KR20020028848A - 반사방지 포로겐 - Google Patents
반사방지 포로겐 Download PDFInfo
- Publication number
- KR20020028848A KR20020028848A KR1020010062495A KR20010062495A KR20020028848A KR 20020028848 A KR20020028848 A KR 20020028848A KR 1020010062495 A KR1020010062495 A KR 1020010062495A KR 20010062495 A KR20010062495 A KR 20010062495A KR 20020028848 A KR20020028848 A KR 20020028848A
- Authority
- KR
- South Korea
- Prior art keywords
- porogen
- poly
- meth
- polysilica dielectric
- acrylate
- Prior art date
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- 239000003361 porogen Substances 0.000 title claims abstract description 206
- 230000003667 anti-reflective effect Effects 0.000 title description 55
- 239000000178 monomer Substances 0.000 claims abstract description 139
- 239000003989 dielectric material Substances 0.000 claims abstract description 136
- 239000000203 mixture Substances 0.000 claims abstract description 90
- 238000000034 method Methods 0.000 claims abstract description 59
- 239000006117 anti-reflective coating Substances 0.000 claims abstract description 21
- 125000000962 organic group Chemical group 0.000 claims abstract description 20
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 15
- 125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 claims abstract description 13
- 125000001624 naphthyl group Chemical group 0.000 claims abstract description 12
- 125000001792 phenanthrenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C=CC12)* 0.000 claims abstract description 12
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract description 3
- 239000010410 layer Substances 0.000 claims description 88
- 239000011159 matrix material Substances 0.000 claims description 75
- 229920002120 photoresistant polymer Polymers 0.000 claims description 60
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 58
- -1 γ-trimethoxysilylpropyl Chemical group 0.000 claims description 48
- 125000000217 alkyl group Chemical group 0.000 claims description 43
- 239000002245 particle Substances 0.000 claims description 38
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 25
- 239000000758 substrate Substances 0.000 claims description 22
- 230000000593 degrading effect Effects 0.000 claims description 21
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 20
- 229920001451 polypropylene glycol Polymers 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 17
- 125000003118 aryl group Chemical group 0.000 claims description 14
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 150000005215 alkyl ethers Chemical class 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 6
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 6
- HBWGDHDXAMFADB-UHFFFAOYSA-N ethenyl(triethyl)silane Chemical compound CC[Si](CC)(CC)C=C HBWGDHDXAMFADB-UHFFFAOYSA-N 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 125000003107 substituted aryl group Chemical group 0.000 claims description 5
- AJUBKAPANIUYJT-UHFFFAOYSA-N 2-methylprop-1-enyl(silyloxy)silane Chemical compound CC(C)=C[SiH2]O[SiH3] AJUBKAPANIUYJT-UHFFFAOYSA-N 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 4
