KR20100084519A - 천이 금속 착물로부터 금속 석출을 억제하는 방법 - Google Patents

천이 금속 착물로부터 금속 석출을 억제하는 방법 Download PDF

Info

Publication number
KR20100084519A
KR20100084519A KR1020107008311A KR20107008311A KR20100084519A KR 20100084519 A KR20100084519 A KR 20100084519A KR 1020107008311 A KR1020107008311 A KR 1020107008311A KR 20107008311 A KR20107008311 A KR 20107008311A KR 20100084519 A KR20100084519 A KR 20100084519A
Authority
KR
South Korea
Prior art keywords
group
transition metal
reaction
palladium
phosphite
Prior art date
Application number
KR1020107008311A
Other languages
English (en)
Korean (ko)
Inventor
마사루 우츠노미야
미와코 오오쿠보
Original Assignee
미쓰비시 가가꾸 가부시키가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 미쓰비시 가가꾸 가부시키가이샤 filed Critical 미쓰비시 가가꾸 가부시키가이샤
Publication of KR20100084519A publication Critical patent/KR20100084519A/ko

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/6574Esters of oxyacids of phosphorus
    • C07F9/65744Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B01J31/186Mono- or diamide derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006Palladium compounds
    • C07F15/0066Palladium compounds without a metal-carbon linkage
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/06Phosphorus compounds without P—C bonds
    • C07F9/08Esters of oxyacids of phosphorus
    • C07F9/141Esters of phosphorous acids
    • C07F9/145Esters of phosphorous acids with hydroxyaryl compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/06Phosphorus compounds without P—C bonds
    • C07F9/22Amides of acids of phosphorus
    • C07F9/24Esteramides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576Six-membered rings
    • C07F9/60Quinoline or hydrogenated quinoline ring systems
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/547Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
    • C07F9/657154Cyclic esteramides of oxyacids of phosphorus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/824Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
KR1020107008311A 2007-11-06 2008-11-04 천이 금속 착물로부터 금속 석출을 억제하는 방법 KR20100084519A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007288508 2007-11-06
JPJP-P-2007-288508 2007-11-06

Publications (1)

Publication Number Publication Date
KR20100084519A true KR20100084519A (ko) 2010-07-26

Family

ID=40625728

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020107008311A KR20100084519A (ko) 2007-11-06 2008-11-04 천이 금속 착물로부터 금속 석출을 억제하는 방법

Country Status (5)

Country Link
JP (2) JP5604783B2 (ja)
KR (1) KR20100084519A (ja)
CN (1) CN101835786A (ja)
TW (1) TWI483949B (ja)
WO (1) WO2009060840A1 (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9707552B1 (en) 2015-07-13 2017-07-18 Lg Chem. Ltd. Catalyst composition comprising phosphorus-based ligand and hydroformylation process using the same

