KR20000070671A - 수 분산성/재분산성 소수성 폴리에스테르 수지 및 피복물에서의그의 용도 - Google Patents
수 분산성/재분산성 소수성 폴리에스테르 수지 및 피복물에서의그의 용도 Download PDFInfo
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Abstract
Description
Claims (41)
- 하기 화학식 1의 수분산성 및 소수성 폴리에스테르 수지로서,식중 I는 약 1 내지 20 중량%의 양으로 존재하고, 폴리에스테르 골격은 약 30 내지 80 중량%의 양으로 존재하며, 지방족 지방산 기는 약 10 내지 60 중량%의 양으로 존재하고;상기 수지로 피복된 셀룰로스성 기재의 표면에 수적이 적용될 때 98°이상의 초기 접촉각을 나타낼 만큼 높은 발수성(water repellency)을 나타내는 수지:화학식 1In-P-Am상기 식에서,I는 이온성 기이고;n은 이온성 기의 수를 정의하는 1 내지 3의 정수이고;P는 폴리에스테르 골격이고;A는 지방족 지방산 기이고;m은 지방족 지방산 기의 수를 정의하는 3 내지 8의 정수이다.
- 제 1 항에 있어서,식중 I가 5 내지 10 중량%의 양으로 존재하는 수분산성 및 소수성 폴리에스테르 수지.
- 제 1 항에 있어서,식중 폴리에스테르 골격(P)이 50 내지 60 중량%의 양으로 존재하는 수분산성 및 소수성 폴리에스테르 수지.
- 제 1 항에 있어서,식중 지방산 기(A)가 20 내지 40 중량%의 양으로 존재하는 수분산성 및 소수성 폴리에스테르 수지.
- 제 1 항에 있어서,식중 I가 트리멜리트산 무수물, 트리멜리트산 및 말레산 무수물로 구성된 그룹으로부터 선택된 폴리카복실산 또는 무수물로부터 유래하는 수분산성 및 소수성 폴리에스테르 수지.
- 제 1 항에 있어서,식중 폴리에스테르 골격(P)이 폴리에틸렌 테레프탈레이트, 폴리프로필렌 테레프탈레이트 및 폴리부틸렌 테레프탈레이트로 구성된 그룹으로부터 선택된 폴리알킬렌 테레프탈레이트인 수분산성 및 소수성 폴리에스테르 수지.
- 제 1 항에 있어서,식중 지방산 기(A)가 스테아르산, 베헨산, 팔미트산, 라우르산, 올레산 및 리놀레산으로 구성된 그룹으로부터 선택되는 수분산성 및 소수성 폴리에스테르 수지.
- 테레프탈레이트 중합체 30 내지 70 중량%; 2개 이상의 하이드록실 기를 갖는 하이드록시 작용성 화합물 5 내지 40 중량%; 2개 이상의 카복실 기를 갖는 카복시 작용성 화합물 1 내지 20 중량%; 및 C6내지 C24의 직쇄 또는 분지쇄 지방산 및 그의 트리글리세라이드로 구성된 그룹으로부터 선택된 소수성 화합물 10 내지 60 중량%로 이루어진 반응 생성물을 포함하고, 또한 하이드록시 작용성 화합물이 소수성 잔기의 1 내지 3배 당량으로 존재함을 특징으로 하는, 수분산성 및 소수성 폴리에스테르 수지.
- 제 8 항에 있어서,하기 화학식 2 단위의 폐 테레프탈레이트의 반응 생성물을 포함하는 수분산성 및 소수성 폴리에스테르 수지:화학식 2상기 식에서,R은 하기 화학식 3을 갖는, 탄소수 2 내지 10의 지방족 또는 사이클로지방족 글리콜, 또는 산소화 글리콜이다:화학식 3HO(CxH2xO)nCxH2xOH상기 식에서,x는 2 내지 4의 정수이고, n은 1 내지 10이다.
- 제 8 항에 있어서,폐 테레프탈레이트 중합체가 폴리에틸렌 테레프탈레이트, 폴리 1,2-프로필렌 테레프탈레이트, 폴리 1,3-프로필렌 테레프탈레이트, 폴리부틸렌 테레프탈레이트, 폴리(사이클로헥산디메탄올 테레프탈레이트) 또는 이들의 혼합물인, 수분산성 및 소수성 폴리에스테르 수지.
