KR102637919B1 - 리튬 이온 전기화학셀용 고체 전해질 - Google Patents
리튬 이온 전기화학셀용 고체 전해질 Download PDFInfo
- Publication number
- KR102637919B1 KR102637919B1 KR1020207008261A KR20207008261A KR102637919B1 KR 102637919 B1 KR102637919 B1 KR 102637919B1 KR 1020207008261 A KR1020207008261 A KR 1020207008261A KR 20207008261 A KR20207008261 A KR 20207008261A KR 102637919 B1 KR102637919 B1 KR 102637919B1
- Authority
- KR
- South Korea
- Prior art keywords
- compound
- solid electrolyte
- active material
- lithium
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 239000007784 solid electrolyte Substances 0.000 title claims abstract description 47
- 229910001416 lithium ion Inorganic materials 0.000 title abstract description 14
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 94
- 239000000203 mixture Substances 0.000 claims description 41
- 238000000227 grinding Methods 0.000 claims description 24
- 229910052744 lithium Inorganic materials 0.000 claims description 19
- 229910018091 Li 2 S Inorganic materials 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 14
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 12
- 239000011149 active material Substances 0.000 claims description 12
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 10
- 229910052801 chlorine Inorganic materials 0.000 claims description 9
- 229910052738 indium Inorganic materials 0.000 claims description 9
- 150000002500 ions Chemical class 0.000 claims description 9
- 229910052740 iodine Inorganic materials 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 230000005518 electrochemistry Effects 0.000 claims description 6
- 229910052794 bromium Inorganic materials 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 4
- OAEGRYMCJYIXQT-UHFFFAOYSA-N dithiooxamide Chemical compound NC(=S)C(N)=S OAEGRYMCJYIXQT-UHFFFAOYSA-N 0.000 claims description 4
- 239000011262 electrochemically active material Substances 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 150000003464 sulfur compounds Chemical class 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 150000001450 anions Chemical class 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims description 2
- MAHNFPMIPQKPPI-UHFFFAOYSA-N disulfur Chemical class S=S MAHNFPMIPQKPPI-UHFFFAOYSA-N 0.000 claims description 2
- 229910000314 transition metal oxide Inorganic materials 0.000 claims description 2
- 238000001228 spectrum Methods 0.000 description 23
- 239000000460 chlorine Substances 0.000 description 15
- 239000003792 electrolyte Substances 0.000 description 11
- -1 lithium halide Chemical class 0.000 description 11
- 239000007774 positive electrode material Substances 0.000 description 10
- 238000006467 substitution reaction Methods 0.000 description 9
- 238000002441 X-ray diffraction Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 239000011230 binding agent Substances 0.000 description 6
- 229910052750 molybdenum Inorganic materials 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 239000008188 pellet Substances 0.000 description 6
- 239000006182 cathode active material Substances 0.000 description 5
- 229910003480 inorganic solid Inorganic materials 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 239000007773 negative electrode material Substances 0.000 description 4
- 229910052758 niobium Inorganic materials 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 239000012448 Lithium borohydride Substances 0.000 description 3
- 230000018199 S phase Effects 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052727 yttrium Inorganic materials 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- 229920002943 EPDM rubber Polymers 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000006183 anode active material Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 2
