AR063358A1 - Mejora de la selectividad en la hidrogenolisis de glicerol - Google Patents
Mejora de la selectividad en la hidrogenolisis de glicerolInfo
- Publication number
- AR063358A1 AR063358A1 ARP070104690A ARP070104690A AR063358A1 AR 063358 A1 AR063358 A1 AR 063358A1 AR P070104690 A ARP070104690 A AR P070104690A AR P070104690 A ARP070104690 A AR P070104690A AR 063358 A1 AR063358 A1 AR 063358A1
- Authority
- AR
- Argentina
- Prior art keywords
- formation
- selectivity
- hydrogenolysis
- polyols
- glycerol
- Prior art date
Links
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 title abstract 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 6
- 230000015572 biosynthetic process Effects 0.000 abstract 5
- 238000007327 hydrogenolysis reaction Methods 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 229920005862 polyol Polymers 0.000 abstract 3
- 150000003077 polyols Chemical class 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical class CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000011949 solid catalyst Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by elimination of -OH groups, e.g. by dehydration
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La presente proporciona métodos para la hidrogenolisis de polioles, los cuales maximizan la selectividad de la reaccion hacia la formacion de propilenglicol y minimizan la formacion de otros polioles. En una modalidad, la presente divulga procesos para la hidrogenolisis de glicerol, los cuales maximizan la selectividad de la reaccion hacia la formacion de propilenglicol y minimizan la formacion de otros polioles. Particularmente la presente se refiere a un proceso para la hidrogenolisis de glicerol que comprende poner glicerol en contacto con hidrogeno y un catalizador solido a una velocidad espacial líquida por hora de 0,5h-1 a 2,5h-1 para minimizar la formacion de butanodioles.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US85357406P | 2006-10-23 | 2006-10-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR063358A1 true AR063358A1 (es) | 2009-01-21 |
Family
ID=39146898
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP070104690A AR063358A1 (es) | 2006-10-23 | 2007-10-23 | Mejora de la selectividad en la hidrogenolisis de glicerol |
Country Status (3)
| Country | Link |
|---|---|
| US (3) | US7928148B2 (es) |
| AR (1) | AR063358A1 (es) |
| WO (1) | WO2008051540A2 (es) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080274019A1 (en) * | 2007-04-24 | 2008-11-06 | Joseph Robert Beggin | Preparation of Derivative of Polyhydric Alcohols |
| US20090246430A1 (en) | 2008-03-28 | 2009-10-01 | The Coca-Cola Company | Bio-based polyethylene terephthalate polymer and method of making same |
| US20090264687A1 (en) | 2008-04-16 | 2009-10-22 | Battelle Memorial Institute | Chemical Production Processes and Systems |
| GB0807255D0 (en) * | 2008-04-21 | 2008-05-28 | Isis Innovation | Methanol production process |
| US8101807B2 (en) * | 2008-12-23 | 2012-01-24 | Uop Llc | Methods for converting glycerol to propanol |
| CN105254858A (zh) | 2009-03-03 | 2016-01-20 | 可口可乐公司 | 生物基聚对苯二甲酸乙二酯包装及制备其的方法 |
| BRPI0902818A2 (pt) * | 2009-03-09 | 2010-11-23 | Petroleo Brasileiro Sa | processo de produção de propilenoglicol a partir de glicerina de biodiesel |
| WO2010144448A2 (en) * | 2009-06-08 | 2010-12-16 | University Of Kansas | Polyol hydrogenolysis by in-situ generated hydrogen |
| US8357621B2 (en) * | 2009-06-29 | 2013-01-22 | E.I. Du Pont De Nemours And Company | Soil resist method |
| US7901589B2 (en) * | 2009-06-29 | 2011-03-08 | E.I. Du Pont De Nemours And Company | Propanediol soil resist compositions |
