KR20070088595A - 가수분해성 금속 알콕시드 부위를 갖는 불소 함유 화합물,상기 화합물로부터 얻어지는 경화성 불소 함유 중합체 및상기 중합체를 포함하는 경화성 불소 함유 수지 조성물 - Google Patents
가수분해성 금속 알콕시드 부위를 갖는 불소 함유 화합물,상기 화합물로부터 얻어지는 경화성 불소 함유 중합체 및상기 중합체를 포함하는 경화성 불소 함유 수지 조성물 Download PDFInfo
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- KR20070088595A KR20070088595A KR1020077007925A KR20077007925A KR20070088595A KR 20070088595 A KR20070088595 A KR 20070088595A KR 1020077007925 A KR1020077007925 A KR 1020077007925A KR 20077007925 A KR20077007925 A KR 20077007925A KR 20070088595 A KR20070088595 A KR 20070088595A
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- KR
- South Korea
- Prior art keywords
- fluorine
- structural unit
- formula
- same
- represented
- Prior art date
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
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- C—CHEMISTRY; METALLURGY
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Abstract
Description
Claims (17)
- 하기 화학식 2로 표시되고, 구조 단위 M을 0.1 내지 100몰%, 구조 단위 N을 0 내지 99.9몰% 및 구조 단위 A를 0 내지 99.9몰% 포함하는, 수 평균 분자량이 500 내지 1,000,000인 가수분해성 금속 알콕시드 부위를 갖는 경화성 불소 함유 중합체.<화학식 2>[식 중,구조 단위 M은 하기 화학식 M으로 표시되는 가수분해성 금속 알콕시드 부위를 갖는 불소 함유 에틸렌성 단량체 유래의 구조 단위이고;구조 단위 N은 하기 화학식 N으로 표시되는 불소 함유 에틸렌성 단량체에서 유래되는 구조 단위이며;구조 단위 A는 상기 화학식 M 및 N으로 표시되는 구조 단위를 제공하는 불소 함유 에틸렌성 단량체와 공중합 가능한 단량체에서 유래되는 구조 단위임]<화학식 M>(식 중, X1 및 X2는 동일하거나 또는 상이하고, H 또는 F이고; X3은 H, F, CH3 또는 CF3이고; X4 및 X5는 동일하거나 또는 상이하고, H, F 또는 CF3이고; Rf1은 탄소수 1 내지 40의 불소 함유 알킬기 또는 탄소수 2 내지 100의 에테르 결합을 갖는 불소 함유 알킬기로서, 수소 원자의 1 내지 3개가 Y1(Y1은 말단에 탄소수 1 내지 50의 가수분해성 금속 알콕시드 부위를 1개 이상 포함하는 관능기임)로 치환된 유기기이고; a는 0 내지 3의 정수이며; b 및 c는 동일하거나 또는 상이하고, 0 또는 1임)<화학식 N>(식 중, X1 및 X2는 동일하거나 또는 상이하고, H 또는 F이고; X3은 H, F, CH3 또는 CF3이고; X4 및 X5는 동일하거나 또는 상이하고, H, F 또는 CF3이고; Rf2는 탄소수 1 내지 40의 불소 함유 알킬기 또는 탄소수 2 내지 100의 에테르 결합을 갖는 불소 함유 알킬기로서, 수소 원자의 1 내지 3개가 Y2(Y2는 말단에 에틸렌성 탄소-탄소 이중 결합을 갖는 탄소수 2 내지 10의 1가의 유기기임)로 치환된 유기기이고; a는 0 내지 3의 정수이며; b 및 c는 동일하거나 또는 상이하고, 0 또는 1임)