- QRHCILLLMDEFSD-UHFFFAOYSA-N bis(ethenyl)-dimethylsilane Chemical compound C=C[Si](C)(C)C=C QRHCILLLMDEFSD-UHFFFAOYSA-N 0.000 claims description 4
- JRMHUZLFQVKRNB-UHFFFAOYSA-N bis(ethenyl)-diphenylsilane Chemical compound C=1C=CC=CC=1[Si](C=C)(C=C)C1=CC=CC=C1 JRMHUZLFQVKRNB-UHFFFAOYSA-N 0.000 claims description 4
- PMSZNCMIJVNSPB-UHFFFAOYSA-N bis(ethenyl)silicon Chemical compound C=C[Si]C=C PMSZNCMIJVNSPB-UHFFFAOYSA-N 0.000 claims description 4
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 4
- GCSJLQSCSDMKTP-UHFFFAOYSA-N ethenyl(trimethyl)silane Chemical group C[Si](C)(C)C=C GCSJLQSCSDMKTP-UHFFFAOYSA-N 0.000 claims description 4
- DSQPRECRRGZSCV-UHFFFAOYSA-N penta-1,4-dien-3-yl(phenyl)silane Chemical compound C=CC([SiH2]c1ccccc1)C=C DSQPRECRRGZSCV-UHFFFAOYSA-N 0.000 claims description 4
- VYRLHRGPAOAVTO-UHFFFAOYSA-N penta-1,4-dien-3-ylsilane Chemical compound [SiH3]C(C=C)C=C VYRLHRGPAOAVTO-UHFFFAOYSA-N 0.000 claims description 4
- UFHILTCGAOPTOV-UHFFFAOYSA-N tetrakis(ethenyl)silane Chemical compound C=C[Si](C=C)(C=C)C=C UFHILTCGAOPTOV-UHFFFAOYSA-N 0.000 claims description 4
- PKRKCDBTXBGLKV-UHFFFAOYSA-N tris(ethenyl)-methylsilane Chemical compound C=C[Si](C)(C=C)C=C PKRKCDBTXBGLKV-UHFFFAOYSA-N 0.000 claims description 4
- BNCOGDMUGQWFQE-UHFFFAOYSA-N tris(ethenyl)silicon Chemical compound C=C[Si](C=C)C=C BNCOGDMUGQWFQE-UHFFFAOYSA-N 0.000 claims description 4
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 claims description 3
- WJNKEHHLMRWLMC-UHFFFAOYSA-N bis(ethenyl)-phenylsilane Chemical compound C=C[SiH](C=C)C1=CC=CC=C1 WJNKEHHLMRWLMC-UHFFFAOYSA-N 0.000 claims description 3
- HFTNNOZFRQLFQB-UHFFFAOYSA-N ethenoxy(trimethyl)silane Chemical compound C[Si](C)(C)OC=C HFTNNOZFRQLFQB-UHFFFAOYSA-N 0.000 claims description 3
- OVOIHGSHJGMSMZ-UHFFFAOYSA-N ethenyl(triphenyl)silane Chemical compound C=1C=CC=CC=1[Si](C=1C=CC=CC=1)(C=C)C1=CC=CC=C1 OVOIHGSHJGMSMZ-UHFFFAOYSA-N 0.000 claims description 3
- MBGQQKKTDDNCSG-UHFFFAOYSA-N ethenyl-diethoxy-methylsilane Chemical compound CCO[Si](C)(C=C)OCC MBGQQKKTDDNCSG-UHFFFAOYSA-N 0.000 claims description 3
- BAVNDESSHRPRRF-UHFFFAOYSA-N ethenyl-diethyl-methylsilane Chemical compound CC[Si](C)(CC)C=C BAVNDESSHRPRRF-UHFFFAOYSA-N 0.000 claims description 3
- QDEZCOQKJSRQNN-UHFFFAOYSA-N ethenyl-dimethyl-phenylsilane Chemical compound C=C[Si](C)(C)C1=CC=CC=C1 QDEZCOQKJSRQNN-UHFFFAOYSA-N 0.000 claims description 3
- JEWCZPTVOYXPGG-UHFFFAOYSA-N ethenyl-ethoxy-dimethylsilane Chemical compound CCO[Si](C)(C)C=C JEWCZPTVOYXPGG-UHFFFAOYSA-N 0.000 claims description 3
- CHEFFAKKAFRMHG-UHFFFAOYSA-N ethenyl-tris(trimethylsilyloxy)silane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C=C CHEFFAKKAFRMHG-UHFFFAOYSA-N 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- DHWVPYLVNAKSEU-UHFFFAOYSA-N tert-butyl-dimethyl-prop-2-enoxysilane Chemical compound CC(C)(C)[Si](C)(C)OCC=C DHWVPYLVNAKSEU-UHFFFAOYSA-N 0.000 claims description 3
- AKQHUJRZKBYZLC-UHFFFAOYSA-N tri(propan-2-yl)-prop-2-enylsilane Chemical compound CC(C)[Si](C(C)C)(C(C)C)CC=C AKQHUJRZKBYZLC-UHFFFAOYSA-N 0.000 claims description 3
