KR20020087962A - 저 폼 또는 폼 억제 계면활성제로서 사용되는 알콜알콕실레이트 - Google Patents
저 폼 또는 폼 억제 계면활성제로서 사용되는 알콜알콕실레이트 Download PDFInfo
- Publication number
- KR20020087962A KR20020087962A KR1020027013441A KR20027013441A KR20020087962A KR 20020087962 A KR20020087962 A KR 20020087962A KR 1020027013441 A KR1020027013441 A KR 1020027013441A KR 20027013441 A KR20027013441 A KR 20027013441A KR 20020087962 A KR20020087962 A KR 20020087962A
- Authority
- KR
- South Korea
- Prior art keywords
- alcohol
- average
- mixture
- alkyl
- foam
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/04—Saturated ethers
- C07C43/13—Saturated ethers containing hydroxy or O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
- C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
- C08G65/2609—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Polyethers (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Description
Claims (12)
- 하기 화학식 I의 알콜 알콕실레이트:화학식 IR1-O-(CH2-CHR5-O-)r(CH2-CH2-O-)n(CH2-CHR6-O-)s(CH2-CHR2-O-)mH상기 식에서,R1은 분지쇄가 1 개 이상인 C4-22알킬이고;R2는 C3-4알킬이며;R5는 C1-4알킬이고;R6는 메틸 또는 에틸이며;n은 1 내지 50의 평균치이고;m은 0 내지 20의 평균치이며;r은 0 내지 50의 평균치이고;s는 0 내지 50의 평균치이며;R5가 메틸 또는 에틸이거나, r이 0인 경우, m은 0.5 이상이다.
- 제1항에 있어서, R5는 메틸인 것인 알콜 알콕실레이트.
- 제1항 또는 제2항에 있어서, n은 4 내지 15의 평균치를 갖는 것인 알콜 알콕실레이트.
- 제1항 내지 제3항 중 어느 한 항에 있어서, m은 0.5 내지 4의 평균치를 갖는 것인 알콜 알콕실레이트.
- 제1항 내지 제4항 중 어느 한 항에 따른 1 종 이상의 알콜 알콕실레이트 20 내지 95 중량%와, R1이 동일한 탄소 원자 수를 가진 비분지쇄 알킬 라디칼인 상응하는 알콜 알콕실레이트 5 내지 80 중량%를 포함하는 혼합물.
- 하기 화학식 II의 알콜 알콕실레이트:화학식 IIR3-O-(CH2-CH2-O-)p(CH2-CHR4-O-)qH상기 식에서,R3는 분지쇄 또는 비분지쇄 C4-22알킬이고;R4는 C3-4알킬이며;p는 1 내지 50의 평균치이고;q는 0.5 내지 20의 평균치이다.
- 제6항에 있어서, R3는 분지쇄 또는 비분지쇄 C8-15알킬이고, R4는 프로필이며, q는 0.5 내지 4의 평균치를 갖는 것인 알콜 알콕실레이트.
- R3가 분지쇄 알킬 라디칼인 제6항 또는 제7항에 따른 1 종 이상의 알콜 알콕실레이트 5 내지 95 중량%와, R3가 동일한 탄소 원자 수를 가진 비분지쇄 알킬 라디칼인 상응하는 알콜 알콕실레이트 5 내지 95 중량%를 포함하는 혼합물.
- 화학식 R1-OH 또는 R3-OH의 알콜 또는 상응하는 분지쇄 및 비분지쇄 알콜의 혼합물을 임의로 C3-6알킬렌 옥시드와 반응시킨 다음, 에틸렌 옥시드와 반응시키고, 이어서 임의로 C3-4알킬렌 옥시드와 반응시킨 다음, C5-6알킬렌 옥시드와 반응시키는, 제1항 내지 제4항, 또는 제6항 또는 제7항 중 어느 한 항에 따른 알콜 알콕실레이트 또는 제5항 또는 제8항에 따른 혼합물의 제조 방법.
- 저 폼 또는 폼 억제 계면활성제로서의 제1항 내지 제4항, 제6항 또는 제7항에 따른 알콜 알콕실레이트, 또는 제5항 또는 제8항에 따른 혼합물의 용도.