| US9447347B2 (en) * | 2009-12-31 | 2016-09-20 | Shell Oil Company | Biofuels via hydrogenolysis-condensation |
| US8937202B2 (en) * | 2010-02-23 | 2015-01-20 | Battelle Memorial Institute | Processes and systems for the production of propylene glycol from glycerol |
| US20110207972A1 (en) * | 2010-02-23 | 2011-08-25 | Battelle Memorial Institute | Catalysts and processes for the hydrogenolysis of glycerol and other organic compounds for producing polyols and propylene glycol |
| BRPI1000430A2 (pt) | 2010-02-24 | 2011-10-25 | Petroleo Brasileiro Sa | produção de propilenoglicol a partir de glicerina |
| WO2011115781A1 (en) * | 2010-03-17 | 2011-09-22 | The Regents Of The University Of California | Conversion of oxygenates to hydrocarbon fuels by deoxygenation |
| EP3153219B1 (en) * | 2011-03-14 | 2019-06-19 | Archer Daniels Midland Company | Improved methods for producing bioderived propylene glycol |
| US20140107380A1 (en) * | 2011-05-11 | 2014-04-17 | Archer Daniels Midland Company | Method for producing bioderived dipropylene and tripropylene glycols without propylene oxide |
| US9778243B2 (en) | 2011-06-14 | 2017-10-03 | The Coca-Cola Company | Methods for measuring renewable bio-source content in renewable bioplastic materials |
| PL2720991T3 (pl) * | 2011-06-14 | 2015-12-31 | Shell Int Research | Współwytwarzanie biopaliw i glikoli |
| EP2720992B1 (en) | 2011-06-14 | 2015-07-29 | Shell Internationale Research Maatschappij B.V. | Co-production of biofuels and glycols |
| ITMI20112290A1 (it) * | 2011-12-16 | 2013-06-17 | Dks Aromatic Srl | Composizione per sigarette elettroniche |
| WO2014062757A1 (en) * | 2012-10-17 | 2014-04-24 | Archer Daniels Midland Company | Improved hydrogenolysis catalysts and uses thereof |
| WO2014081951A1 (en) * | 2012-11-21 | 2014-05-30 | University Of Tennesee Research Foundation | Methods, systems and devices for simultaneous production of lactic acid and propylene glycol from glycerol |
| EP4086239A1 (en) * | 2014-04-22 | 2022-11-09 | Archer Daniels Midland Company | Improved process of making bioderived propylene glycol |
| US11253839B2 (en) | 2014-04-29 | 2022-02-22 | Archer-Daniels-Midland Company | Shaped porous carbon products |
| PL3160928T3 (pl) | 2014-06-30 | 2024-03-04 | Topsoe A/S | Sposób wytwarzania glikolu etylenowego z cukrów |
| JP6846202B2 (ja) | 2014-06-30 | 2021-03-24 | ハルドール・トプサー・アクチエゼルスカベット | 糖からのエチレングリコールの製造方法 |
| EP3322526B1 (en) * | 2015-07-15 | 2022-02-16 | Archer Daniels Midland Company | Improved copper-containing multimetallic catalysts, and method for using the same to make biobased 1,2-propanediol |
| AU2017205691B2 (en) | 2016-01-07 | 2021-06-17 | Haldor Topsøe A/S | Process for the preparation of ethylene glycol from sugars |
| RU2737159C2 (ru) | 2016-01-07 | 2020-11-25 | Хальдор Топсёэ А/С | Способ получения этиленгликоля из сахаров |
| US9796948B2 (en) | 2016-01-13 | 2017-10-24 | The Procter & Gamble Company | Laundry detergent compositions comprising renewable components |
| JP7094894B2 (ja) | 2016-06-03 | 2022-07-04 | アイオワ・コーン・プロモーション・ボード | アルドヘキソースを生じる炭水化物のエチレングリコールへの高度に選択的な変換のための連続プロセス |
| US10472310B2 (en) | 2016-06-03 | 2019-11-12 | Iowa Corn Promotion Board | Continuous processes for the highly selective conversion of sugars to propylene glycol or mixtures of propylene glycol and ethylene glycol |
| CN105949034B (zh) * | 2016-06-24 | 2017-10-10 | 湘潭大学 | 一种由甘油水液直接氢解生成1,2‑丙二醇的方法 |
| WO2020097297A1 (en) | 2018-11-07 | 2020-05-14 | The Procter & Gamble Company | Low ph detergent composition |
| WO2020102477A1 (en) | 2018-11-16 | 2020-05-22 | The Procter & Gamble Company | Composition and method for removing stains from fabrics |