- UMFJXASDGBJDEB-UHFFFAOYSA-N triethoxy(prop-2-enyl)silane Chemical compound CCO[Si](CC=C)(OCC)OCC UMFJXASDGBJDEB-UHFFFAOYSA-N 0.000 claims description 3
- MNMVKGDEKPPREK-UHFFFAOYSA-N trimethyl(prop-2-enoxy)silane Chemical compound C[Si](C)(C)OCC=C MNMVKGDEKPPREK-UHFFFAOYSA-N 0.000 claims description 3
- HYWCXWRMUZYRPH-UHFFFAOYSA-N trimethyl(prop-2-enyl)silane Chemical compound C[Si](C)(C)CC=C HYWCXWRMUZYRPH-UHFFFAOYSA-N 0.000 claims description 3
- DXJZZRSMGLGFPW-UHFFFAOYSA-N triphenyl(prop-2-enyl)silane Chemical compound C=1C=CC=CC=1[Si](C=1C=CC=CC=1)(CC=C)C1=CC=CC=C1 DXJZZRSMGLGFPW-UHFFFAOYSA-N 0.000 claims description 3
- LFRDHGNFBLIJIY-UHFFFAOYSA-N trimethoxy(prop-2-enyl)silane Chemical compound CO[Si](OC)(OC)CC=C LFRDHGNFBLIJIY-UHFFFAOYSA-N 0.000 claims description 2
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- HXFBPZLMFXKESB-UHFFFAOYSA-N 2,2-diphenylethenyl(ethoxy)silane Chemical compound C(C)O[SiH2]C=C(C1=CC=CC=C1)C1=CC=CC=C1 HXFBPZLMFXKESB-UHFFFAOYSA-N 0.000 claims 2
- 229920000126 latex Polymers 0.000 claims 2
- 239000004816 latex Substances 0.000 claims 2
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 claims 2
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 25
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 37
- 229920000642 polymer Polymers 0.000 description 33
- 230000005855 radiation Effects 0.000 description 28
- 239000000463 material Substances 0.000 description 20
- 229910052751 metal Inorganic materials 0.000 description 16
- 239000002184 metal Substances 0.000 description 16
- 230000004888 barrier function Effects 0.000 description 13
- 239000004971 Cross linker Substances 0.000 description 11
- 238000000576 coating method Methods 0.000 description 10
- 239000011148 porous material Substances 0.000 description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 9
- 229910052802 copper Inorganic materials 0.000 description 9
- 239000010949 copper Substances 0.000 description 9
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 239000010408 film Substances 0.000 description 7
- 229920003209 poly(hydridosilsesquioxane) Polymers 0.000 description 7
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 229920001400 block copolymer Polymers 0.000 description 6
- 125000003709 fluoroalkyl group Chemical group 0.000 description 6
- 238000001465 metallisation Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 6
- 229920002554 vinyl polymer Polymers 0.000 description 6
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical group C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 125000005103 alkyl silyl group Chemical group 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 238000000151 deposition Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000005192 partition Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 description 4
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 4
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 102100026735 Coagulation factor VIII Human genes 0.000 description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
- 101000911390 Homo sapiens Coagulation factor VIII Proteins 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 4