- 제10항에 있어서,세제 및 세정제 조제물용 계면활성제로서,금속 가공 공업용 계면활성제로서,직물의 제조 및 가공용 계면활성제로서,피혁, 제지, 인쇄, 전기도금 및 사진 공업용 계면활성제로서,수처리용 계면활성제로서,곡물 보호 조제물용 계면활성제로서, 또는중합체 생산 및 중합체 가공 공업용 계면활성제 또는 유화제로서의 용도.
- 조제물의 총 중량을 기준으로, 제1항 내지 제4항, 제6항 또는 제7항 중 어느 한 항에 따른 1 종 이상의 알콜 알콕실레이트, 또는 제5항 또는 제8항에 따른 1 종 이상의 혼합물 0.1 내지 40 중량%를 포함하는 세제 또는 세정제.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10017197.4 | 2000-04-07 | ||
DE10017197A DE10017197A1 (de) | 2000-04-07 | 2000-04-07 | Alkoholalkoxylate als schaumarme oder schaumdämpfende Tenside |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20020087962A true KR20020087962A (ko) | 2002-11-23 |
KR100863757B1 KR100863757B1 (ko) | 2008-10-16 |
Family
ID=7637833
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020027013441A KR100863757B1 (ko) | 2000-04-07 | 2001-04-04 | 저 폼 또는 폼 억제 계면활성제로서 사용되는 알콜알콕실레이트 |
Country Status (13)
Country | Link |
---|---|
US (1) | US6680412B2 (ko) |
EP (1) | EP1276841B1 (ko) |
JP (1) | JP4898060B2 (ko) |
KR (1) | KR100863757B1 (ko) |
CN (1) | CN1234834C (ko) |
AT (1) | ATE261489T1 (ko) |
AU (1) | AU5477701A (ko) |
BR (1) | BR0109882B1 (ko) |
CA (1) | CA2406431C (ko) |
DE (2) | DE10017197A1 (ko) |
ES (1) | ES2218409T3 (ko) |
MX (1) | MX226142B (ko) |
WO (1) | WO2001077276A1 (ko) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MY137154A (en) * | 2002-01-21 | 2008-12-31 | Basf Ag | Alkylglycol alkoxylates or alkyldiglycol alkoxylates, mixtures thereof with tensides and their use |
US8129312B2 (en) * | 2002-04-24 | 2012-03-06 | Basf Se | Use of defined alcohol alkoxylates as adjuvants in the agrotechnical field |
AU2003232206A1 (en) * | 2002-04-26 | 2003-11-10 | Basf Aktiengesellschaft | C10-alkanolalkoxylate mixtures and the use thereof |
WO2003091191A1 (de) * | 2002-04-26 | 2003-11-06 | Basf Aktiengesellschaft | C10-alkanolalkoxylate und ihre verwendung |
CN1312099C (zh) * | 2002-04-26 | 2007-04-25 | 巴斯福股份公司 | 烷氧基化物混合物及包含该混合物的洗涤剂 |
DE10243365A1 (de) * | 2002-09-18 | 2004-04-01 | Basf Ag | Alkoxylate mit niedrigem Restalkohol-Gehalt |
DE10246140A1 (de) * | 2002-10-01 | 2004-04-15 | Basf Ag | Umsetzungsprodukte von 2-Propylheptanol mit1-Halogen-2,3-epoxypropanen und 1-Hydroxy-2,3-epoxypropan |
US7001634B2 (en) * | 2002-11-07 | 2006-02-21 | Bayer Materialscience Llc | Process for suppressing the foaming of an aqueous system |
KR20060064624A (ko) * | 2003-08-14 | 2006-06-13 | 바스프 악티엔게젤샤프트 | 벤즈아미독심 살진균 유도체를 위한 아쥬반트 형태의 알콜옥시알킬레이트의 용도, 적절한 약제 및 키트 |
US20070000075A1 (en) * | 2003-08-21 | 2007-01-04 | Manfred Jungen | Multifunctional textile-pretreating agent |
JP2009057392A (ja) * | 2005-12-28 | 2009-03-19 | Daikin Ind Ltd | フルオロポリマー水性分散液 |
US20080176997A1 (en) * | 2006-10-20 | 2008-07-24 | Fernandez Ana Maria | Surfactants and methods for using in emulsion polymerization reactions and polymer dispersions, and for stabilizing emulsion polymers and polymer dispersions |
EP2150515B1 (de) * | 2007-04-25 | 2016-08-24 | Basf Se | Alkoholalkoxylate, diese enthaltende mittel und verwendung der alkoholalkoxylate als adjuvans für den agrochemischen bereich |