- 하기 화학식 2-1로 표시되고, 구조 단위 M이 0.1 내지 90몰%, 구조 단위 N 이 0 내지 99.9몰%, 구조 단위 A1이 0 내지 99.9몰% 및 구조 단위 A2가 0 내지 99.9몰%이면서 N+A1+A2를 10 내지 99.9몰% 포함하는, 수 평균 분자량이 500 내지 1,000,000인 가수분해성 금속 알콕시드 부위를 갖는 경화성 불소 함유 중합체.<화학식 2-1>-(M)-(N)-(A1)-(A2)-[식 중, 구조 단위 M은 제1항에 기재된 화학식 M으로 표시되는 가수분해성 금속 알콕시드 부위를 갖는 불소 함유 에틸렌성 단량체 유래의 구조 단위이고, 구조 단위 N은 제1항에 기재된 화학식 N으로 표시되는 불소 함유 에틸렌성 단량체에서 유래되는 구조 단위이며, 구조 단위 A1은 하기 화학식 A1로 표시되는 구조 단위이고, 구조 단위 A2는 하기 화학식 A2로 표시되는 구조 단위임]<화학식 A1>(식 중, X11, X12, X13은 동일하거나 또는 상이하고, H 또는 F이고; X14는 H, F 또는 CF3이고; h는 0 내지 2의 정수이고; i는 0 또는 1이고; Rf4는 탄소수 1 내지 40의 2가의 불소 함유 알킬렌기 또는 탄소수 2 내지 100의 에테르 결합을 갖는 2가의 불소 함유 알킬렌기이며; Z1은 -OH, -CH2OH, -COOH, 카르복실산 유도체, -SO3H, 술폰산 유도체, 에폭시기 및 시아노기로 이루어지는 군에서 선택되는 기임)<화학식 A2>(식 중, X15, X16, X18은 동일하거나 또는 상이하고, H 또는 F이고; X17은 H, F 또는 CF3이고; h1, i1, j는 동일하거나 또는 상이하고, 0 또는 1이고; Z2는 H, F, Cl 또는 탄소수 1 내지 16의 직쇄상 또는 분지상 퍼플루오로알킬기이고; Rf5는 탄소수 1 내지 20의 2가의 불소 함유 알킬렌기 또는 탄소수 2 내지 100의 에테르 결합을 포함하는 2가의 불소 함유 알킬렌기임)
- 제1항 또는 제2항에 있어서, Y1의 1개 이상이 Rf1의 말단에 결합되어 있는 경화성 불소 함유 중합체.
- 제2항 또는 제3항에 있어서, Y2의 1개 이상이 Rf2의 말단에 결합되어 있는 경화성 불소 함유 중합체.
- 제1항 내지 제7항 중 어느 한 항에 있어서, Rf1이 화학식 -D-Ry[식 중, -D-은 하기 화학식 D로 표시되는 플루오로에테르의 단위이고; Ry는 수소 원자의 일부 또는 전부가 불소 원자로 치환될 수 있는 탄소수 1 내지 39의 탄화수소기 또는 수소 원자의 일부 또는 전부가 불소 원자로 치환될 수 있는 탄소수 1 내지 99의 에테르 결합을 갖는 탄화수소기로서, 수소 원자의 1 내지 3개가 Y1(Y1은 상기와 동일함)로 치환된 유기기임]로 표시되는 경화성 불소 함유 중합체.<화학식 D>(식 중, n은 1 내지 20의 정수이고; R은 수소 원자의 1개 이상이 불소 원자로 치환된 탄소수 1 내지 5의 2가의 불소 함유 알킬렌기에서 선택되는 1종 이상이고, n이 2 이상인 경우에는 동일하거나 상이할 수 있음)
