KR20030010669A - 불포화 니트릴 및 공액 디엔을 기재로 한 분지 공중합체 - Google Patents
불포화 니트릴 및 공액 디엔을 기재로 한 분지 공중합체 Download PDFInfo
- Publication number
- KR20030010669A KR20030010669A KR1020027016650A KR20027016650A KR20030010669A KR 20030010669 A KR20030010669 A KR 20030010669A KR 1020027016650 A KR1020027016650 A KR 1020027016650A KR 20027016650 A KR20027016650 A KR 20027016650A KR 20030010669 A KR20030010669 A KR 20030010669A
- Authority
- KR
- South Korea
- Prior art keywords
- copolymers
- conjugated dienes
- weight
- branched
- unsaturated nitriles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 150000002825 nitriles Chemical class 0.000 title claims abstract description 24
- 229920005605 branched copolymer Polymers 0.000 title claims abstract description 21
- 150000001993 dienes Chemical class 0.000 title claims abstract description 18
- 229920001577 copolymer Polymers 0.000 claims abstract description 35
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000001746 injection moulding Methods 0.000 claims abstract description 7
- 229920001971 elastomer Polymers 0.000 claims abstract description 6
- 238000004519 manufacturing process Methods 0.000 claims abstract description 5
- 239000000806 elastomer Substances 0.000 claims abstract description 4
- 229920006168 hydrated nitrile rubber Polymers 0.000 claims abstract description 4
- 238000001125 extrusion Methods 0.000 claims abstract description 3
- 239000000178 monomer Substances 0.000 claims description 20
- 238000006116 polymerization reaction Methods 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 239000000839 emulsion Substances 0.000 claims description 2
- 238000000465 moulding Methods 0.000 abstract description 9
- 229920000459 Nitrile rubber Polymers 0.000 description 21
- 229920000642 polymer Polymers 0.000 description 13
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
- 239000003607 modifier Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- -1 vinylnorborene Chemical class 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000004073 vulcanization Methods 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000007429 general method Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229910052717 sulfur Chemical group 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 238000001495 thermal field-flow fractionation Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- QZLAEIZEPJAELS-UHFFFAOYSA-N 2,4,4-trimethylpentane-2-thiol Chemical compound CC(C)(C)CC(C)(C)S QZLAEIZEPJAELS-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000007696 Kjeldahl method Methods 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- 150000001356 alkyl thiols Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 229920005684 linear copolymer Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229940102838 methylmethacrylate Drugs 0.000 description 1
- WZRWMBWPUCWZNN-UHFFFAOYSA-N nonane-4-thiol Chemical compound CCCCCC(S)CCC WZRWMBWPUCWZNN-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10027768.3 | 2000-06-07 | ||
| DE10027768A DE10027768A1 (de) | 2000-06-07 | 2000-06-07 | Verzweigte Copolymere auf Basis von ungesättigten Nitrilen und konjugierten Dienen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20030010669A true KR20030010669A (ko) | 2003-02-05 |
Family