WO2009013247A2 (de) * | 2007-07-20 | 2009-01-29 | Basf Se | Mittel enthaltend alkoholalkoxylate und verwendung der alkoholalkoxylate als adjuvans für den agrochemischen bereich |
JP5567496B2 (ja) * | 2008-01-11 | 2014-08-06 | ダウ グローバル テクノロジーズ エルエルシー | 界面活性剤として有用なアルキレンオキシドでキャップされた第2級アルコールアルコキシレート |
EP2271697B1 (de) * | 2008-04-24 | 2014-07-09 | Basf Se | Alkoholalkoxylate, diese enthaltende mittel und verwendung der alkoholalkoxylate als adjuvans für den agrochemischen bereich |
BRPI0917973A2 (pt) | 2008-08-11 | 2015-11-17 | Basf Se | processo para o pós-tratamento de materiais têxteis tingidos e/ ou impressos. |
WO2010036555A2 (en) * | 2008-09-24 | 2010-04-01 | Dow Global Technologies, Inc. | Alkylene oxide capped secondary alcohol ethoxylates as fermentation foam control agents |
TW201031743A (en) * | 2008-12-18 | 2010-09-01 | Basf Se | Surfactant mixture comprising branched short-chain and branched long-chain components |
US20110319669A1 (en) * | 2010-06-29 | 2011-12-29 | Wanglin Yu | Branched secondary alcohol alkoxylate surfactants and process to make them |
WO2016048764A1 (en) * | 2014-09-24 | 2016-03-31 | Dow Global Technologies Llc | Branched biodegradable low foam nonionic surfactants |
WO2023218409A1 (en) | 2022-05-11 | 2023-11-16 | Adama Makhteshim Ltd. | Phthalimide fungicide composition |
CN115124709B (zh) * | 2022-06-29 | 2023-04-21 | 东营市金美化工有限公司 | 以癸基十四醇为起始剂的聚醚破乳剂及其制备方法和应用 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3956401A (en) * | 1975-03-10 | 1976-05-11 | Olin Corporation | Low foaming, biodegradable, nonionic surfactants |
US4317940A (en) * | 1980-12-23 | 1982-03-02 | Olin Corporation | Biodegradable surfactants |
US4438014A (en) * | 1982-02-16 | 1984-03-20 | Union Carbide Corporation | Nonionic surfactants for automatic dishwasher detergents |
US4827028A (en) * | 1984-04-23 | 1989-05-02 | Olin Corporation | Anionic surfactants |
JPH05125391A (ja) * | 1991-03-28 | 1993-05-21 | Union Carbide Chem & Plast Technol Corp | 洗浄用組成物及びその使用方法 |
US5294365A (en) | 1991-12-12 | 1994-03-15 | Basf Corporation | Hydroxypolyethers as low-foam surfactants |
US5576281A (en) | 1993-04-05 | 1996-11-19 | Olin Corporation | Biogradable low foaming surfactants as a rinse aid for autodish applications |
DE4416303A1 (de) | 1994-05-09 | 1995-11-16 | Bayer Ag | Schaumarmes Netzmittel und seine Verwendung |
TW387937B (en) * | 1994-10-14 | 2000-04-21 | Olin Corp | Biodegradable surfactant and blends thereof as a rinse aid |
-
2000
- 2000-04-07 DE DE10017197A patent/DE10017197A1/de not_active Withdrawn
-
2001
- 2001-04-04 DE DE50101659T patent/DE50101659D1/de not_active Expired - Lifetime
- 2001-04-04 MX MXPA02009742 patent/MX226142B/es active IP Right Grant
- 2001-04-04 KR KR1020027013441A patent/KR100863757B1/ko active IP Right Grant
- 2001-04-04 EP EP01927871A patent/EP1276841B1/de not_active Expired - Lifetime
- 2001-04-04 BR BRPI0109882-9A patent/BR0109882B1/pt not_active IP Right Cessation
- 2001-04-04 US US10/239,884 patent/US6680412B2/en not_active Expired - Lifetime