- 239000011247 coating layer Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000003431 cross linking reagent Substances 0.000 description 4
- 125000005843 halogen group Chemical group 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 150000004767 nitrides Chemical class 0.000 description 4
- KBXJHRABGYYAFC-UHFFFAOYSA-N octaphenylsilsesquioxane Chemical compound O1[Si](O2)(C=3C=CC=CC=3)O[Si](O3)(C=4C=CC=CC=4)O[Si](O4)(C=5C=CC=CC=5)O[Si]1(C=1C=CC=CC=1)O[Si](O1)(C=5C=CC=CC=5)O[Si]2(C=2C=CC=CC=2)O[Si]3(C=2C=CC=CC=2)O[Si]41C1=CC=CC=C1 KBXJHRABGYYAFC-UHFFFAOYSA-N 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 238000000059 patterning Methods 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 3
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 3
- 239000004642 Polyimide Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 3
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 3
- 150000003926 acrylamides Chemical class 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 125000005370 alkoxysilyl group Chemical group 0.000 description 3
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 125000005677 ethinylene group Chemical group [*:2]C#C[*:1] 0.000 description 3
- DOMLXBPXLNDFAB-UHFFFAOYSA-N ethoxyethane;methyl prop-2-enoate Chemical compound CCOCC.COC(=O)C=C DOMLXBPXLNDFAB-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 238000003384 imaging method Methods 0.000 description 3
- 239000012212 insulator Substances 0.000 description 3
- 230000005693 optoelectronics Effects 0.000 description 3
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 238000005240 physical vapour deposition Methods 0.000 description 3
- 229920001721 polyimide Polymers 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 229910021332 silicide Inorganic materials 0.000 description 3
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- 125000000027 (C1-C10) alkoxy group Chemical group 0.000 description 2
- ZMARGGQEAJXRFP-UHFFFAOYSA-N 1-hydroxypropan-2-yl 2-methylprop-2-enoate Chemical compound OCC(C)OC(=O)C(C)=C ZMARGGQEAJXRFP-UHFFFAOYSA-N 0.000 description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- RFJVDJWCXSPUBY-UHFFFAOYSA-N 2-(difluoromethylidene)-4,4,5-trifluoro-5-(trifluoromethyl)-1,3-dioxolane Chemical compound FC(F)=C1OC(F)(F)C(F)(C(F)(F)F)O1 RFJVDJWCXSPUBY-UHFFFAOYSA-N 0.000 description 2
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical class CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 2
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 description 2
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- 238000001556 precipitation Methods 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000007155 step growth polymerization reaction Methods 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- BZBMBZJUNPMEBD-UHFFFAOYSA-N tert-butyl bicyclo[2.2.1]hept-2-ene-5-carboxylate Chemical compound C1C2C(C(=O)OC(C)(C)C)CC1C=C2 BZBMBZJUNPMEBD-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- ATZHWSYYKQKSSY-UHFFFAOYSA-N tetradecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)=C ATZHWSYYKQKSSY-UHFFFAOYSA-N 0.000 description 1
