KR20040089679A - 분자 체를 포함하는 촉매 조성물, 이들의 제조 방법 및전환 공정에서의 이들의 용도 - Google Patents

분자 체를 포함하는 촉매 조성물, 이들의 제조 방법 및전환 공정에서의 이들의 용도 Download PDF

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Publication number
KR20040089679A
KR20040089679A KR10-2004-7013378A KR20047013378A KR20040089679A KR 20040089679 A KR20040089679 A KR 20040089679A KR 20047013378 A KR20047013378 A KR 20047013378A KR 20040089679 A KR20040089679 A KR 20040089679A
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South Korea
Prior art keywords
oxide
catalyst composition
metal oxide
molecular sieve
carbon dioxide
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KR10-2004-7013378A
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English (en)
Korean (ko)
Inventor
레빈도론
바툴리제임스씨
Original Assignee
엑손모빌 케미칼 패턴츠 인코포레이티드
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Priority claimed from US10/215,511 external-priority patent/US6906232B2/en
Application filed by 엑손모빌 케미칼 패턴츠 인코포레이티드 filed Critical 엑손모빌 케미칼 패턴츠 인코포레이티드
Publication of KR20040089679A publication Critical patent/KR20040089679A/ko

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C10G50/02—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation of hydrocarbon oils for lubricating purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
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    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
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    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
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    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
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    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
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    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
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    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
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    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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    • C—CHEMISTRY; METALLURGY
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
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    • C07C2529/82—Phosphates
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    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
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    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
KR10-2004-7013378A 2002-02-28 2003-02-10 분자 체를 포함하는 촉매 조성물, 이들의 제조 방법 및전환 공정에서의 이들의 용도 KR20040089679A (ko)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
US36096302P 2002-02-28 2002-02-28
US60/360,963 2002-02-28
US36601202P 2002-03-20 2002-03-20
US60/366,012 2002-03-20
US37469702P 2002-04-22 2002-04-22
US60/374,697 2002-04-22
US10/215,511 US6906232B2 (en) 2002-08-09 2002-08-09 Molecular sieve compositions, catalysts thereof, their making and use in conversion processes
US10/215,511 2002-08-09
PCT/US2003/004169 WO2003074177A2 (en) 2002-02-28 2003-02-10 Catalyst compositions comprising molecular sieves, their preparation and use in conversion processes

Publications (1)

Publication Number Publication Date
KR20040089679A true KR20040089679A (ko) 2004-10-21

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Family Applications (3)

Application Number Title Priority Date Filing Date
KR10-2004-7013377A KR20040091080A (ko) 2002-02-28 2003-02-10 분자 체를 함유하는 촉매 조성물, 이들의 제조 방법 및전환 공정에서의 이들의 용도
KR10-2004-7013384A KR20040089680A (ko) 2002-02-28 2003-02-10 분자 체를 포함하는 촉매 조성물, 이들의 제조 방법 및전환 공정에서의 이들의 용도
KR10-2004-7013378A KR20040089679A (ko) 2002-02-28 2003-02-10 분자 체를 포함하는 촉매 조성물, 이들의 제조 방법 및전환 공정에서의 이들의 용도

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KR10-2004-7013377A KR20040091080A (ko) 2002-02-28 2003-02-10 분자 체를 함유하는 촉매 조성물, 이들의 제조 방법 및전환 공정에서의 이들의 용도
KR10-2004-7013384A KR20040089680A (ko) 2002-02-28 2003-02-10 분자 체를 포함하는 촉매 조성물, 이들의 제조 방법 및전환 공정에서의 이들의 용도

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Country Link
EP (3) EP1478462A2 (de)
JP (3) JP2005518928A (de)
KR (3) KR20040091080A (de)
CN (3) CN1298427C (de)
AU (3) AU2003225560B2 (de)
BR (1) BR0308011A (de)
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Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1298427C (zh) * 2002-02-28 2007-02-07 埃克森美孚化学专利公司 分子筛组合物,含有该组合物的催化剂以及它们的制备方法和在转化方法中的应用
US7074739B2 (en) * 2002-11-19 2006-07-11 Exxonmobil Chemical Patents Inc. Multi-component molecular sieve catalyst compositions and their use in aromatics reactions
US6951830B2 (en) 2003-08-05 2005-10-04 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst compositions, their production and use in conversion processes
US7404891B2 (en) * 2004-03-29 2008-07-29 Exxonmobil Chemical Patents Inc. Heat recovery technique for catalyst regenerator flue gas
US7166757B2 (en) 2004-07-30 2007-01-23 Exxonmobil Chemical Patents Inc. Conversion of oxygenates to olefins
WO2007021394A2 (en) * 2005-08-18 2007-02-22 Exxonmobil Chemical Patents Inc. Catalytic conversion of oxygenates to olefins
CN101003018A (zh) * 2006-01-20 2007-07-25 中国石油天然气股份有限公司 一种多相催化固体碱催化剂及其制备方法和应用
US7335621B2 (en) 2006-04-19 2008-02-26 Exxonmobil Chemical Patents Inc. Catalyst compositions and preparation thereof
JP4710744B2 (ja) 2006-07-18 2011-06-29 トヨタ自動車株式会社 複合金属酸化物の製造方法
US7595275B2 (en) 2006-08-15 2009-09-29 Exxonmobil Chemical Patents Inc. Catalyst compositions and their synthesis
CN101239866B (zh) * 2007-02-07 2010-12-01 中国石油化工股份有限公司 含氧化合物生产乙烯、丙烯的方法
CN101239878B (zh) * 2007-02-07 2010-05-19 中国石油化工股份有限公司 碳四及其以上烯烃增产乙烯、丙烯的方法
CA2578494A1 (en) * 2007-02-14 2008-08-14 Nova Chemicals Corporation Catalytic cracking of ethers to 1-olefins
EP2022565A1 (de) * 2007-07-06 2009-02-11 Casale Chemicals S.A. Verfahren zur Herstellung molekularer Silicoaluminophosphat-Molekularsiebe, Katalysatoren mit besagten Sieben und katalytische Dehydrierungsprozesse mit besagten Katalysatoren
EP2183203A1 (de) * 2007-08-13 2010-05-12 Saudi Basic Industries Corporation Verfahren zur umwandlung aliphatischer oxygenate in aromatische verbindungen
DE102007059129A1 (de) * 2007-12-07 2009-06-10 Süd-Chemie AG Katalysator mit erhöhter Olefinselektivität zur Umsetzung von Oxygenaten zu Olefinen
US20110105819A1 (en) * 2008-04-04 2011-05-05 Petr Vasiliev Zeolite catalyst zeolite secondary structure
JP5818133B2 (ja) * 2011-05-20 2015-11-18 国立大学法人東京工業大学 オレフィン製造用触媒及びオレフィンの製造方法
CN102344328B (zh) * 2011-07-25 2014-03-12 浙江大学 一种使用移动床技术将甲醇转化为丙烯的半连续方法
EP2907571B1 (de) 2012-10-15 2017-12-13 Mitsubishi Gas Chemical Company, Inc. Verfahren zur herstellung eines katalysators zur verwendung bei der herstellung einer methylaminverbindung und verfahren zur herstellung der methylaminverbindung
US9656244B2 (en) 2013-05-07 2017-05-23 Synthos S.A. Process for the production of 1,3-butadiene
CN107661774B (zh) * 2016-07-27 2020-11-03 中国科学院大连化学物理研究所 一种催化剂及合成气直接转化制低碳烯烃的方法
CN107661773B (zh) * 2016-07-29 2020-08-04 中国科学院大连化学物理研究所 一种催化剂及合成气直接转化制液体燃料联产低碳烯烃的方法
CN108568311B (zh) * 2017-03-07 2021-03-23 中国科学院大连化学物理研究所 一种催化剂及合成气直接转化制乙烯的方法
RU2747308C1 (ru) * 2017-04-27 2021-05-04 Далянь Инститьют Оф Кемикал Физикс, Чайниз Академи Оф Сайенсиз Способ in-situ получения катализатора для получения по меньшей мере одного из толуола, пара-ксилола и низших олефинов, а также процесс реакции
CN109939667B (zh) * 2018-01-26 2021-01-05 中国科学院大连化学物理研究所 一种催化剂及合成气直接转化制低碳烯烃的方法
CN109939722B (zh) * 2018-01-26 2021-05-25 中国科学院大连化学物理研究所 一种有机碱修饰的复合催化剂及一氧化碳加氢制乙烯的方法
US20210370276A1 (en) * 2018-10-30 2021-12-02 Exxonmobil Chemical Patents Inc. Group 1 Metal Ion Content of Microporous Molecular Sieve Catalysts
CN111346664B (zh) * 2018-12-24 2022-11-15 中国石油化工股份有限公司 改性钒硅分子筛及其制备方法以及硫醚氧化方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4465889A (en) * 1982-07-02 1984-08-14 Summit Gas Systems Pte. Ltd. Catalytic conversion of methanol, dimethyl ether and mixtures thereof to a hydrocarbon product rich in iso-C4 compounds and new catalysts therefor
US4781816A (en) 1987-10-19 1988-11-01 Phillips Petroleum Company Cracking process
US6040264A (en) * 1996-04-04 2000-03-21 Exxon Chemical Patents Inc. Use of alkaline earth metal containing small pore non-zeolitic molecular sieve catalysts in oxygenate conversion
TW412510B (en) * 1996-12-31 2000-11-21 Exxon Chemical Patents Inc Oxygenate conversions using small pore non-zeolitic molecular sieve catalysts
US6423879B1 (en) * 1997-10-02 2002-07-23 Exxonmobil Oil Corporation Selective para-xylene production by toluene methylation
JP4221532B2 (ja) * 1998-06-26 2009-02-12 三菱瓦斯化学株式会社 メチルアミン製造用触媒及び該触媒を用いたメチルアミン類の製造方法
US6388156B1 (en) * 1999-05-14 2002-05-14 Exxonmobil Chemical Patents Inc. Direct selective synthesis of para-xylene by reacting an aromatic compound with a methylating agent formed from CO, Co2 and H2
AU2001236984A1 (en) * 2000-03-01 2001-09-12 Exxonmobil Chemical Patents Inc Thorium-containing sapo molecular sieve for producing olefins
US6448197B1 (en) * 2000-07-13 2002-09-10 Exxonmobil Chemical Patents Inc. Method for making a metal containing small pore molecular sieve catalyst
AU2001275901A1 (en) * 2000-07-13 2002-01-30 Uop Llc Attrition resistant catalyst for light olefin production
CA2369318A1 (en) * 2002-01-28 2003-07-28 Universite Concordia Hybrid catalysts for the deep catalytic cracking of petroleum naphthas and other hydrocarbon feedstocks for the selective production of light olefins
CN1298427C (zh) * 2002-02-28 2007-02-07 埃克森美孚化学专利公司 分子筛组合物,含有该组合物的催化剂以及它们的制备方法和在转化方法中的应用

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