- 2001-04-04 WO PCT/EP2001/003850 patent/WO2001077276A1/de active IP Right Grant
- 2001-04-04 AU AU54777/01A patent/AU5477701A/en not_active Abandoned
- 2001-04-04 JP JP2001575130A patent/JP4898060B2/ja not_active Expired - Fee Related
- 2001-04-04 AT AT01927871T patent/ATE261489T1/de not_active IP Right Cessation
- 2001-04-04 CA CA2406431A patent/CA2406431C/en not_active Expired - Fee Related
- 2001-04-04 ES ES01927871T patent/ES2218409T3/es not_active Expired - Lifetime
- 2001-04-04 CN CNB018089836A patent/CN1234834C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN1427884A (zh) | 2003-07-02 |
BR0109882B1 (pt) | 2011-02-08 |
US6680412B2 (en) | 2004-01-20 |
ATE261489T1 (de) | 2004-03-15 |
DE10017197A1 (de) | 2001-10-11 |
US20030092587A1 (en) | 2003-05-15 |
DE50101659D1 (de) | 2004-04-15 |
MX226142B (es) | 2005-02-08 |
JP2003530368A (ja) | 2003-10-14 |
WO2001077276A1 (de) | 2001-10-18 |
CA2406431A1 (en) | 2002-10-04 |
EP1276841B1 (de) | 2004-03-10 |
CN1234834C (zh) | 2006-01-04 |
KR100863757B1 (ko) | 2008-10-16 |
EP1276841A1 (de) | 2003-01-22 |
JP4898060B2 (ja) | 2012-03-14 |
BR0109882A (pt) | 2003-06-03 |
CA2406431C (en) | 2010-02-23 |
AU5477701A (en) | 2001-10-23 |
MXPA02009742A (es) | 2003-04-22 |
ES2218409T3 (es) | 2004-11-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR100863757B1 (ko) | 저 폼 또는 폼 억제 계면활성제로서 사용되는 알콜알콕실레이트 | |
JP5346299B2 (ja) | アルコキシレート混合物界面活性剤 | |
JP5567496B2 (ja) | 界面活性剤として有用なアルキレンオキシドでキャップされた第2級アルコールアルコキシレート | |
US7560494B2 (en) | Rapid low-foam wetting agents for hydrophobic surfaces | |
US7504373B2 (en) | Surfactant composition and method of forming | |
US6057284A (en) | Iso-tridecanolalkoxylates in block form as low-foam or antifoaming surfactants | |
JP2533555B2 (ja) | 清浄剤用添加剤およびそれを含む水性清浄剤 | |
KR101673275B1 (ko) | 알콕시화 2-프로필헵탄올을 포함하는 소포제 조성물 | |
JPS60255898A (ja) | 工業的洗浄のための末端基閉鎖の脂肪アルコールアルコキシレート | |
EP2382297B1 (en) | Surfactant compositions with wide ph stability | |
JP2011524940A (ja) | ミッドレンジ・アルコキシレートを含む洗浄用組成物 | |
JP2007527938A (ja) | アルコールアルコキシラートを含む組成物およびその使用 | |
TW201012783A (en) | Fluorosurfactants | |
KR20040111607A (ko) | 텍스타일 가공용 유연제 실리콘 제형 | |
JP6655336B2 (ja) | 繊維処理剤 | |
EP4334423A1 (en) | Process for ethoxylation of a mixture of straight chain fatty alcohol and branched chain fatty alcohol in a single stage reaction | |
KR20070036028A (ko) | 알콜 알콕실레이트를 함유하는 조성물 및 그 용도 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
E902 | Notification of reason for refusal | ||
E902 | Notification of reason for refusal | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20120925 Year of fee payment: 5 |
|
FPAY | Annual fee payment |
Payment date: 20130924 Year of fee payment: 6 |
|
FPAY | Annual fee payment |
Payment date: 20140919 Year of fee payment: 7 |
|
FPAY | Annual fee payment |
Payment date: 20150930 Year of fee payment: 8 |
|
FPAY | Annual fee payment |
Payment date: 20160929 Year of fee payment: 9 |
|
FPAY | Annual fee payment |
Payment date: 20170919 Year of fee payment: 10 |
|
FPAY | Annual fee payment |
Payment date: 20180928 Year of fee payment: 11 |