp System and method for producing naphthenone
CN101607875B (zh) * 2008-06-17 2012-07-25 中国石油化学工业开发股份有限公司 制造环烷酮的方法
FR2952055B1 (fr) * 2009-11-05 2011-11-11 Rhodia Operations Procede de preparation de composes hydroperoxyde d'alkyle
EA027382B1 (ru) 2011-12-07 2017-07-31 Кап Iii Б.В. Способ получения смеси, содержащей циклогексанол и циклогексанон
CN103987683B (zh) 2011-12-07 2015-12-02 帝斯曼知识产权资产管理有限公司 包含环己醇和环己酮的混合物的制备方法
JP6565926B2 (ja) 2014-10-31 2019-09-04 宇部興産株式会社 ケトン及び／又はアルコールの製造方法及びそのシステム
US10392334B2 (en) 2015-12-07 2019-08-27 Ube Industries, Ltd. Method for producing ketone and/or alcohol, and system thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2127520A1 (de) * 1971-06-03 1972-12-14 Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Cycloalkanol- und Cycloalkanon-Gemischen
NL7506790A (nl) * 1975-06-07 1976-12-09 Stamicarbon Werkwijze voor het bereiden van cycloalkanonen en cycloalkanolen.
NL7802125A (nl) * 1978-02-25 1979-08-28 Stamicarbon Werkwijze voor het bereiden van cycloalkanolen en cycloalkanonen.

Also Published As

Publication number Publication date
ES521744A0 (es) 1984-01-16
JPS58192839A (ja) 1983-11-10
DE3364495D1 (en) 1986-08-21
ES8402249A1 (es) 1984-01-16
EP0092867A1 (en) 1983-11-02
PT76592A (en) 1983-05-01
PT76592B (en) 1985-12-10
EP0092867B1 (en) 1986-07-16
CA1244475A (en) 1988-11-08
NL8201695A (nl) 1983-11-16
JPH0615484B2 (ja) 1994-03-02
BR8302088A (pt) 1983-12-27
KR870000056B1 (ko) 1987-02-09

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