- AKRQMTFHUVDMIL-UHFFFAOYSA-N tetrakis(prop-2-enyl)silane Chemical compound C=CC[Si](CC=C)(CC=C)CC=C AKRQMTFHUVDMIL-UHFFFAOYSA-N 0.000 description 1
- OIUCPPFBFOLPIO-UHFFFAOYSA-N tetratriacontyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCOC(=O)C(C)=C OIUCPPFBFOLPIO-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- KEROTHRUZYBWCY-UHFFFAOYSA-N tridecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCOC(=O)C(C)=C KEROTHRUZYBWCY-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical class [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- PZJJKWKADRNWSW-UHFFFAOYSA-N trimethoxysilicon Chemical group CO[Si](OC)OC PZJJKWKADRNWSW-UHFFFAOYSA-N 0.000 description 1
- CLCMTDPVKAALLC-UHFFFAOYSA-N trimethoxysilyl 2-methylhex-2-enoate Chemical compound CCCC=C(C)C(=O)O[Si](OC)(OC)OC CLCMTDPVKAALLC-UHFFFAOYSA-N 0.000 description 1
- KRLHYNPADOCLAJ-UHFFFAOYSA-N undecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCOC(=O)C(C)=C KRLHYNPADOCLAJ-UHFFFAOYSA-N 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
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Abstract
Description
MeSQ 매트릭스 | 분자량 | 하이드록시 함량 |
A | 높음 | 낮음 |
B | 낮음 | 높음 |
C | 중간 | 중간 |
샘플 | 포로겐 | MeSQ 샘플 | 포로겐 % |
1 | BA/MAPS/TMPTMA(18/72/10) | A | 50 |
" | A/C(9:1) | 50 | |
2 | BA/MAPS/TMPTMA(45/45/10) | A | 50 |
" | B | 50 | |
3 | BA/MAPS/TMPTMA(72/18/10) | A | 50 |
" | B | 50 | |
" | C | 50 | |
" | C | 30 | |
4 | BA/HPMA/MAPS/TMPTMA(15/60/15/10) | A | 50 |
" | A | 30 | |
" | A/C(9:1) | 50 | |
" | B | 50 | |
" | C | 50 | |
" | C | 30 | |
5 | BA/HPMA/MAPS/TMPTMA(60/15/15/10) | A | 50 |
" | A/C(9:1) | 30 | |
" | 50 | ||
" | B | 50 | |
" | C | 50 | |
6 | BA/HPMA/MAPS/TMPTMA(15/15/60/10) | A | 50 |
" | A/C(9:1) | 50 | |
" | B | 50 | |
7 | BA/VTMOS/DVB(80/10/10) | C | 50 |
" | A/C(9:1) | 50 | |
" | B | 50 | |
8 | BA/VTMOS/DVB(85/5/10) | C | 50 |
" | A/C(9:1) | 50 | |
" | B | 50 | |
9 | PPGMEA260/VTMOS/DVB(80/10/10) | C | 50 |
" | A/C(9:1) | 50 | |
" | B | 50 | |
" | A | 30 | |
10 | PEGMEMA475/VTMOS/DVB(80/10/10) | C | 50 |
" | A/C(9:1) | 30 | |
" | A/C(9:1) | 50 | |
" | B | 50 | |
" | A | 30 | |
11 | PPGMEA260/VTMS/DVB(80/10/10) | C | 50 |
" | C | 30 | |
" | A/C(9:1) | 50 | |
" | B | 50 | |
" | A | 30 | |
12 | BA/VTMS/TMPTMA(80/10/10) | C | 50 |
" | C | 30 | |
" | A/C(9:1) | 50 | |
13 | ANTMA/HEMA/MMA/TMPTMA(37.7/24.2/31.1/7) | - | - |
14 | ANTMA/HEMA/MMA/TMPTMA(38.5/24.8/31.7/5) | - | - |
Claims (30)
- 제거가능한 포로겐을 포함하며, 이 포로겐이 하나 이상의 발색단(chromophore)을 포함하는, 다공성 유기 폴리실리카 유전물질을 형성하는데 유용한 조성물.
- 제 1 항에 있어서, 하나 이상의 발색단이 페닐, 치환된 페닐, 나프틸, 치환된 나프틸, 안트라세닐, 치환된 안트라세닐, 페난트레닐, 치환된 페난트레닐, 및 하나 이상의 (C4-C24)알킬 그룹을 함유한 모노머 중에서 선택되는 조성물.
- 제 2 항에 있어서, 하나 이상의 발색단이 다음 화학식 1의 모노머인 조성물:상기 식에서,R1은 H 또는 CH3이며;R2는 페닐, 벤질,중에서 선택된다.
- 제 2 항에 있어서, 하나 이상의 발색단이 (C4-C24)알킬 (메트)아크릴레이트인 조성물.
- 제 1 항에 있어서, 제거가능한 포로겐이 중합 단위로서 실릴 함유 모노머 및 폴리(알킬렌 옥사이드)모노머 중에서 선택된 하나 이상의 모노머를 추가로 포함하는 조성물.
- B-단계 유기 폴리실리카 유전물질과 포로겐을 포함하며, 포로겐이 하나 이상의 발색단을 포함하는 조성물.
- 제 6 항에 있어서, 하나 이상의 발색단이 페닐, 치환된 페닐, 나프틸, 치환된 나프틸, 안트라세닐, 치환된 안트라세닐, 페난트레닐, 치환된 페난트레닐, 및 하나 이상의 (C4-C24)알킬 그룹을 함유한 모노머 중에서 선택되는 조성물.
- 제 6 항에 있어서, 제거가능한 포로겐이 중합 단위로서 실릴 함유 모노머 및 폴리(알킬렌 옥사이드)모노머 중에서 선택된 하나 이상의 모노머를 추가로 포함하는 조성물.