| CN110082837A (zh) * | 2019-06-03 | 2019-08-02 | 长安大学 | 一种探寻碳同位素存在的方法 |
| BR112022022606A2 (pt) * | 2020-05-18 | 2022-12-20 | Archer Daniels Midland Co | Processos para a hidrogenólise de glicerol |
| CN117043225A (zh) | 2021-01-29 | 2023-11-10 | 布拉斯科公司 | 具有提高的结晶控制的2,4-fdca的共聚酯 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4401823A (en) | 1981-05-18 | 1983-08-30 | Uop Inc. | Hydrogenolysis of polyhydroxylated compounds |
| DE3928285A1 (de) * | 1989-08-26 | 1991-02-28 | Basf Ag | Verfahren zur herstellung niederer, mehrwertiger alkohole |
| IT1249955B (it) | 1991-07-10 | 1995-03-30 | Menon S R L | Procedimento di idrogenazione della glicerina |
| IT1249956B (it) * | 1991-07-10 | 1995-03-30 | Menon S R L | Procedimento di idrogenazione catalitica della glicerina |
| IT1256802B (it) | 1992-01-31 | 1995-12-15 | Novamont Spa | Catalizzatore di idrogenazione, procedimento per la sua preparazione ed impiego, particolarmente per l'drogenazione e/o idrogenolisi di carboidrati e polioli. |
| DE4302464A1 (de) * | 1993-01-29 | 1994-08-04 | Henkel Kgaa | Herstellung von 1,2-Propandiol aus Glycerin |
| US5977013A (en) * | 1996-12-19 | 1999-11-02 | Battelle Memorial Institute | Catalyst and method for aqueous phase reactions |
| US6570043B2 (en) | 1999-09-03 | 2003-05-27 | Battelle Memorial Institute | Converting sugars to sugar alcohols by aqueous phase catalytic hydrogenation |
| US6291725B1 (en) | 2000-03-03 | 2001-09-18 | Board Of Trustees Operating Michigan State University | Catalysts and process for hydrogenolysis of sugar alcohols to polyols |
| US6670300B2 (en) | 2001-06-18 | 2003-12-30 | Battelle Memorial Institute | Textured catalysts, methods of making textured catalysts, and methods of catalyzing reactions conducted in hydrothermal conditions |
| US6841085B2 (en) | 2001-10-23 | 2005-01-11 | Battelle Memorial Institute | Hydrogenolysis of 6-carbon sugars and other organic compounds |
| US6479713B1 (en) * | 2001-10-23 | 2002-11-12 | Battelle Memorial Institute | Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen |
| US7663004B2 (en) | 2002-04-22 | 2010-02-16 | The Curators Of The University Of Missouri | Method of producing lower alcohols from glycerol |
| GB0325386D0 (en) | 2003-10-30 | 2003-12-03 | Davy Process Techn Ltd | Process |
| US7888542B2 (en) | 2005-12-12 | 2011-02-15 | Neste Oil Oyj | Process for producing a saturated hydrocarbon component |
| WO2007095255A2 (en) | 2006-02-10 | 2007-08-23 | Dupont Tate & Lyle Bio Products Company, Llc | Biodegradable compositions comprising renewably-based, biodegradable 1.3-propanediol |
| US20070203323A1 (en) | 2006-02-10 | 2007-08-30 | Gyorgyi Fenyvesi | Food compositions comprising biologically-based biodegradable 1,3-propanediol esters |
| CA2642592A1 (en) * | 2006-03-03 | 2007-09-07 | Basf Se | Process for the preparation of 1,2-propanediol |
-
2007
- 2007-10-23 WO PCT/US2007/022481 patent/WO2008051540A2/en active Application Filing
- 2007-10-23 AR ARP070104690A patent/AR063358A1/es unknown
- 2007-10-23 US US11/876,912 patent/US7928148B2/en active Active
-
2008
- 2008-05-30 US US12/130,124 patent/US8153847B2/en active Active
- 2008-05-30 US US12/130,088 patent/US20090104092A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US20090104092A1 (en) | 2009-04-23 |
| US20080228014A1 (en) | 2008-09-18 |
| US7928148B2 (en) | 2011-04-19 |
| US20080103339A1 (en) | 2008-05-01 |
| WO2008051540A3 (en) | 2008-06-26 |
| WO2008051540A2 (en) | 2008-05-02 |
| US8153847B2 (en) | 2012-04-10 |
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| Date | Code | Title | Description |
|---|---|---|---|
| FB | Suspension of granting procedure |