ID=7644732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020027016650A Withdrawn KR20030010669A (ko) | 2000-06-07 | 2001-05-25 | 불포화 니트릴 및 공액 디엔을 기재로 한 분지 공중합체 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20030171518A1 (https=) |
| EP (1) | EP1297037A1 (https=) |
| JP (1) | JP4903973B2 (https=) |
| KR (1) | KR20030010669A (https=) |
| AU (1) | AU2001263939A1 (https=) |
| BR (1) | BR0111517A (https=) |
| CA (1) | CA2411680C (https=) |
| DE (1) | DE10027768A1 (https=) |
| MX (1) | MXPA02012109A (https=) |
| PL (1) | PL199382B1 (https=) |
| RU (1) | RU2003100394A (https=) |
| TW (1) | TWI307347B (https=) |
| WO (1) | WO2001094432A1 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6899500B2 (en) * | 2001-06-19 | 2005-05-31 | Illinois Tool Works Inc. | Fastner having multiple-bossed lead |
| CA2409434A1 (en) | 2002-10-17 | 2004-04-17 | Bayer Inc. | Polymer blends comprising low molecular weight nitrile rubber |
| CA2409429A1 (en) * | 2002-10-17 | 2004-04-17 | Bayer Inc. | Hydrogenated nitrile rubber composites with improved proccesability |
| CA2409436A1 (en) * | 2002-10-17 | 2004-04-17 | Bayer Inc. | Polymer composites comprising low molecular weight nitrile rubber |
| MXPA06002029A (es) * | 2003-08-22 | 2006-05-17 | Upjohn Co | N-aril-2-cianooxazolidinonas y sus derivados. |
| DE102007024008A1 (de) * | 2007-05-22 | 2008-11-27 | Lanxess Deutschland Gmbh | Nitrilkautschuke |
| EP2423234A1 (de) * | 2010-08-31 | 2012-02-29 | LANXESS Deutschland GmbH | Kautschukblends aus verschiedenen Nitrilkautschuken |
| MX2016003369A (es) * | 2013-09-30 | 2016-08-12 | Zeon Corp | Caucho de copolimero de nitrilo y metodo de produccion del mismo. |
| EP2860196A1 (de) | 2013-10-14 | 2015-04-15 | LANXESS Deutschland GmbH | Nitrilkautschuke mit niedrigen Emissionswerten |
| JP6864471B2 (ja) * | 2016-12-26 | 2021-04-28 | マクセルホールディングス株式会社 | 熱接着テープおよび熱接着テープの製造方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD124526A1 (de) * | 1975-11-17 | 1977-03-02 | Werner Hufenreuter | Verfahren zur herstellung von copolymeren mit verbesserten eigenschaften aus konzentrierten dienen und polaren vinylmonomeren |
| DD154702A1 (de) * | 1980-11-25 | 1982-04-14 | Joerg Stricker | Verfahren zur herstellung von butadien-acrylnitril-copolymerisaten |
| DE3329974A1 (de) * | 1983-08-19 | 1985-02-28 | Bayer Ag, 5090 Leverkusen | Herstellung von hydrierten nitrilkautschuken |
| DE3529252A1 (de) * | 1985-08-16 | 1987-02-19 | Bayer Ag | Verfahren zur selektiven hydrierung ungesaettigter verbindungen |
| US5627250A (en) * | 1993-03-30 | 1997-05-06 | Nippon Zion Co., Ltd. | Unsaturated nitrile-conjugated diene copolymer, process for producing same and rubber composition |
| EP0779301B1 (en) * | 1994-08-29 | 2000-08-23 | Nippon Zeon Co., Ltd. | Unsaturated nitrile-conjugated diene copolymer, process for producing the same, and vulcanizable rubber composition |
| JP3579929B2 (ja) * | 1994-08-29 | 2004-10-20 | 日本ゼオン株式会社 | 不飽和ニトリル−共役ジエン共重合体、その製造方法および加硫性ゴム組成物 |
| JP3603344B2 (ja) * | 1994-09-07 | 2004-12-22 | 日本ゼオン株式会社 | 不飽和ニトリル−共役ジエン共重合体、その製造方法および加硫性ゴム組成物 |
| JP3391116B2 (ja) * | 1994-09-30 | 2003-03-31 | 日本ゼオン株式会社 | ニトリル基含有高飽和共重合体ゴム、その製造方法および加硫性ゴム組成物 |
| US5651995A (en) * | 1994-09-30 | 1997-07-29 | Nippon Zeon Co., Ltd. | Highly saturated nitrile rubber, process for producing same, vulcanizable rubber composition, aqueous emulsion and adhesive composition |