- 제 8 항에 있어서, 실릴 함유 모노머가 비닐트리메틸실란, 비닐트리에틸실란, 비닐트리메톡시실란, 비닐트리에톡시실란, γ-트리메톡시실릴프로필(메트)아크릴레이트, 디비닐실란, 트리비닐실란, 디메틸디비닐실란, 디비닐메틸실란, 메틸트리비닐실란, 디페닐디비닐실란, 디비닐페닐실란, 트리비닐페닐실란, 디비닐메틸페닐실란, 테트라비닐실란, 디메틸비닐디실록산, 폴리(ap틸비닐실록산), 폴리(비닐하이드로실록산), 폴리(페닐비닐실록산), 알릴옥시-tert-부틸디메틸실란, 알릴옥시트리메틸실란, 알릴트리에톡시실란, 알릴트리-이소-프로필실란, 알릴트리메톡시실란, 알릴트리메틸실란, 알릴트리페닐실란, 디에톡시 메틸비닐실란, 디에틸 메틸비닐실란, 디메틸 에톡시비닐실란, 디메틸 페닐비닐실란, 에톡시 디페닐비닐실란, 메틸 비스(트리메틸실릴옥시)비닐실란, 트리아세톡시비닐실란, 트리에톡시비닐실란, 트리에틸비닐실란, 트리페닐비닐실란, 트리스(트리메틸실릴옥시)비닐실란, 비닐옥시트리메틸실란 및 이들의 혼합물 중에서 선택되는 조성물.
- 제 8 항에 있어서, 폴리(알킬렌 옥사이드)모노머가 폴리(프로필렌 옥사이드) 모노머, 폴리(에틸렌 옥사이드) 모노머, 폴리(에틸렌 옥사이드/프로필렌 옥사이드) 모노머, 폴리(프로필렌 글리콜)(메트)아크릴레이트, 폴리(프로필렌 글리콜) 알킬 에테르 (메트)아크릴레이트, 폴리(프로필렌 글리콜)페닐 에테르(메트)아크릴레이트, 폴리(프로필렌 글리콜) 4-노닐페놀 에테르(메트)아크릴레이트, 폴리(에틸렌 글리콜)(메트)아크릴레이트, 폴리(에틸렌 글리콜)알킬 에테르(메트)아크릴레이트, 폴리(에틸렌 글리콜)페닐 에테르(메트)아크릴레이트, 폴리(프로필렌/에틸렌 글리콜)알킬 에테르(메트)아크릴레이트 및 이들의 혼합물 중에서 선택되는 조성물.
- 제 6 항에 있어서, 포로겐이 중합 단위로서 하나 이상의 플루오르화 모노머를 추가로 포함하는 조성물.
- 제 6 항에 있어서, B-단계 유기 폴리실리카 유전체 매트릭스 물질이 다음 화학식 2를 가지고 있는 조성물:
((RR1SiO)a(R2SiO1.5)b(R3SiO1.5)c(SiO2)d)n 상기 식에서,R, R1, R2및 R3는 독립적으로 수소, (C1-C6)알킬, 아릴, 및 치환된 아릴 중에서 선택되며;a, c 및 d는 독립적으로 0 내지 1의 수이고;b는 0.2 내지 1의 수이며;n은 약 3 내지 약 10,000의 정수이며;단, a+b+c+d=1이고, R, R1및 R2중 적어도 하나는 수소가 아니다. - 제 6 항에 있어서, 포로겐이 약 0.5 내지 약 1000 nm의 입도를 가지는 조성물.
- 제 13 항에 있어서, 입도가 약 0.5 내지 약 200 nm인 조성물.
- 제 6 항에 있어서, 포로겐이 실질적으로 B-단계 유기 폴리실리카 유전체 매트릭스 물질과 상용성이 있는 조성물.
- a) 기판상에 포로겐을 포함하는 B-단계 유기 폴리실리카 유전물질을 배치하고;b) B-단계 유기 폴리실리카 유전물질을 경화시켜 실질적으로 포로겐을 분해하지 않고 유기 폴리실리카 유전체 매트릭스 물질을 형성한후;c) 유기 폴리실리카 유전체 매트릭스 물질을 적어도 부분적으로 포로겐을 제거하는 조건하에 처리하여 실질적으로 유기 폴리실리카 유전물질을 분해하지 않고 다공성 유기 폴리실리카 유전물질을 형성하는 단계를 포함하며,포로겐이 하나 이상의 발색단을 포함하는 것을 특징으로 하여 전자 디바이스를 제조하는 방법.