- 제 8 항에 있어서,2개 이상의 하이드록실 기를 갖는 하이드록시 작용성 화합물이 에틸렌 글리콜, 디에틸렌 글리콜, 트리에틸렌 글리콜, 사이클로헥산디메탄올, 프로필렌 글리콜, 1,2-프로필렌 글리콜, 1,3-프로판디올, 1,2-부틸렌 글리콜, 1,3-부탄디올, 1,4-부탄디올, 네오펜틸 글리콜, 1,5-펜탄디올, 1,6-헥산디올, 글리세롤, 트리메틸롤프로판, 트리메틸롤에탄, 펜타에리트리톨, 에리트리톨 및 단당류로 구성된 그룹으로부터 선택되는, 수분산성 및 소수성 폴리에스테르 수지.
- 제 8 항에 있어서,2개 이상의 하이드록실 기를 갖는 하이드록시 작용성 화합물이 하이드록실 작용성 화합물의 하이드록실 기 1몰당 5 내지 30몰의 에틸렌 옥사이드, 프로필렌 옥사이드 또는 이들의 혼합물로 옥시알킬화된 글리세롤, 트리메틸롤프로판, 트리메틸롤에탄, 펜타에리트리톨, 에리트리톨, 및 단당류의 유도체로 구성된 그룹으로부터 선택되는, 수분산성 및 소수성 폴리에스테르 수지.
- 제 8 항에 있어서,2개 이상의 카복실 기를 갖는 카복시 작용성 화합물이 트리멜리트산, 트리멜리트산 무수물, 말레산, 말레산 무수물, 푸마르산 및 이소프탈산으로 구성된 그룹으로부터 선택되는, 수분산성 및 소수성 폴리에스테르 수지.
- 제 8 항에 있어서,소수성 화합물이 스테아르산, 올레산, 리놀레산, 베헨산, 라우르산, 팔미트산, 우지(beef tallow), 돈지(lard), 옥수수유 및 대두유로 구성된 그룹으로부터 선택되는, 수분산성 및 소수성 폴리에스테르 수지.
- 제 8 항에 있어서,폴리에틸렌 테레프탈레이트 중합체 40 내지 60 중량%; 네오펜틸글리콜 1 내지 10 중량%; 펜타에리트리톨 5 내지 10 중량%; 트리멜리트산 또는 트리멜리트산 무수물 3 내지 15 중량%; 및 스테아르산 10 내지 45 중량%로 이루어진 반응 생성물을 포함하는, 수분산성 및 소수성 폴리에스테르 수지.
- 제 8 항에 있어서,모노부틸 주석산 또는 테트라알킬 티타네이트, 또는 이들의 혼합물의 존재하에 제조된 반응 생성물을 포함하는, 수분산성 및 소수성 폴리에스테르 수지.
- 제 8 항에 있어서,알칼리 금속 또는 암모늄 하이드록사이드, 또는 알칼리 금속 또는 암모늄 카보네이트와 함께 물에 분산되는, 수분산성 및 소수성 폴리에스테르 수지.
- 제 15 항에 있어서,알칼리 금속 또는 암모늄 하이드록사이드, 또는 알칼리 금속 또는 암모늄 카보네이트와 함께 물에 분산되는, 수분산성 및 소수성 폴리에스테르 수지.
- 테레프탈레이트 중합체 30 내지 70 중량%; 2개 이상의 하이드록실 기를 갖는 하이드록시 작용성 화합물 5 내지 40 중량%; 2개 이상의 카복실 기를 갖는 카복시 작용성 화합물 1 내지 20 중량%; 및 C6내지 C24의 직쇄 또는 분지쇄 지방산 및 그의 트리글리세라이드로 구성된 그룹으로부터 선택된 소수성 화합물 10 내지 60 중량%로 이루어진 반응 생성물을 포함하는 수분산성 및 소수성 폴리에스테르 피복 조성물로 피복된 기재를 포함하는 제품.
- 제 19 항에 있어서,기재가 섬유인 제품.
- 제 19 항에 있어서,기재가 종이인 제품.
- 제 19 항에 있어서,기재가 직물인 제품.
- 제 19 항에 있어서,기재가 식품 포장재인 제품.
- 제 19 항에 있어서,기재가 릴리이스지(release paper)인 제품.
- 제 19 항에 있어서,기재가 콘크리트인 제품.
- 제 19 항에 있어서,테레프탈레이트 중합체가 하기 화학식 2의 단위의 폐 테레프탈레이트인 피복된 제품:화학식 2상기 식에서,R은 하기 화학식 3을 갖는, 탄소수 2 내지 10의 지방족 또는 사이클로지방족 글리콜, 또는 산소화 글리콜이다:화학식 3HO(CxH2xO)nCxH2xOH상기 식에서,x는 2 내지 4의 정수이고, n은 1 내지 10이다.