-
2000
- 2000-06-07 DE DE10027768A patent/DE10027768A1/de not_active Withdrawn
-
2001
- 2001-05-25 JP JP2002501979A patent/JP4903973B2/ja not_active Expired - Fee Related
- 2001-05-25 AU AU2001263939A patent/AU2001263939A1/en not_active Abandoned
- 2001-05-25 BR BR0111517-0A patent/BR0111517A/pt not_active Application Discontinuation
- 2001-05-25 PL PL358983A patent/PL199382B1/pl unknown
- 2001-05-25 MX MXPA02012109A patent/MXPA02012109A/es unknown
- 2001-05-25 EP EP01938236A patent/EP1297037A1/de not_active Withdrawn
- 2001-05-25 KR KR1020027016650A patent/KR20030010669A/ko not_active Withdrawn
- 2001-05-25 RU RU2003100394/04A patent/RU2003100394A/ru not_active Application Discontinuation
- 2001-05-25 CA CA2411680A patent/CA2411680C/en not_active Expired - Fee Related
- 2001-05-25 WO PCT/EP2001/005970 patent/WO2001094432A1/de not_active Ceased
- 2001-05-28 US US10/297,292 patent/US20030171518A1/en not_active Abandoned
- 2001-06-06 TW TW090113636A patent/TWI307347B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BR0111517A (pt) | 2003-05-06 |
| AU2001263939A1 (en) | 2001-12-17 |
| PL358983A1 (en) | 2004-08-23 |
| CA2411680C (en) | 2011-07-26 |
| CA2411680A1 (en) | 2002-12-04 |
| US20030171518A1 (en) | 2003-09-11 |
| WO2001094432A1 (de) | 2001-12-13 |
| TWI307347B (en) | 2009-03-11 |
| RU2003100394A (ru) | 2004-07-10 |
| MXPA02012109A (es) | 2003-06-06 |
| DE10027768A1 (de) | 2001-12-13 |
| EP1297037A1 (de) | 2003-04-02 |
| JP2003535931A (ja) | 2003-12-02 |
| JP4903973B2 (ja) | 2012-03-28 |
| PL199382B1 (pl) | 2008-09-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0692496B1 (en) | Unsaturated nitrile/conjugated diene copolymer, process for producing the same, and rubber composition | |
| US10494467B2 (en) | Copolymer rubber containing nitrile groups | |
| US6548604B1 (en) | Rubber, crosslinkable rubber composition, and crosslinked object | |
| CN110023343B (zh) | 氢化的腈-二烯-羧酸酯共聚物 | |
| KR20030010669A (ko) | 불포화 니트릴 및 공액 디엔을 기재로 한 분지 공중합체 | |
| EP0115081B1 (en) | Elastomer acrylic ester type copolymer | |
| JP6641487B2 (ja) | 水素化ニトリル−ブタジエン−ｐｅｇアクリレートコポリマー | |
| WO2007090634A1 (en) | Polybutadiene compositions, methods and articles | |
| CA2030592A1 (en) | Tapered block copolymers | |
| JP7252212B2 (ja) | 高い熱伝導性を有する加硫可能なｈｎｂｒ組成物 | |
| KR101092052B1 (ko) | 블로우 성형성 및 도장성이 우수한 열가소성 수지 조성물 | |
| JP7440421B2 (ja) | 冷却剤と接触状態にある、ｈｎｂｒ－ｐｅｇアクリレートコポリマーを含む加硫物の使用 | |
| US4306043A (en) | Process for producing thermoplastic resins | |
| KR960016624B1 (ko) | Hcfc 내성이 우수한 열가소성 수지 조성물의 제조방법 | |
| US4644024A (en) | Pentadienyl chloride derived polymers | |
| JP2001288213A (ja) | 熱可塑性エラストマー組成物 | |
| JP2001343072A (ja) | 水素化クロロプレン系ゴムブーツ | |
| KR20210121546A (ko) | 니트릴계 공중합체의 제조방법 | |
| WO2021001357A1 (en) | Use of vulcanisates comprising peg acrylate-hnbr copolymer in contact with pah | |
| JP2001343049A (ja) | 水素化クロロプレン系ゴムベルト | |
| JP2001343091A (ja) | 水素化クロロプレン系ゴムホース | |
| JP2001342215A (ja) | 水素化クロロプレン系防振ゴム | |
| JPH0345636A (ja) | 成形加硫用ゴム組成物 | |
| JPH04130160A (ja) | 重合体組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20021206 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
| PC1203 | Withdrawal of no request for examination | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |