KR20060093346A - 신규한 다분기 고분자 - Google Patents
신규한 다분기 고분자 Download PDFInfo
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- KR20060093346A KR20060093346A KR1020067010615A KR20067010615A KR20060093346A KR 20060093346 A KR20060093346 A KR 20060093346A KR 1020067010615 A KR1020067010615 A KR 1020067010615A KR 20067010615 A KR20067010615 A KR 20067010615A KR 20060093346 A KR20060093346 A KR 20060093346A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by hetero atoms or groups containing heteroatoms
- C08F12/16—Halogens
- C08F12/18—Chlorine
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/22—Esters containing halogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by heteroatoms or groups containing heteroatoms
- C08F212/16—Halogens
- C08F212/18—Chlorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/002—Dendritic macromolecules
- C08G83/005—Hyperbranched macromolecules
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
Description
Claims (20)
- 제 1 항에 있어서,상기 식 (I) 로 표시되는 반복 단위가 식 (II)(식 중, R1∼R3 은 상기와 동일한 의미를 나타내고, Z 는 단결합 또는 2가 이 상의 연결기를 나타내고, A 는 방향족 탄화수소기 또는 방향족 복소환기를 나타낸다. R4 는 활성 할로겐 원자를 가질 수 있는 관능기를 나타내고, b 는 2 이상의 정수를 나타내고, R4 끼리는 동일하거나 상이해도 된다. R5 는 할로겐 원자 또는 유기기를 나타내고, d 는 0 또는 1 이상의 정수를 나타내고, d 가 2 이상인 경우, R5 끼리는 동일하거나 상이해도 된다) 로 표시되는 반복 단위인 것을 특징으로 하는 다분기 고분자.
- 제 4 항에 있어서,상기 식 (IV) 중, V 가 알킬렌폴리옥시기인 것을 특징으로 하는 다분기 고분자.
- 제 7 항에 있어서,상기 식 (VI) 으로 표시되는 화합물이 식 (VII)(식 중, R8∼R10 은 상기와 동일한 의미를 나타내고, Z1 은 단결합 또는 2가 이상의 연결기를 나타내고, A1 은 방향족 탄화수소기 또는 방향족 복소환기를 나타낸다. R24 는 활성 할로겐 원자를 가질 수 있는 관능기를 나타내고, b1 은 2 이상의 정수를 나타내고, R24 끼리는 동일하거나 상이해도 된다. R25 는 할로겐 원자 또는 유기기를 나타내고, d1 은 0 또는 1 이상의 정수를 나타내고, d1 이 2 이상인 경우, R25 끼리는 동일하거나 상이해도 된다. R26 는 염소 원자, 브롬 원자 또는 요오드 원자를 나타낸다) 로 표시되는 화합물인 것을 특징으로 하는 다분기 고분자.
- 제 10 항에 있어서,상기 식 (IX) 중, V11 이 알킬렌폴리옥시기인 것을 특징으로 하는 다분기 고 분자.
- 제 1 항 내지 제 12 항 중 어느 한 항에 있어서,중량 평균 분자량 (Mw) 과 수평균 분자량 (Mn) 의 비 (Mw/Mn) 가 1.01∼9.99 범위인 것을 특징으로 하는 다분기 고분자.
- 제 1 항 내지 제 13 항 중 어느 한 항에 있어서,수평균 분자량 (Mn) 이 200∼20,000,000 범위인 것을 특징으로 하는 다분기 고분자.
- 제 1 항 내지 제 14 항 중 어느 한 항에 있어서,다분기 고분자가 하이퍼 브랜치 폴리머인 것을 특징으로 하는 다분기 고분자.
- 탄소-탄소 결합에 의해 분기하고, 중량 평균 분자량 (Mw) 과 수평균 분자량 (Mn) 의 비 (Mw/Mn) 가, 1.01∼9.99 범위인 것을 특징으로 하는 하이퍼 브랜치 폴리머.
- 2 이상의 중합 개시점과 중합성 불포화 결합을 갖는 화합물을 금속 촉매를 사용한 리빙라디칼 중합법을 사용하여 중합시켜 얻어진 것을 특징으로 하는 하이퍼 브랜치 폴리머.
- 제 16 항 또는 제 17 항에 있어서,수평균 분자량 (Mn) 이 200∼20,000,000 범위인 것을 특징으로 하는 하이퍼 브랜치 폴리머.
- 제 16 항 내지 제 18 항 중 어느 한 항에 있어서,폴리머 말단에, 관능기를 갖는 것을 특징으로 하는 하이퍼 브랜치 폴리머.
- 제 1 항 내지 제 15 항 중 어느 한 항에 기재된 다분기 고분자, 또는 제 16 항 내지 제 19 항 중 어느 한 항에 기재된 하이퍼 브랜치 폴리머를 코어로 하는 것을 특징으로 하는 스타 폴리머.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JPJP-P-2003-00394867 | 2003-11-26 | ||
JP2003394867 | 2003-11-26 |
Related Child Applications (1)
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KR1020077027726A Division KR20070119097A (ko) | 2003-11-26 | 2004-11-25 | 신규한 다분기 고분자 |
Publications (2)
Publication Number | Publication Date |
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KR20060093346A true KR20060093346A (ko) | 2006-08-24 |
KR100814315B1 KR100814315B1 (ko) | 2008-03-18 |
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KR1020077027726A KR20070119097A (ko) | 2003-11-26 | 2004-11-25 | 신규한 다분기 고분자 |
KR1020067010615A KR100814315B1 (ko) | 2003-11-26 | 2004-11-25 | 신규한 다분기 고분자 |
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KR1020077027726A KR20070119097A (ko) | 2003-11-26 | 2004-11-25 | 신규한 다분기 고분자 |
Country Status (6)
Country | Link |
---|---|
US (1) | US7732549B2 (ko) |
EP (1) | EP1688440B1 (ko) |
JP (2) | JP5101816B2 (ko) |
KR (2) | KR20070119097A (ko) |
CN (2) | CN1886431B (ko) |
WO (1) | WO2005052009A1 (ko) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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EP1367080A1 (en) | 2002-05-29 | 2003-12-03 | Hycail B.V. | Hyperbranched poly(hydroxycarboxylic acid) polymers |
JP5101816B2 (ja) * | 2003-11-26 | 2012-12-19 | 日本曹達株式会社 | 多分岐高分子 |
WO2008029806A1 (fr) * | 2006-09-07 | 2008-03-13 | Nissan Chemical Industries, Ltd. | Polymère hyperramifié et son procédé de production |
CA2665607C (en) * | 2006-10-04 | 2014-12-02 | University Of Akron | Synthesis of inimers and hyperbranched polymers |
JP6833485B2 (ja) * | 2016-12-05 | 2021-02-24 | 大日精化工業株式会社 | 星形ポリマーの製造方法、星形ポリマー、及びフィラー分散体 |
JP6924434B2 (ja) | 2017-03-02 | 2021-08-25 | 国立大学法人京都大学 | グラフトポリマーの開始剤 |
US11981777B2 (en) | 2018-08-20 | 2024-05-14 | The University Of Akron | Synthesis of hyperbranched polymethacrylates and polyacrylates by a haloinimer approach |
WO2020142144A1 (en) * | 2019-01-04 | 2020-07-09 | Carbon, Inc. | Additively manufactured products having a matte surface finish |
CN115057961B (zh) * | 2022-01-04 | 2024-01-26 | 浙江新力新材料股份有限公司 | 一种超支化聚合物及其制备方法与应用 |
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EP0464408B1 (en) * | 1990-06-14 | 1994-01-12 | Sekisui Chemical Co., Ltd. | Process for preparing star compounds |
JPH082923B2 (ja) * | 1990-06-14 | 1996-01-17 | 積水化学工業株式会社 | 星型化合物の製造方法 |
JP3112711B2 (ja) * | 1991-08-12 | 2000-11-27 | 積水化学工業株式会社 | アルケニルエーテル化合物およびその用途 |
US5763548A (en) * | 1995-03-31 | 1998-06-09 | Carnegie-Mellon University | (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization |
JP4183293B2 (ja) * | 1997-07-09 | 2008-11-19 | 日本曹達株式会社 | (メタ)アクリル酸エステル系重合体及びその製造方法 |
US6255424B1 (en) * | 1997-11-25 | 2001-07-03 | Colorado School Of Mines | Dendritic polymers and convergent method of synthesis |
US6414101B1 (en) * | 1999-03-26 | 2002-07-02 | Shin-Etsu Chemical Co., Ltd. | Dendritic polymers and making method |
JP4420152B2 (ja) * | 1999-03-26 | 2010-02-24 | 信越化学工業株式会社 | 高分子化合物及びその製造方法 |
JP4623690B2 (ja) | 1999-08-31 | 2011-02-02 | 日本曹達株式会社 | 星型ブロックコポリマー |
EP1211270B1 (en) * | 1999-08-31 | 2006-10-11 | Nippon Soda Co., Ltd. | Star block copolymer |
JP4491103B2 (ja) * | 1999-12-27 | 2010-06-30 | 株式会社Kri | 多分岐高分子、その製造方法、固体電解質及び電気化学素子 |
JP4288445B2 (ja) * | 2000-10-23 | 2009-07-01 | 信越化学工業株式会社 | 新規オニウム塩及びレジスト材料用光酸発生剤並びにレジスト材料及びパターン形成方法 |
JP4116788B2 (ja) * | 2000-11-21 | 2008-07-09 | 日本曹達株式会社 | スターポリマーおよび高分子電解質 |
JP3946080B2 (ja) * | 2001-05-01 | 2007-07-18 | 株式会社クラレ | 熱可塑性エラストマー組成物 |
US6639032B2 (en) * | 2001-11-28 | 2003-10-28 | Eastman Kodak Company | Highly branched polymer from telomerization |
JP5101816B2 (ja) * | 2003-11-26 | 2012-12-19 | 日本曹達株式会社 | 多分岐高分子 |
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2004
- 2004-11-25 JP JP2005515842A patent/JP5101816B2/ja not_active Expired - Fee Related
- 2004-11-25 KR KR1020077027726A patent/KR20070119097A/ko not_active Application Discontinuation
- 2004-11-25 CN CN200480034676.7A patent/CN1886431B/zh not_active Expired - Fee Related
- 2004-11-25 US US10/595,974 patent/US7732549B2/en not_active Expired - Fee Related
- 2004-11-25 WO PCT/JP2004/017897 patent/WO2005052009A1/ja active Application Filing
- 2004-11-25 KR KR1020067010615A patent/KR100814315B1/ko active IP Right Grant
- 2004-11-25 CN CN201210236774.5A patent/CN102775535B/zh not_active Expired - Fee Related
- 2004-11-25 EP EP04799895.0A patent/EP1688440B1/en active Active
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2010
- 2010-04-19 JP JP2010096506A patent/JP5600467B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR100814315B1 (ko) | 2008-03-18 |
WO2005052009A1 (ja) | 2005-06-09 |
US20070142504A1 (en) | 2007-06-21 |
CN1886431B (zh) | 2014-02-05 |
JPWO2005052009A1 (ja) | 2007-06-21 |
EP1688440A1 (en) | 2006-08-09 |
JP5101816B2 (ja) | 2012-12-19 |
US7732549B2 (en) | 2010-06-08 |
KR20070119097A (ko) | 2007-12-18 |
CN102775535B (zh) | 2014-08-27 |
JP2010209340A (ja) | 2010-09-24 |
CN1886431A (zh) | 2006-12-27 |
EP1688440A4 (en) | 2009-01-21 |
CN102775535A (zh) | 2012-11-14 |
JP5600467B2 (ja) | 2014-10-01 |
EP1688440B1 (en) | 2014-01-01 |
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