- 229910001947 lithium oxide Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000871495 Heeria argentea Species 0.000 description 1
- 229910000846 In alloy Inorganic materials 0.000 description 1
- 229910000733 Li alloy Inorganic materials 0.000 description 1
- 229910001216 Li2S Inorganic materials 0.000 description 1
- 229910015118 LiMO Inorganic materials 0.000 description 1
- 229910016003 MoS3 Inorganic materials 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229910020346 SiS 2 Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910003092 TiS2 Inorganic materials 0.000 description 1
- 229910010322 TiS3 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical compound [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 description 1
- 208000020960 lithium transport Diseases 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910052960 marcasite Inorganic materials 0.000 description 1
- 238000000133 mechanosynthesis reaction Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229910052961 molybdenite Inorganic materials 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- TVWWSIKTCILRBF-UHFFFAOYSA-N molybdenum trisulfide Chemical compound S=[Mo](=S)=S TVWWSIKTCILRBF-UHFFFAOYSA-N 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- YGHCWPXPAHSSNA-UHFFFAOYSA-N nickel subsulfide Chemical compound [Ni].[Ni]=S.[Ni]=S YGHCWPXPAHSSNA-UHFFFAOYSA-N 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- RCYJPSGNXVLIBO-UHFFFAOYSA-N sulfanylidenetitanium Chemical compound [S].[Ti] RCYJPSGNXVLIBO-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/24—Hydrides containing at least two metals; Addition complexes thereof
- C01B6/246—Hydrides containing at least two metals; Addition complexes thereof also containing non-metals other than hydrogen
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/02—Amorphous compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Conductive Materials (AREA)
- Primary Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1758782A FR3071656B1 (fr) | 2017-09-22 | 2017-09-22 | Electrolyte solide pour element electrochimique lithium-ion |
| FR1758782 | 2017-09-22 | ||
| PCT/EP2018/075516 WO2019057840A1 (fr) | 2017-09-22 | 2018-09-20 | Electrolyte solide pour element electrochimique lithium-ion |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20200090739A KR20200090739A (ko) | 2020-07-29 |
| KR102637919B1 true KR102637919B1 (ko) | 2024-02-20 |
Family
ID=61750198
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020207008261A Active KR102637919B1 (ko) | 2017-09-22 | 2018-09-20 | 리튬 이온 전기화학셀용 고체 전해질 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US11670798B2 (enExample) |
| EP (1) | EP3685466B1 (enExample) |
| JP (1) | JP7182633B2 (enExample) |
| KR (1) | KR102637919B1 (enExample) |
| CN (1) | CN111213274A (enExample) |
| FR (1) | FR3071656B1 (enExample) |
| WO (1) | WO2019057840A1 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110112457A (zh) * | 2019-05-23 | 2019-08-09 | 桑德新能源技术开发有限公司 | 一种全固态电池及其制备方法 |
| CN110120510B (zh) * | 2019-05-23 | 2021-07-13 | 桑德新能源技术开发有限公司 | 一种全固态电池及其制备方法 |
| KR102414948B1 (ko) * | 2019-09-11 | 2022-07-01 | 미쓰이금속광업주식회사 | 황화물 고체 전해질 |
| US12334497B2 (en) | 2019-10-29 | 2025-06-17 | Mitsui Mining & Smelting Co., Ltd. | Solid electrolyte, and electrode mixture, solid electrolyte layer and solid-state battery, each using same |
| KR20220088688A (ko) * | 2019-10-29 | 2022-06-28 | 미쓰이금속광업주식회사 | 고체 전해질 및 그것을 사용한 전극 합제, 고체 전해질층, 고체 전지 |
| US12431533B2 (en) | 2019-10-29 | 2025-09-30 | Mitsui Mining & Smelting Co., Ltd. | Solid electrolyte, and electrode mixture, solid electrolyte layer and solid-state battery, each using same |
| CN115362586A (zh) * | 2020-03-23 | 2022-11-18 | 坚固力量公司 | 固体电解质材料及由其制成的固态电池 |
| US11588177B2 (en) | 2020-11-25 | 2023-02-21 | Samsung Electronics Co., Ltd | Solid-state electrolyte, solid-state battery including the electrolyte, and method of making the same |
| FR3118308B1 (fr) | 2020-12-18 | 2024-01-12 | Accumulateurs Fixes | Element electrochimique lithium-soufre tout solide |
| EP4266444A4 (en) * | 2020-12-18 | 2025-04-09 | Research Institute Of Industrial Science & Technology | SOLID ELECTROLYTE, PREPARATION METHOD THEREOF AND ALL-SOLID-STATE BATTERY COMPRISING SAME |
| CN113104813B (zh) * | 2021-04-08 | 2022-10-11 | 上海大学 | 一种硫化物固态电解质及其制备方法、全固态电池 |
| JP7666411B2 (ja) | 2022-06-13 | 2025-04-22 | トヨタ自動車株式会社 | イオン伝導体、全固体電池およびイオン伝導体の製造方法 |
| WO2024225810A1 (ko) * | 2023-04-26 | 2024-10-31 | 주식회사 엘지에너지솔루션 | 전고체전지용 수소화황화물계 고체전해질 및 그 제조방법 |
| CN117276642B (zh) * | 2023-08-16 | 2024-08-02 | 黄冈师范学院 | 一种钠离子硫化物电解质及其制备方法和应用 |
| FR3157001A1 (fr) | 2023-12-18 | 2025-06-20 | Saft | Electrolyte gélifié pour élément électrochimique au lithium |
| CN117913244B (zh) * | 2024-01-03 | 2025-11-11 | 安徽通能新能源科技有限公司 | 一种高倍率性能的钛硫化聚丙烯腈正极材料及其制备方法 |
| US20250379251A1 (en) * | 2024-06-11 | 2025-12-11 | Toyota Jidosha Kabushiki Kaisha | Mixture and battery |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016134316A (ja) | 2015-01-20 | 2016-07-25 | 出光興産株式会社 | 固体電解質 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007048289A1 (de) * | 2007-10-08 | 2009-04-09 | Universität Siegen | Lithium-Argyrodite |
| WO2013024537A1 (ja) * | 2011-08-17 | 2013-02-21 | 富士通株式会社 | リチウムイオン導電体及びその製造方法、全固体リチウム二次電池 |
| EP2919313A4 (en) * | 2012-11-06 | 2016-03-30 | Idemitsu Kosan Co | SOLID ELECTROLYTE |
| WO2015011937A1 (ja) * | 2013-07-25 | 2015-01-29 | 三井金属鉱業株式会社 | リチウムイオン電池用硫化物系固体電解質 |
| RU2665046C2 (ru) | 2013-09-02 | 2018-08-28 | Мицубиси Газ Кемикал Компани, Инк. | Твердотельная батарея |
| DE102013219606A1 (de) | 2013-09-27 | 2015-04-02 | Robert Bosch Gmbh | Elektrodenmaterial mit Lithium-Argyrodit |
| JP2014089971A (ja) * | 2013-12-18 | 2014-05-15 | Toyota Motor Corp | 硫化物固体電解質材料、リチウム固体電池、および、硫化物固体電解質材料の製造方法 |
| CN107112065B (zh) * | 2014-12-22 | 2019-07-23 | 三菱瓦斯化学株式会社 | 离子导体及其制造方法 |
| US9640836B1 (en) * | 2016-02-12 | 2017-05-02 | Toyota Motor Engineering & Manufacturing North America, Inc. | Class of solid state electrolytes for magnesium batteries |
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2017
- 2017-09-22 FR FR1758782A patent/FR3071656B1/fr active Active
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2018
- 2018-09-20 EP EP18769383.3A patent/EP3685466B1/fr active Active
- 2018-09-20 KR KR1020207008261A patent/KR102637919B1/ko active Active
- 2018-09-20 US US16/648,329 patent/US11670798B2/en active Active
- 2018-09-20 CN CN201880061262.5A patent/CN111213274A/zh active Pending
- 2018-09-20 JP JP2020537861A patent/JP7182633B2/ja active Active
- 2018-09-20 WO PCT/EP2018/075516 patent/WO2019057840A1/fr not_active Ceased
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2016134316A (ja) | 2015-01-20 | 2016-07-25 | 出光興産株式会社 | 固体電解質 |
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| Title |
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| Journal of Power Sources Volume 244, 15 December 2013, Pages 707-710 |
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|---|---|
| US20200227776A1 (en) | 2020-07-16 |
| KR20200090739A (ko) | 2020-07-29 |
| US11670798B2 (en) | 2023-06-06 |
| FR3071656A1 (fr) | 2019-03-29 |
| JP2020534245A (ja) | 2020-11-26 |
| FR3071656B1 (fr) | 2019-10-11 |
| CN111213274A (zh) | 2020-05-29 |
| EP3685466B1 (fr) | 2021-09-08 |
| EP3685466A1 (fr) | 2020-07-29 |
| JP7182633B2 (ja) | 2022-12-02 |
| WO2019057840A1 (fr) | 2019-03-28 |
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