KR20010034378A - 플루오로케미칼 벤조트리아졸 - Google Patents
플루오로케미칼 벤조트리아졸 Download PDFInfo
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- KR20010034378A KR20010034378A KR1020007008129A KR20007008129A KR20010034378A KR 20010034378 A KR20010034378 A KR 20010034378A KR 1020007008129 A KR1020007008129 A KR 1020007008129A KR 20007008129 A KR20007008129 A KR 20007008129A KR 20010034378 A KR20010034378 A KR 20010034378A
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- KR
- South Korea
- Prior art keywords
- benzotriazole
- fluorochemical
- fluorochemical benzotriazole
- composition
- metal
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
- B29C33/60—Releasing, lubricating or separating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/16—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms condensed with carbocyclic rings or ring systems
- C07D249/18—Benzotriazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/38—Heterocyclic nitrogen compounds
- C10M133/44—Five-membered ring containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/14—Nitrogen-containing compounds
- C23F11/149—Heterocyclic compounds containing nitrogen as hetero atom
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/261—In terms of molecular thickness or light wave length
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
Abstract
Description
박리 접착력 값 | ||||
기재 | 스코치(상표명) 브랜드 매직(상표명) 테이프 | 하이랜드(상표명) 브랜드 패키징 테이프 | ||
박리# | 박리력(N/100 mm) | 박리# | 박리력(N/100 mm) | |
비처리된 구리 | 1 | 40.4 | 1 | 19.3 |
2 | 40.6 | 2 | 24.2 | |
3 | 40.0 | 3 | 25.2 | |
4 | 37.5 | 4 | 25.8 | |
5 | 37.5 | 5 | 32.1 | |
6 | 37.7 | 6 | 30.2 | |
7 | 34.3 | |||
BTA-FCE-12로 처리된 구리 | 1 | 7.9 | 1 | 3.1 |
2 | 8.6 | 2 | 2.9 | |
3 | 7.2 | 3 | 3.1 | |
4 | 7.7 | 4 | 2.6 | |
5 | 8.2 | 5 | 2.5 | |
6 | 8.0 | 6 | 2.6 | |
7 | 8.3 | 7 | 2.6 | |
실리콘 금형 이형제로 처리된 구리 | 1 | 16.6 | 1 | 20.4 |
2 | 17.1 | 2 | 24.7 | |
3 | 20.0 | 3 | 29.5 | |
4 | 22.5 | 4 | 38.8 | |
5 | 22.0 | 5 | 42.2 | |
6 | 47.7 | |||
BTA로 처리된 구리 | 1 | 56.2 | 1 | 13.4 |
2 | 67.7 | 2 | 49.9 | |
3 | 63.5 | 3 | 72.5 | |
4 | 57.1 | 4 | 71.7 | |
5 | 57.8 | 5 | 70.8 | |
6 | 52.4 | 6 | 68.7 | |
7 | 52.5 | 7 | 68.4 |
XPS(ESCA)에 의한 각 구리 표면상에 검측할 수 있는 수준으로 존재하는 원소 | ||||||
시료 | 원자% 농도 | |||||
C | O | N | Cu | F | S | |
대조 시료-H2S에 노출되지 않음 | ||||||
비처리된 구리 | 50.5 | 22.9 | 검측되지 않음 | 26.6 | 검측되지 않음 | 검측되지 않음 |
BTA-FCE-12로 처리된 구리 | 39.0 | 3.1 | 3.8 | 0.9 | 53.2 | 검측되지 않음 |
BTA로 처리된 구리 | 65.4 | 0.9 | 24.8 | 8.9 | 검측되지 않음 | 검측되지 않음 |
100㎕ H2S에 1시간 동안 노출됨 | ||||||
비처리된 구리 | 58.8 | 7.0 | 검측되지 않음 | 19.6 | 검측되지 않음 | 14.6 |
BTA-FCE-12로 처리된 구리 | 39.1 | 3.3 | 3.9 | 0.9 | 52.8 | 검측되지 않음 |
BTA로 처리된 구리 | 63.2 | 2.1 | 25.3 | 8.6 | 검측되지 않음 | 0.8 |
Claims (24)
- 하기 화학식의 플루오로케미칼 벤조트리아졸.식중, Rf는 CnF2n+1-(CH2)m-(여기서, n은 1 내지 22의 정수이고, m은 0 또는 1 내지 3의 정수임)이고;X는 -CO2-, -SO3-, -CONH-, -O-, -S-, 공유 결합, -SO2NR- 또는 -NR-(여기서, R은 H 또는 C1내지 C5알킬렌임)이고;Y는 -CH2-이고, z는 0 또는 1이고;R1은 H, 저급 알킬 또는 Rf-X-Yz-이고,단, X가 -S- 또는 -O-이고, m이 0이고, z가 0인 경우, n≥7이고, X가 공유결합인 경우, m 또는 z는 1 이상이다.
- 제1항에 있어서, R1이 H인 플루오로케미칼 벤조트리아졸.
- 제1항에 있어서, n이 3 내지 12인 플루오로케미칼 벤조트리아졸.
- 제3항에 있어서, z가 0인 플루오로케미칼 벤조트리아졸.
- 제4항에 있어서, X가 -CO2-, -SO3-, -O-, -NR-, -SO2NR-, -NR- 또는 -S-인 플루오로케미칼 벤조트리아졸.
- 제5항에 있어서, n이 3 이상인 플루오로케미칼 벤조트리아졸.
- 제1항에 있어서, n이 6 내지 12인 플루오로케미칼 벤조트리아졸.
- 제7항에 있어서, m이 2이고, z가 0인 플루오로케미칼 벤조트리아졸.
