KR20180026460A - 흑연 개질된 리튬 금속 전극 - Google Patents

흑연 개질된 리튬 금속 전극 Download PDF

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Publication number
KR20180026460A
KR20180026460A KR1020187001547A KR20187001547A KR20180026460A KR 20180026460 A KR20180026460 A KR 20180026460A KR 1020187001547 A KR1020187001547 A KR 1020187001547A KR 20187001547 A KR20187001547 A KR 20187001547A KR 20180026460 A KR20180026460 A KR 20180026460A
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South Korea
Prior art keywords
surface layer
lithium metal
lithium
graphite
metal electrode
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KR1020187001547A
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English (en)
Korean (ko)
Inventor
래리 제이 크라우스
로웰 디 젠센
Original Assignee
쓰리엠 이노베이티브 프로퍼티즈 캄파니
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Publication of KR20180026460A publication Critical patent/KR20180026460A/ko
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H01M4/382—Lithium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y02E60/122—
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/54—

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Hybrid Cells (AREA)
KR1020187001547A 2015-07-27 2016-07-21 흑연 개질된 리튬 금속 전극 Withdrawn KR20180026460A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562197203P 2015-07-27 2015-07-27
US62/197,203 2015-07-27
PCT/US2016/043291 WO2017019436A1 (en) 2015-07-27 2016-07-21 Graphite modified lithium metal electrode

Publications (1)

Publication Number Publication Date
KR20180026460A true KR20180026460A (ko) 2018-03-12

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KR1020187001547A Withdrawn KR20180026460A (ko) 2015-07-27 2016-07-21 흑연 개질된 리튬 금속 전극

Country Status (6)

Country Link
US (1) US20180212270A1 (cg-RX-API-DMAC10.html)
EP (1) EP3329538A4 (cg-RX-API-DMAC10.html)
JP (1) JP2018527702A (cg-RX-API-DMAC10.html)
KR (1) KR20180026460A (cg-RX-API-DMAC10.html)
CN (1) CN107851835A (cg-RX-API-DMAC10.html)
WO (1) WO2017019436A1 (cg-RX-API-DMAC10.html)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021225304A1 (en) 2020-05-06 2021-11-11 Samsung Electronics Co., Ltd. Secondary battery and method of preparing the same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11063248B2 (en) * 2018-05-24 2021-07-13 GM Global Technology Operations LLC Protective coating for lithium-containing electrode and methods of making the same
DE102018128451A1 (de) * 2018-11-13 2020-05-14 Bayerische Motoren Werke Aktiengesellschaft Kalorimetrisches Verfahren zur quantitativen Bestimmung von auf einer Anode einer Lithium-Ionen-Zelle abgeschiedenem metallischen Lithium
CN111430663A (zh) * 2019-11-28 2020-07-17 蜂巢能源科技有限公司 锂负极极片及其制备方法和锂电池
CN112993383B (zh) 2019-12-18 2023-04-11 财团法人工业技术研究院 电池
CN114388746B (zh) * 2020-10-21 2024-01-23 安徽盟维新能源科技有限公司 锂金属负极、锂金属电池及其制备方法与抑制锂枝晶方法

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JPH04248276A (ja) * 1991-01-25 1992-09-03 Matsushita Electric Ind Co Ltd リチウム二次電池
JPH0636759A (ja) * 1992-07-17 1994-02-10 Mitsubishi Cable Ind Ltd リチウム二次電池
US5387479A (en) 1993-06-16 1995-02-07 Valence Technology, Inc. Electrodes for rechargeable lithium batteries
US5503946A (en) * 1994-09-29 1996-04-02 Arthur D. Little, Inc. Particulate interface for electrolytic cells and electrolytic process
US5720780A (en) 1996-11-04 1998-02-24 Valence Technology, Inc. Film forming method for lithium ion rechargeable batteries
JPH11135116A (ja) * 1997-10-27 1999-05-21 Fuji Elelctrochem Co Ltd リチウム二次電池用負極及びその負極を用いたリチウム二次電池、並びにそのリチウム二次電池用負極の製造方法
US6537701B1 (en) * 1998-09-03 2003-03-25 Polyplus Battery Company, Inc. Coated lithium electrodes
US6589299B2 (en) 2001-02-13 2003-07-08 3M Innovative Properties Company Method for making electrode
JP2003045415A (ja) * 2001-07-31 2003-02-14 Nec Corp 二次電池用負極
JP4150516B2 (ja) * 2001-12-21 2008-09-17 三星エスディアイ株式会社 リチウム二次電池の負極用の黒鉛含有組成物の製造方法並びにリチウム二次電池用の負極の製造方法及びリチウム二次電池の製造方法
US7326497B2 (en) * 2001-12-21 2008-02-05 Samsung Sdi Co., Ltd. Graphite-containing composition, negative electrode for a lithium secondary battery, and lithium secondary battery
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US7348102B2 (en) * 2004-03-16 2008-03-25 Toyota Motor Corporation Corrosion protection using carbon coated electron collector for lithium-ion battery with molten salt electrolyte
JP5167914B2 (ja) 2008-04-09 2013-03-21 トヨタ自動車株式会社 固体リチウム二次電池の製造方法
US8178241B2 (en) * 2008-08-28 2012-05-15 3M Innovative Properties Company Electrode including current collector with nano-scale coating and method of making the same
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KR20130067920A (ko) * 2011-12-14 2013-06-25 한국전자통신연구원 탄소 분말을 리튬 표면에 코팅한 음극을 적용한 리튬 이차 전지
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021225304A1 (en) 2020-05-06 2021-11-11 Samsung Electronics Co., Ltd. Secondary battery and method of preparing the same
EP4147293A4 (en) * 2020-05-06 2025-05-28 Samsung Electronics Co., Ltd. Secondary battery and method for producing the same

Also Published As

Publication number Publication date
JP2018527702A (ja) 2018-09-20
US20180212270A1 (en) 2018-07-26
CN107851835A (zh) 2018-03-27
EP3329538A1 (en) 2018-06-06
EP3329538A4 (en) 2019-01-23
WO2017019436A1 (en) 2017-02-02

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PA0105 International application

Patent event date: 20180117

Patent event code: PA01051R01D

Comment text: International Patent Application

PG1501 Laying open of application
PC1203 Withdrawal of no request for examination