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009060840A1 (ja) * 2007-11-06 2009-05-14 Mitsubishi Chemical Corporation 遷移金属錯体から金属析出を抑制する方法
US7928267B1 (en) * 2009-06-22 2011-04-19 Eastman Chemical Company Phosphite containing catalysts for hydroformylation processes
WO2018155473A1 (ja) 2017-02-27 2018-08-30 株式会社クラレ 触媒液の製造方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL6815746A (ja) * 1967-11-06 1969-05-08
DE3505654A1 (de) * 1985-02-19 1986-08-21 Degussa Ag, 6000 Frankfurt Verfahren zur herstellung von 2-alkyl-1,4-butandial
JPH08295683A (ja) * 1995-04-28 1996-11-12 Mitsui Toatsu Chem Inc 3−ホルミルテトラヒドロフランの製造法
EP0839794A1 (en) * 1996-11-04 1998-05-06 Dsm N.V. Process for the continuous preparation of an alkyl 5-formylvalerate compound
JP3948792B2 (ja) * 1997-08-11 2007-07-25 三井化学株式会社 3−ホルミルテトラヒドロフランの製造法
JP3903575B2 (ja) * 1998-03-09 2007-04-11 三菱化学株式会社 アルデヒド類の製造方法
JP4085566B2 (ja) * 2000-09-29 2008-05-14 三菱化学株式会社 アリル化合物の製造方法
JP4328080B2 (ja) * 2002-10-30 2009-09-09 三菱化学株式会社 固体担持有機リン化合物、遷移金属錯体、及び触媒反応方法
JP4292960B2 (ja) * 2002-12-10 2009-07-08 三菱化学株式会社 Viii族金属−有機ホスファイト錯体触媒液の保存方法
US7015360B2 (en) * 2003-03-28 2006-03-21 Dow Global Technologies, Inc. Asymmetric catalysts prepared from optically active bisphosphites bridged by achiral diols
JP2007039490A (ja) * 2005-08-01 2007-02-15 Mitsubishi Rayon Co Ltd 流動性向上剤、芳香族ポリカーボネート樹脂組成物および成形品
CN1986055B (zh) * 2006-12-22 2012-06-27 中国科学院上海有机化学研究所 一种丙烯氢甲酰化催化体系和方法
WO2009060840A1 (ja) * 2007-11-06 2009-05-14 Mitsubishi Chemical Corporation 遷移金属錯体から金属析出を抑制する方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9707552B1 (en) 2015-07-13 2017-07-18 Lg Chem. Ltd. Catalyst composition comprising phosphorus-based ligand and hydroformylation process using the same

Also Published As

Publication number Publication date
JP5604783B2 (ja) 2014-10-15
TW200934787A (en) 2009-08-16
WO2009060840A1 (ja) 2009-05-14
TWI483949B (zh) 2015-05-11
CN101835786A (zh) 2010-09-15
JP2014169346A (ja) 2014-09-18
JP2009132697A (ja) 2009-06-18

Similar Documents

Publication Publication Date Title
KR100218841B1 (ko) 히드로포르밀화법 및 여기에 사용되는 비스 포스파이트 화합물
EP0159460A1 (en) A hydroformylation catalyst and process
KR930003936B1 (ko) 알데히드의 제조공정
MXPA05001396A (es) Procedimiento para la obtencion de aldehidos mediante la hidroformilacion de compuestos olefinicamente insaturados, catalizado con complejos de metal no modificados en presencia de esteres ciclicos de acido carboxilico.
JPS6332342B2 (ja)
JPH02277550A (ja) カルボニル化触媒系
GB2026473A (en) Hydroformylation
JP4996683B2 (ja) ヒドロ二量化によるジエンの製造方法
WO1999013984A1 (en) Hydroformylation process using novel phosphite-metal catalyst system
KR20100084519A (ko) 천이 금속 착물로부터 금속 석출을 억제하는 방법
KR20000017504A (ko) 발러알데하이드 및 이의 제조방법
EP2342210A1 (en) Acetylene tolerant hydroformylation catalysts
EP0922691A1 (en) Hydroformylation process
CN107438630B (zh) 丁二烯短链聚合催化剂及其制备
JP2007302938A (ja) 金属の分離方法
US6187962B1 (en) Hydroformylation process
JP4548103B2 (ja) ヒドロホルミル化方法
US7160835B2 (en) Bisphosphine process for producing the same and use thereof
KR101540487B1 (ko) 알릴 화합물의 이성화 방법
KR20050044848A (ko) Tcd-모넨알의 제조방법
JP2008524156A (ja) 非分枝鎖状の非環式アクリル酸オクタトリエンの製造方法
US20240043362A1 (en) Process for the preparation of polycyclic aliphatic dialdehydes
KR101122325B1 (ko) 1-옥텐의 제조 방법
JP4595495B2 (ja) アルデヒドの製造方法
KR100221353B1 (ko) 히드로포르밀화법 및 여기에 사용되는 비스포스파이트 화합물

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E601 Decision to refuse application