KR20230162097A - 망간의 제거 방법 및 산화철의 제조 방법 - Google Patents
망간의 제거 방법 및 산화철의 제조 방법 Download PDFInfo
- Publication number
- KR20230162097A KR20230162097A KR1020237037340A KR20237037340A KR20230162097A KR 20230162097 A KR20230162097 A KR 20230162097A KR 1020237037340 A KR1020237037340 A KR 1020237037340A KR 20237037340 A KR20237037340 A KR 20237037340A KR 20230162097 A KR20230162097 A KR 20230162097A
- Authority
- KR
- South Korea
- Prior art keywords
- manganese
- ions
- solution
- iron
- mass
- Prior art date
Links
- 239000011572 manganese Substances 0.000 title claims abstract description 96
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 69
- 238000000034 method Methods 0.000 title claims abstract description 39
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 title claims description 90
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 122
- 239000000243 solution Substances 0.000 claims abstract description 98
- 229910052742 iron Inorganic materials 0.000 claims abstract description 90
- -1 iron ions Chemical class 0.000 claims abstract description 77
- 229910001437 manganese ion Inorganic materials 0.000 claims abstract description 56
- 239000012670 alkaline solution Substances 0.000 claims abstract description 25
- 239000002244 precipitate Substances 0.000 claims abstract description 20
- 239000007800 oxidant agent Substances 0.000 claims abstract description 15
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 9
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 17
- 238000011084 recovery Methods 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 6
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 claims description 6
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
- 239000002253 acid Substances 0.000 description 58
- 239000002699 waste material Substances 0.000 description 29
- 238000006386 neutralization reaction Methods 0.000 description 25
- 229910000831 Steel Inorganic materials 0.000 description 24
- 239000010959 steel Substances 0.000 description 24
- 239000000047 product Substances 0.000 description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 14
- 239000007788 liquid Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 10
- 238000000926 separation method Methods 0.000 description 10
- 239000000126 substance Substances 0.000 description 9
- 239000012535 impurity Substances 0.000 description 7
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 229910021577 Iron(II) chloride Inorganic materials 0.000 description 5
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
- 238000007664 blowing Methods 0.000 description 5
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 5
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 230000033116 oxidation-reduction process Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000010979 pH adjustment Methods 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 239000010926 waste battery Substances 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B47/00—Obtaining manganese
- C22B47/0018—Treating ocean floor nodules
- C22B47/0045—Treating ocean floor nodules by wet processes
- C22B47/0054—Treating ocean floor nodules by wet processes leaching processes
- C22B47/0063—Treating ocean floor nodules by wet processes leaching processes with acids or salt solutions
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/02—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
- C02F1/62—Heavy metal compounds
- C02F1/64—Heavy metal compounds of iron or manganese
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B47/00—Obtaining manganese
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Ocean & Marine Engineering (AREA)
- Oceanography (AREA)
- Removal Of Specific Substances (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2021137793 | 2021-08-26 | ||
| JPJP-P-2021-137793 | 2021-08-26 | ||
| PCT/JP2022/031111 WO2023026931A1 (ja) | 2021-08-26 | 2022-08-17 | マンガンの除去方法および酸化鉄の製造方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20230162097A true KR20230162097A (ko) | 2023-11-28 |
Family
ID=85321950
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020237037340A KR20230162097A (ko) | 2021-08-26 | 2022-08-17 | 망간의 제거 방법 및 산화철의 제조 방법 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP7276626B1 (zh) |
| KR (1) | KR20230162097A (zh) |
| CN (1) | CN117242196A (zh) |
| WO (1) | WO2023026931A1 (zh) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5229416B1 (ja) | 2011-06-29 | 2013-07-03 | Ｊｆｅスチール株式会社 | マンガン回収方法 |
| JP2015206077A (ja) | 2014-04-21 | 2015-11-19 | Ｊｆｅスチール株式会社 | 廃乾電池からの資源の分離、回収方法および分離、回収設備および回収物 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19812260A1 (de) * | 1998-03-20 | 1999-09-23 | Bayer Ag | Verfahren zur Herstellung von Eisenoxid-Pigmenten aus Dünnsäure aus der TiO¶2¶-Herstellung |
| US6682644B2 (en) * | 2002-05-31 | 2004-01-27 | Midamerican Energy Holdings Company | Process for producing electrolytic manganese dioxide from geothermal brines |
| JP3843052B2 (ja) * | 2002-09-20 | 2006-11-08 | 新日本製鐵株式会社 | 金属含有排水中の有価金属の回収方法および利用方法 |
| JP5444024B2 (ja) * | 2010-01-29 | 2014-03-19 | Ｊｆｅエンジニアリング株式会社 | 亜鉛めっき廃液の資源化方法 |
| DK2882880T3 (en) * | 2012-08-09 | 2018-01-15 | Deepgreen Eng Pte Ltd | Processing of manganese-containing materials |
| JP6289411B2 (ja) * | 2015-03-31 | 2018-03-07 | Ｊｘ金属株式会社 | 鉄含有溶液からの鉄の除去方法及び、有価金属の回収方法 |
| JP7232119B2 (ja) * | 2019-04-26 | 2023-03-02 | Ｊｘ金属株式会社 | リチウムイオン電池廃棄物の処理方法および、硫酸塩の製造方法 |
| CN110066925A (zh) * | 2019-04-28 | 2019-07-30 | 浙江天能新材料有限公司 | 一种废旧镍钴锰三元锂电池中有价金属的回收方法 |
-
2022
- 2022-08-17 JP JP2022564118A patent/JP7276626B1/ja active Active
- 2022-08-17 WO PCT/JP2022/031111 patent/WO2023026931A1/ja active Application Filing
- 2022-08-17 KR KR1020237037340A patent/KR20230162097A/ko unknown
- 2022-08-17 CN CN202280032523.7A patent/CN117242196A/zh active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5229416B1 (ja) | 2011-06-29 | 2013-07-03 | Ｊｆｅスチール株式会社 | マンガン回収方法 |
| JP2015206077A (ja) | 2014-04-21 | 2015-11-19 | Ｊｆｅスチール株式会社 | 廃乾電池からの資源の分離、回収方法および分離、回収設備および回収物 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2023026931A1 (ja) | 2023-03-02 |
| CN117242196A (zh) | 2023-12-15 |
| JP7276626B1 (ja) | 2023-05-18 |
| JPWO2023026931A1 (zh) | 2023-03-02 |
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