- 제 26 항에 있어서,폐 테레프탈레이트 중합체가 폴리에틸렌 테레프탈레이트, 폴리 1,2-프로필렌 테레프탈레이트, 폴리 1,3-프로필렌 테레프탈레이트, 폴리부틸렌 테레프탈레이트, 폴리(사이클로헥산디메탄올 테레프탈레이트) 또는 이들의 혼합물인 피복된 제품.
- 제 19 항에 있어서,2개 이상의 하이드록실 기를 갖는 하이드록시 작용성 화합물이 에틸렌 글리콜, 디에틸렌 글리콜, 트리에틸렌 글리콜, 사이클로헥산디메탄올, 프로필렌 글리콜, 1,2-프로필렌 글리콜, 1,3-프로판디올, 1,2-부틸렌 글리콜, 1,3-부탄디올, 1,4-부탄디올, 네오펜틸 글리콜, 1,5-펜탄디올, 1,6-헥산디올, 글리세롤, 트리메틸올프로판, 트리메틸올에탄, 펜타에리트리톨, 에리트리톨 및 단당류로 구성된 그룹으로부터 선택되는 피복된 제품.
- 제 19 항에 있어서,2개 이상의 하이드록실 기를 갖는 하이드록시 작용성 화합물이 하이드록시 작용성 화합물의 하이드록실 기 1몰당 5 내지 30몰의 에틸렌 옥사이드, 프로필렌 옥사이드 또는 이들의 혼합물로 옥시알킬화된 글리세롤, 트리메틸올프로판, 트리메틸올에탄, 펜타에리트리톨, 에리트리톨, 및 단당류의 유도체로 구성된 그룹으로부터 선택되는 피복된 제품.
- 제 19 항에 있어서,2개 이상의 카복실 기를 갖는 카복시 작용성 화합물이 트리멜리트산, 트리멜리트산 무수물, 말레산, 말레산 무수물, 푸마르산 및 이소프탈산으로 구성된 그룹으로부터 선택되는 피복된 제품.
- 제 19 항에 있어서,소수성 화합물이 스테아르산, 올레산, 리놀레산, 베헨산, 라우르산, 팔미트산, 우지, 돈지, 옥수수유 및 대두유로 구성된 그룹으로부터 선택되는 피복된 제품.
- 폴리에틸렌 테레프탈레이트 중합체 40 내지 60 중량%; 네오펜틸글리콜 1 내지 10 중량%; 펜타에리트리톨 5 내지 10 중량%; 트리멜리트산 또는 트리멜리트산 무수물 3 내지 15 중량%; 및 스테아르산 10 내지 45 중량%로 이루어진 반응 생성물을 포함하는 수분산성 및 소수성 폴리에스테르 피복 조성물로 피복된기재를 포함하는 제품.
- 제 32 항에 있어서,기재가 섬유인 제품.
- 제 32 항에 있어서,기재가 종이인 제품.
- 제 32 항에 있어서,기재가 직물인 제품.
- 제 32 항에 있어서,기재가 식품 포장재인 제품.
- 제 32 항에 있어서,기재가 릴리이스지인 제품.
- 제 32 항에 있어서,기재가 콘크리트인 제품.
- 테레프탈레이트 중합체 30 내지 70 중량%; 2개 이상의 하이드록실 기를 갖는 하이드록시 작용성 화합물 5 내지 40 중량%; 2개 이상의 카복실 기를 갖는 카복시 작용성 화합물 1 내지 20 중량%; 및 C6내지 C24의 직쇄 또는 분지쇄 지방산 및 그의 트리글리세라이드로 구성된 그룹으로부터 선택된 소수성 화합물 10 내지 60 중량%로 이루어진 반응 생성물을 포함하는, 발수성 폴리에스테르 피복 조성물.
- 폴리에틸렌 테레프탈레이트 중합체 40 내지 60 중량%; 네오펜틸글리콜 1 내지 10 중량%; 펜타에리트리톨 5 내지 10 중량%; 트리멜리트산 또는 트리멜리트산 무수물 3 내지 15 중량%; 및 스테아르산 10 내지 45 중량%로 이루어진 반응 생성물을 포함하는, 발수성 폴리에스테르 피복 조성물.