- a) 기판상에 포로겐을 포함하는 B-단계 유기 폴리실리카 유전물질을 배치하고;b) B-단계 유기 폴리실리카 유전물질을 경화시켜 실질적으로 포로겐을 분해하지 않고 유기 폴리실리카 유전체 매트릭스 물질을 형성하며;c) 포토레지스트를 유기 폴리실리카 유전체 매트릭스 물질상에 배치하고;d) 포토레지스트를 노광한후;e) 유기 폴리실리카 유전체 매트릭스 물질을 적어도 부분적으로 포로겐을 제거하는 조건하에 처리하여 실질적으로 유기 폴리실리카 유전물질을 분해하지 않고 다공성 유기 폴리실리카 유전물질을 형성하는 단계를 포함하며,포로겐이 하나 이상의 발색단을 포함하는 것을 특징으로 하여 전자 디바이스를 제조하는 방법.
- 제 17 항에 있어서, 하나 이상의 발색단이 페닐, 치환된 페닐, 나프틸, 치환된 나프틸, 안트라세닐, 치환된 안트라세닐, 페난트레닐, 치환된 페난트레닐, 및 하나 이상의 (C4-C24)알킬 그룹을 함유한 모노머 중에서 선택되는 방법.
- 제 17 항에 있어서, 제거가능한 포로겐이 중합 단위로서 실릴 함유 모노머및 폴리(알킬렌 옥사이드)모노머 중에서 선택된 하나 이상의 모노머를 추가로 포함하는 방법.
- 제 19 항에 있어서, 실릴 함유 모노머가 비닐트리메틸실란, 비닐트리에틸실란, 비닐트리메톡시실란, 비닐트리에톡시실란, γ-트리메톡시실릴프로필(메트)아크릴레이트, 디비닐실란, 트리비닐실란, 디메틸디비닐실란, 디비닐메틸실란, 메틸트리비닐실란, 디페닐디비닐실란, 디비닐페닐실란, 트리비닐페닐실란, 디비닐메틸페닐실란, 테트라비닐실란, 디메틸비닐디실록산, 폴리(메틸비닐실록산), 폴리(비닐하이드로실록산), 폴리(페닐비닐실록산), 알릴옥시-tert-부틸디메틸실란, 알릴옥시트리메틸실란, 알릴트리에톡시실란, 알릴트리-이소-프로필실란, 알릴트리메톡시실란, 알릴트리메틸실란, 알릴트리페닐실란, 디에톡시 메틸비닐실란, 디에틸 메틸비닐실란, 디메틸 에톡시비닐실란, 디메틸 페닐비닐실란, 에톡시 디페닐비닐실란, 메틸 비스(트리메틸실릴옥시)비닐실란, 트리아세톡시비닐실란, 트리에톡시비닐실란, 트리에틸비닐실란, 트리페닐비닐실란, 트리스(트리메틸실릴옥시)비닐실란, 비닐옥시트리메틸실란 및 이들의 혼합물 중에서 선택되는 방법.
- 제 19 항에 있어서, 폴리(알킬렌 옥사이드)모노머가 폴리(프로필렌 옥사이드) 모노머, 폴리(에틸렌 옥사이드) 모노머, 폴리(에틸렌 옥사이드/프로필렌 옥사이드) 모노머, 폴리(프로필렌 글리콜)(메트)아크릴레이트, 폴리(프로필렌 글리콜) 알킬 에테르 (메트)아크릴레이트, 폴리(프로필렌 글리콜)페닐 에테르(메트)아크릴레이트, 폴리(프로필렌 글리콜) 4-노닐페놀 에테르(메트)아크릴레이트, 폴리(에틸렌 글리콜)(메트)아크릴레이트, 폴리(에틸렌 글리콜)알킬 에테르(메트)아크릴레이트, 폴리(에틸렌 글리콜)페닐 에테르(메트)아크릴레이트, 폴리(프로필렌/에틸렌 글리콜)알킬 에테르(메트)아크릴레이트 및 이들의 혼합물 중에서 선택되는 방법.
