KR102737311B1 - 당으로부터 에틸렌글리콜의 제조를 위한 과정 - Google Patents

당으로부터 에틸렌글리콜의 제조를 위한 과정 Download PDF

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KR102737311B1
KR102737311B1 KR1020187022285A KR20187022285A KR102737311B1 KR 102737311 B1 KR102737311 B1 KR 102737311B1 KR 1020187022285 A KR1020187022285 A KR 1020187022285A KR 20187022285 A KR20187022285 A KR 20187022285A KR 102737311 B1 KR102737311 B1 KR 102737311B1
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oxygenate
reactor
composition
hydrogenation
compound
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KR20180100613A (ko
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마틴 스팬스버그 홀름
크리스티안 마루프 오스문센
에스벤 타닝
아만다 비르짓트 쇨뵈이
모르텐 보베르그 라르센
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토프쉐 에이/에스
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C07C27/04—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by reduction of oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C07C31/202—Ethylene glycol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C07C31/205—1,3-Propanediol; 1,2-Propanediol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C07C47/19—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen containing hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/00033—Continuous processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00277—Apparatus
    • B01J2219/00452—Means for the recovery of reactants or products
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020187022285A 2016-01-07 2017-01-05 당으로부터 에틸렌글리콜의 제조를 위한 과정 Active KR102737311B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DKPA201600008 2016-01-07
DKPA201600008 2016-01-07
PCT/EP2017/050183 WO2017118686A1 (en) 2016-01-07 2017-01-05 Process for the preparation of ethylene glycol from sugars

Publications (2)

Publication Number Publication Date
KR20180100613A KR20180100613A (ko) 2018-09-11
KR102737311B1 true KR102737311B1 (ko) 2024-12-03

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Country Status (16)

Country Link
US (1) US10759726B2 (enExample)
EP (1) EP3400208B1 (enExample)
JP (1) JP6975152B2 (enExample)
KR (1) KR102737311B1 (enExample)
CN (1) CN108473401B (enExample)
AU (1) AU2017205265B2 (enExample)
BR (1) BR112018013543B1 (enExample)
CA (1) CA3010748C (enExample)
DK (1) DK3400208T3 (enExample)
MX (1) MX2018007750A (enExample)
PL (1) PL3400208T3 (enExample)
RU (1) RU2737159C2 (enExample)
TW (1) TWI739786B (enExample)
UA (1) UA123827C2 (enExample)
WO (1) WO2017118686A1 (enExample)
ZA (1) ZA201803648B (enExample)

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DE102019113135A1 (de) * 2019-05-17 2020-11-19 Rheinisch-Westfälische Technische Hochschule (Rwth) Aachen Verfahren zur Herstellung von Glycolen aus Zuckern und Zuckeralkoholen
EP4034524A4 (en) 2019-09-24 2023-05-31 Iowa Corn Promotion Board METHOD OF RUNNING CONTINUOUS UNMODULATED PROCESSES WITH MULTIPLE CATALYTIC STEPS
US11680031B2 (en) 2020-09-24 2023-06-20 T. EN Process Technology, Inc. Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst

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US20050244312A1 (en) 2002-04-22 2005-11-03 Suppes Galen J Method of producing lower alcohols from glycerol
JP2013520486A (ja) 2010-02-26 2013-06-06 カウンシル・オヴ・サイエンティフィック・アンド・インダストリアル・リサーチ ヒドロキシアセトンまたはプロピレングリコールを調製するための方法
US20150329449A1 (en) 2014-05-19 2015-11-19 Iowa Corn Promotion Board Process for the continuous production of ethylene glycol from carbohydrates

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US5334778A (en) 1992-06-03 1994-08-02 Degussa Aktiengesellschaft Process for the production of 1,3-propanediol
US20050244312A1 (en) 2002-04-22 2005-11-03 Suppes Galen J Method of producing lower alcohols from glycerol
JP2013520486A (ja) 2010-02-26 2013-06-06 カウンシル・オヴ・サイエンティフィック・アンド・インダストリアル・リサーチ ヒドロキシアセトンまたはプロピレングリコールを調製するための方法
US20150329449A1 (en) 2014-05-19 2015-11-19 Iowa Corn Promotion Board Process for the continuous production of ethylene glycol from carbohydrates

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UA123827C2 (uk) 2021-06-09
RU2018128473A (ru) 2020-02-07
CN108473401B (zh) 2021-08-27
CA3010748A1 (en) 2017-07-13
EP3400208A1 (en) 2018-11-14
CA3010748C (en) 2023-08-22
AU2017205265B2 (en) 2021-05-27
TW201739729A (zh) 2017-11-16
MX2018007750A (es) 2018-11-14
US10759726B2 (en) 2020-09-01
TWI739786B (zh) 2021-09-21
ZA201803648B (en) 2022-12-21
AU2017205265A1 (en) 2018-06-21
KR20180100613A (ko) 2018-09-11
JP2019501193A (ja) 2019-01-17
EP3400208B1 (en) 2021-07-28
PL3400208T3 (pl) 2021-12-27
RU2018128473A3 (enExample) 2020-03-18
DK3400208T3 (da) 2021-09-20
BR112018013543B1 (pt) 2022-02-08
CN108473401A (zh) 2018-08-31
RU2737159C2 (ru) 2020-11-25
US20190010104A1 (en) 2019-01-10
JP6975152B2 (ja) 2021-12-01
WO2017118686A1 (en) 2017-07-13
BR112018013543A2 (pt) 2018-12-04

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