- 테레프탈레이트 중합체 30 내지 70 중량%; 2개 이상의 하이드록실 기를 갖는 하이드록시 작용성 화합물 5 내지 40 중량%; 2개 이상의 카복실 기를 갖는 카복시 작용성 화합물 1 내지 20 중량%; 및 C6내지 C24의 직쇄 또는 분지쇄 지방산 및 그의 트리글리세라이드로 구성된 그룹으로부터 선택된 소수성 화합물 10 내지 60 중량%로 이루어진 반응 생성물을 포함하는 조성물을 섬유상 기재 및 가죽으로 구성된 그룹으로부터 선택된 기재에 도포함을 포함하는, 이러한 기재에 발수성을 부여하는 방법.
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US08/792,635 US5858551A (en) | 1997-01-31 | 1997-01-31 | Water dispersible/redispersible hydrophobic polyester resins and their application in coatings |
US8/792,635 | 1997-01-31 | ||
US08/792,635 | 1997-01-31 | ||
PCT/US1998/001075 WO1998033646A1 (en) | 1997-01-31 | 1998-01-27 | Water dispersible/redispersible hydrophobic polyester resins and their application in coatings |
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KR20000070671A true KR20000070671A (ko) | 2000-11-25 |
KR100650696B1 KR100650696B1 (ko) | 2006-11-27 |
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KR1019997006920A KR100650696B1 (ko) | 1997-01-31 | 1998-01-27 | 수 분산성/재분산성 소수성 폴리에스테르 수지 및 코팅물에서의 그의 용도 |
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US (2) | US5858551A (ko) |
EP (1) | EP0960021B1 (ko) |
JP (1) | JP2001510498A (ko) |
KR (1) | KR100650696B1 (ko) |
CN (1) | CN1251550A (ko) |
AT (1) | ATE243113T1 (ko) |
AU (1) | AU715768B2 (ko) |
BR (1) | BR9807045A (ko) |
CA (1) | CA2279274C (ko) |
DE (1) | DE69815660T2 (ko) |
EA (1) | EA001544B1 (ko) |
PL (1) | PL334858A1 (ko) |
WO (1) | WO1998033646A1 (ko) |
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- 1997-01-31 US US08/792,635 patent/US5858551A/en not_active Expired - Lifetime
-
1998
- 1998-01-27 AU AU62445/98A patent/AU715768B2/en not_active Ceased
- 1998-01-27 DE DE1998615660 patent/DE69815660T2/de not_active Expired - Lifetime
- 1998-01-27 JP JP53293998A patent/JP2001510498A/ja active Pending
- 1998-01-27 KR KR1019997006920A patent/KR100650696B1/ko active IP Right Grant
- 1998-01-27 EA EA199900697A patent/EA001544B1/ru not_active IP Right Cessation
- 1998-01-27 CN CN98803805A patent/CN1251550A/zh active Pending
- 1998-01-27 CA CA2279274A patent/CA2279274C/en not_active Expired - Lifetime
- 1998-01-27 PL PL33485898A patent/PL334858A1/xx unknown
- 1998-01-27 EP EP19980904606 patent/EP0960021B1/en not_active Expired - Lifetime
- 1998-01-27 BR BR9807045A patent/BR9807045A/pt not_active Application Discontinuation
- 1998-01-27 AT AT98904606T patent/ATE243113T1/de not_active IP Right Cessation
- 1998-01-27 WO PCT/US1998/001075 patent/WO1998033646A1/en active IP Right Grant
- 1998-10-22 US US09/176,942 patent/US5958601A/en not_active Expired - Lifetime
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AU715768B2 (en) | 2000-02-10 |
AU6244598A (en) | 1998-08-25 |
JP2001510498A (ja) | 2001-07-31 |
US5958601A (en) | 1999-09-28 |
US5858551A (en) | 1999-01-12 |
CA2279274A1 (en) | 1998-08-06 |
CN1251550A (zh) | 2000-04-26 |
EP0960021A1 (en) | 1999-12-01 |
KR100650696B1 (ko) | 2006-11-27 |
BR9807045A (pt) | 2000-03-28 |
DE69815660T2 (de) | 2004-05-13 |
WO1998033646A1 (en) | 1998-08-06 |
ATE243113T1 (de) | 2003-07-15 |
EP0960021A4 (en) | 2001-05-02 |
EP0960021B1 (en) | 2003-06-18 |
DE69815660D1 (de) | 2003-07-24 |
CA2279274C (en) | 2010-03-16 |
EA199900697A1 (ru) | 2000-02-28 |
PL334858A1 (en) | 2000-03-27 |
EA001544B1 (ru) | 2001-04-23 |
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