- 제 17 항에 있어서, 포로겐이 중합 단위로서 하나 이상의 플루오르화 모노머를 추가로 포함하는 방법.
- 제 17 항에 있어서, B-단계 유기 폴리실리카 유전체 매트릭스 물질이 다음 화학식 2를 가지는 방법:[화학식 2]((RR1SiO)a(R2SiO1.5)b(R3SiO1.5)c(SiO2)d)n상기 식에서,R, R1, R2및 R3는 독립적으로 수소, (C1-C6)알킬, 아릴, 및 치환된 아릴 중에서 선택되며;a, c 및 d는 독립적으로 0 내지 1의 수이고;b는 0.2 내지 1의 수이며;n은 약 3 내지 약 10,000의 정수이며;단, a+b+c+d=1이고, R, R1및 R2중 적어도 하나는 수소가 아니다.
- 제 17 항에 있어서, 포로겐이 약 0.5 내지 약 1000 nm의 입도를 가지는 방법.
- 제 24 항에 있어서, 입도가 약 0.5 내지 약 200 nm인 방법.
- a) B-단계 유기 폴리실리카 유전물질에 제거가능한 포로겐을 배치하고;b) B-단계 유기 폴리실리카 유전물질을 경화하여 실질적으로 포로겐을 분해하지 않고 유기 폴리실리카 유전체 매트릭스 물질을 형성하며;c) 적어도 부분적으로 포로겐을 제거하는 조건하에 유기 폴리실리카 유전체 매트릭스 물질을 처리하여 실질적으로 유기 폴리실리카 유전물질을 분해하지 않고 다공성 유기 폴리실리카 유전물질을 형성하는 단계를 포함하며;포로겐은 하나 이상의 발색단을 포함하는 것을 특징으로 하여 다공성 유기 폴리실리카 유전물질을 제조하는 방법.
- 포로겐을 포함한 유기 폴리실리카 유전물질의 층을 포함하며, 포로겐이 하나 이상의 발색단을 포함하는 전자 디바이스.
- 제 27 항에 있어서, 유기 폴리실리카 유전물질이 다음 화학식 2를 가지는 디바이스:[화학식 2]((RR1SiO)a(R2SiO1.5)b(R3SiO1.5)c(SiO2)d)n상기 식에서,R, R1, R2및 R3는 독립적으로 수소, (C1-C6)알킬, 아릴, 및 치환된 아릴 중에서 선택되며;a, c 및 d는 독립적으로 0 내지 1의 수이고;b는 0.2 내지 1의 수이며;n은 약 3 내지 약 10,000의 정수이며;단, a+b+c+d=1이고, R, R1및 R2중 적어도 하나는 수소가 아니다.
- 제 27 항에 있어서, 하나 이상의 발색단이 페닐, 치환된 페닐, 나프틸, 치환된 나프틸, 안트라세닐, 치환된 안트라세닐, 페난트레닐, 치환된 페난트레닐, 및 하나 이상의 (C4-C24)알킬 그룹을 함유한 모노머 중에서 선택되는 디바이스.
- 유기 폴리실리카 유전물질상에 릴리프(relief) 이미지를 형성하는 단계를 포함하며, 릴리프 이미지가 반사방지 코팅층을 사용하지 않고 형성되는 것을 특징으로 하여 전자 디바이스를 제조하는 방법.
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JP2002284997A (ja) | 2002-10-03 |
KR100816664B1 (ko) | 2008-03-27 |
JP4758949B2 (ja) | 2011-08-31 |
TW588072B (en) | 2004-05-21 |
US6599951B2 (en) | 2003-07-29 |
JP2007238957A (ja) | 2007-09-20 |
EP1197998A3 (en) | 2005-12-21 |
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