- 제8항에 있어서, X가 -CO2-인 플루오로케미칼 벤조트리아졸.
- 제9항에 있어서, n이 10인 플루오로케미칼 벤조트리아졸.
- 제1항에 있어서, n이 6 이상이고, n+m이 8 내지 20인 플루오로케미칼 벤조트리아졸.
- 제1항의 화합물 1종 이상을 포함하는, 금속 또는 반금속(metalloid) 표면에 이형 또는 부식 억제 특성을 부여하기 위한 조성물.
- 제12항에 있어서, 상기 조성물이 제1항의 화합물 2종 이상을 포함하는 것인 조성물.
- 제12항에 있어서, 용매를 더 함유하는 것인 조성물.
- 제1항에 따른 플루오로케미칼 벤조트리아졸을 포함하는 조성물을 금속 또는 반금속 표면과 접촉시키는 단계를 포함하는, 상기 표면상에 접착성 초박막을 형성하는 방법.
- 제15항에 있어서, 상기 조성물이 용매를 더 포함하는 것인 방법.
- 제15항에 있어서, 상기 조성물이 용액 또는 증기 형태인 방법.
- 금속 또는 비금속 표면에 결합된 제1항에 따른 1종 이상의 플루오로케미칼 벤조트리아졸의 다수의 분자를 포함하며, 이때 다수의 분자는 실질적으로 연속되는 단층인 자가 결합된 필름을 형성하는 것인 초박막.
- 금속 또는 반금속 표면 및 이에 부착된 제1항에 따른 1종 이상의 플루오로케미칼 벤조트리아졸의 다수의 분자를 포함하는 자가 결합된 초박막을 포함하는 제품.
- 제12항에 있어서, 이형제 또는 부식 억제제로서 사용되는 것인 조성물.
- 하기 화학식의 플루오로케미칼 벤조트리아졸 1종 이상을 포함하는 이형제로서 사용하기 위한 조성물.식중, Rf는 CnF2n+1-(CH2)m-(여기서, n은 1 내지 22의 정수이고, m은 0 또는 1 내지 3의 정수임)이고;X는 -CO2-, -SO3-, -S-, -O-, -CONH-, 공유 결합, -SO2NR- 또는 -NR-(여기서, R은 H 또는 C1내지 C5알킬렌임)이고, q는 0 또는 1이고;Y는 C1내지 C4알킬렌이고, z는 0 또는 1이고;R1은 H, 저급 알킬 또는 Rf-X-Yz-이다.
- 금속 또는 반금속 표면 및 이에 부착된 제19항에 따른 1종 이상의 플루오로케미칼 벤조트리아졸의 다수의 분자를 포함하는 자가 결합된 초박막을 포함하는, 이형 표면을 갖는 제품.
- 제19항에 따른 플루오로케미칼 벤조트리아졸을 포함하는 조성물을 금속 또는 반금속 표면과 접촉시키는 단계를 포함하는, 상기 표면상에 접착성 초박막 형태로 이형제를 형성하는 방법.
- 금속 또는 비금속 표면에 결합된 제19항에 따른 1종 이상의 플루오로케미칼 벤조트리아졸의 다수의 분자를 포함하며, 이때 다수의 분자는 실질적으로 연속되는 단층인 자가 결합된 필름을 형성하는 초박막 형태의 이형제.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US1409898A | 1998-01-27 | 1998-01-27 | |
US09/014,098 | 1998-01-27 |
Publications (2)
Publication Number | Publication Date |
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KR20010034378A true KR20010034378A (ko) | 2001-04-25 |
KR100530819B1 KR100530819B1 (ko) | 2005-11-24 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR10-2000-7008129A KR100530819B1 (ko) | 1998-01-27 | 1999-01-15 | 플루오로케미칼 벤조트리아졸 |
Country Status (9)
Country | Link |
---|---|
US (1) | US6376065B1 (ko) |
EP (1) | EP1051408B1 (ko) |
JP (2) | JP4652567B2 (ko) |
KR (1) | KR100530819B1 (ko) |
CN (1) | CN1132821C (ko) |
AU (1) | AU2230599A (ko) |
DE (1) | DE69910732T2 (ko) |
MY (1) | MY122213A (ko) |
WO (1) | WO1999037626A1 (ko) |
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1999
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- 1999-01-15 AU AU22305/99A patent/AU2230599A/en not_active Abandoned
- 1999-01-15 CN CN998023612A patent/CN1132821C/zh not_active Expired - Lifetime
- 1999-01-15 EP EP99902286A patent/EP1051408B1/en not_active Expired - Lifetime
- 1999-01-15 JP JP2000528550A patent/JP4652567B2/ja not_active Expired - Fee Related
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- 1999-01-15 DE DE69910732T patent/DE69910732T2/de not_active Expired - Lifetime
- 1999-01-26 MY MYPI99000260A patent/MY122213A/en unknown
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JP4652567B2 (ja) | 2011-03-16 |
KR100530819B1 (ko) | 2005-11-24 |
MY122213A (en) | 2006-03-31 |
CN1289327A (zh) | 2001-03-28 |
JP2002501057A (ja) | 2002-01-15 |
DE69910732T2 (de) | 2004-06-17 |
DE69910732D1 (de) | 2003-10-02 |
WO1999037626A1 (en) | 1999-07-29 |
EP1051408A1 (en) | 2000-11-15 |
AU2230599A (en) | 1999-08-09 |
JP2011016805A (ja) | 2011-01-27 |
CN1132821C (zh) | 2003-12-31 |
EP1051408B1 (en) | 2003-08-27 |
US6376065B1 (en) | 2002-04-23 |
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