- 제1항 내지 제8항 중 어느 한 항에 있어서, Ry가 하기 화학식 Ry로 표시되는 기인 경화성 불소 함유 중합체.<화학식 Ry>-O-Ry1[식 중, Ry1은 화학식 -(R11)pR12-(Y1a)m(식 중, p는 0 또는 1이고; m은 1 내지 3의 정수이고; R11은 -CONH-이고, R12는 수소 원자의 일부 또는 전부가 불소 원자로 치환될 수 있는 탄소수 1 내지 39의 2 내지 4가의 탄화수소기 또는 수소 원자의 일부 또는 전부가 불소 원자로 치환될 수 있는 탄소수 1 내지 99의 에테르 결합을 갖는 2 내지 4가의 탄화수소기이고; Y1a는 화학식 -[M1O(R29)a(R30)b(R31)c(R32)d]n-M2(R33)e(R34)f(R35)g(R36)h(R37)i(식 중, M1 및 M2는 동일하거나 또는 상이하고, 2 내지 6가의 금속 원자이고; a, b, c 및 d는 0 또는 1로서, a+b+c+d+2가 금속 원자 M1의 가수와 같고; e, f, g, h 및 i는 0 또는 1로서, e+f+g+h+i+1이 금속 원자 M2의 가수와 같고; R29, R30, R31, R32, R33, R34, R35, R36 및 R37은 동일하거나 또는 상이하고, 화학식 OR38 또는 R38(식 중, R38은 수소 원자, 또는 수소 원자의 일부 또는 전부가 불소 원자로 치환될 수 있는 탄소수 1 내지 10의 탄화수소기임)로 표시되는 유기기로서, R29, R30, R31, R32, R33, R34, R35, R36 및 R37 중 하나 이상이 OR38이고; n=0 내지 11의 정수임)로 표시되는 관능기임)으로 표시되는 유기-무기 복합기임]
- 제1항 내지 제11항 중 어느 한 항에 있어서, 화학식 2-1에 있어서, 구조 단위 A2가 테트라플루오로에틸렌, 불화비닐리덴, 클로로트리플루오로에틸렌 및 헥사플루오로프로필렌으로 이루어지는 군에서 선택되는 1종 이상의 단량체에서 유래되는 구조 단위인 경화성 불소 함유 중합체.
- (a) 제1항 내지 제12항 중 어느 한 항에 기재된 가수분해성 금속 알콕시드 부위를 갖는 경화성 불소 함유 중합체, 및 (b) 경화제를 포함하는 경화성 불소 함 유 수지 조성물.
- 제13항에 기재된 경화성 불소 함유 수지 조성물을 경화하여 얻어지는 경화물.
- (a) 제1항 내지 제12항 중 어느 한 항에 기재된 가수분해성 금속 알콕시드 부위를 갖는 경화성 불소 함유 중합체, (b) 경화제, 및 (c) 용제를 포함하는 코팅용 경화성 불소 함유 수지 조성물.
- (a) 제15항에 기재된 코팅용 경화성 불소 함유 수지 조성물을 도포하여 형성되는 피막을 경화하여 얻어지는 경화 피막.
- 하기 화학식 1로 표시되는 가수분해성 금속 알콕시드 부위를 갖는 불소 함유 화합물.<화학식 1>(식 중, X1 및 X2는 동일하거나 또는 상이하고, H 또는 F이고; X3은 H, F, CH3 또는 CF3이고; X4 및 X5는 동일하거나 또는 상이하고, H, F 또는 CF3이고; Rf1은 탄소수 1 내지 40의 불소 함유 알킬기 또는 탄소수 2 내지 100의 에테르 결합을 갖는 불소 함유 알킬기로서, 수소 원자의 1 내지 3개가 Y1(Y1은 말단에 탄소수 1 내지 50의 가수분해성 금속 알콕시드 부위를 1개 이상 포함하는 관능기임)로 치환된 유기기이고; a는 0 내지 3의 정수이며; b 및 c는 동일하거나 또는 상이하고, 0 또는 1임)
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CN101014633A (zh) | 2007-08-08 |
US7585926B2 (en) | 2009-09-08 |
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CN102516459A (zh) | 2012-06-27 |
JP5012025B2 (ja) | 2012-08-29 |
JPWO2006027958A1 (ja) | 2008-05-08 |
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CN102516459B (zh) | 2014-08-27 |
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