KR102615452B1 - 2,5-다이클로로페놀을 제조하는 방법 - Google Patents

2,5-다이클로로페놀을 제조하는 방법 Download PDF

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KR102615452B1
KR102615452B1 KR1020177011983A KR20177011983A KR102615452B1 KR 102615452 B1 KR102615452 B1 KR 102615452B1 KR 1020177011983 A KR1020177011983 A KR 1020177011983A KR 20177011983 A KR20177011983 A KR 20177011983A KR 102615452 B1 KR102615452 B1 KR 102615452B1
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dichlorophenol
zeolite
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zeolite catalyst
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KR20170063923A (ko
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캄-토 완
존 에이치 안
존 왕
돈 프로브스트
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몬산토 테크놀로지 엘엘씨
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
    • C07C37/88—Use of additives, e.g. for stabilisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J35/1038—
    • B01J35/1057—
    • B01J35/1061—
    • B01J35/1066—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/24—Halogenated derivatives
    • C07C39/26—Halogenated derivatives monocyclic monohydroxylic containing halogen bound to ring carbon atoms
    • C07C39/27—Halogenated derivatives monocyclic monohydroxylic containing halogen bound to ring carbon atoms all halogen atoms being bound to ring carbon atoms
    • C07C39/30—Halogenated derivatives monocyclic monohydroxylic containing halogen bound to ring carbon atoms all halogen atoms being bound to ring carbon atoms the halogen being two chlorine atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/367—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/42—Unsaturated compounds containing hydroxy or O-metal groups
    • C07C59/56—Unsaturated compounds containing hydroxy or O-metal groups containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40—Unsaturated compounds
    • C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
    • C07C59/64—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Nanotechnology (AREA)
  • Catalysts (AREA)
KR1020177011983A 2014-10-02 2015-10-02 2,5-다이클로로페놀을 제조하는 방법 Active KR102615452B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201462058886P 2014-10-02 2014-10-02
US62/058,886 2014-10-02
US201462091995P 2014-12-15 2014-12-15
US62/091,995 2014-12-15
PCT/US2015/053715 WO2016054506A1 (en) 2014-10-02 2015-10-02 Processes for preparing 2,5-dichlorophenol

Publications (2)

Publication Number Publication Date
KR20170063923A KR20170063923A (ko) 2017-06-08
KR102615452B1 true KR102615452B1 (ko) 2023-12-19

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US (2) US10550063B2 (https=)
EP (1) EP3201164B1 (https=)
JP (1) JP6752783B2 (https=)
KR (1) KR102615452B1 (https=)
CN (2) CN113801001A (https=)
BR (1) BR112017006338B1 (https=)
WO (1) WO2016054506A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11065611B2 (en) * 2016-10-05 2021-07-20 Monsanto Technology Llc Emission control during catalyst regeneration
CN113160901B (zh) * 2021-03-24 2023-01-03 柳州东风容泰化工股份有限公司 一种提高氯代苯酚合成率的方法及装置
EP4166531A1 (en) * 2021-10-12 2023-04-19 Studiengesellschaft Kohle mbH Process for preparing a phenolic hydrocarbon

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* Cited by examiner, † Cited by third party
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US2480817A (en) 1947-06-17 1949-08-30 Us Rubber Co Preparation of polychlorophenoxyacetic acids useful as plant growth regulators
US2651659A (en) 1952-01-31 1953-09-08 Us Rubber Co Preparation of 2, 4-dichlorophenoxyacetic acid
US2708209A (en) 1953-10-29 1955-05-10 Olin Mathieson Process for selective crystallization of 2, 5-dichlorophenol
US3013054A (en) 1958-08-04 1961-12-12 Velsicol Chemical Corp 2-methoxy-3, 6-dichlorobenzoates
DE1493493A1 (de) 1965-09-10 1969-02-20 Boehringer Sohn Ingelheim Verfahren zur Gewinnung von 2,5-Dichlorphenol aus einem Isomerengemisch von 2,4- und 2,5-Dichlorphenol
GB1221019A (en) 1968-02-09 1971-02-03 Coalite Chem Prod Ltd Process for the production of dihalophenols
US4418235A (en) * 1980-02-14 1983-11-29 Mobil Oil Corporation Hydrocarbon conversion with zeolite having enhanced catalytic activity
US4326994A (en) * 1980-02-14 1982-04-27 Mobil Oil Corporation Enhancement of zeolite catalytic activity
JPS58144330A (ja) * 1982-02-24 1983-08-27 Toray Ind Inc ポリハロゲン化芳香族化合物の異性化方法
EP0144760B1 (de) * 1983-11-12 1989-01-04 Hoechst Aktiengesellschaft Verfahren zur Isomerisierung von Mono- oder Dichlorophenolen
DE3340997A1 (de) * 1983-11-12 1985-05-23 Hoechst Ag, 6230 Frankfurt Verfahren zur isomerisierung von chlorphenolen
JP2725179B2 (ja) * 1988-04-21 1998-03-09 日本カーバイド工業株式会社 ２，４，５−トリフルオロー３−ヒドロキシ安息香酸の製造方法
US5118876A (en) 1989-01-18 1992-06-02 Zinnen Hermann A Separation of dichlorophenol isomers with zeolite adsorbents
FR2648810B1 (fr) 1989-06-22 1992-02-28 Rhone Poulenc Chimie Procede de preparation de phenols
US5110995A (en) 1991-03-12 1992-05-05 Institute Of Catalysis Preparation of phenol or phenol derivatives
RU2058286C1 (ru) 1994-04-12 1996-04-20 Институт катализа им.Г.К.Борескова СО РАН Способ получения фенола или его производных
RU2074164C1 (ru) 1994-04-12 1997-02-27 Институт катализа им.Г.К.Борескова СО РАН Способ получения фенола или его производных
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US6156938A (en) 1997-04-03 2000-12-05 Solutia, Inc. Process for making phenol or phenol derivatives
AU2387597A (en) 1997-04-17 1998-11-13 Novartis Ag Process for the hydroxylation of 1,4-dichlorobenzene
RU2127721C1 (ru) 1997-07-29 1999-03-20 Институт органической химии им.Зелинского РАН Способ получения фенола и его производных
CA2240612A1 (en) * 1997-07-29 1999-01-29 Vladimir Borisovich Kazansky Preparation of phenol and its derivatives
ES2167106T3 (es) 1998-04-30 2002-05-01 Creavis Tech & Innovation Gmbh Procedimiento para preparar compuestos aromaticos que contienen grupos hidroxilo.
RU2155181C1 (ru) 1999-04-05 2000-08-27 Кустов Леонид Модестович Способ окисления бензола и/или толуола в фенол и/или крезолы
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RU2192308C1 (ru) 2001-02-19 2002-11-10 Институт катализа им. Г.К.Борескова СО РАН Способ активации цеолитных катализаторов для процесса окислительного гидроксилирования ароматических соединений
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CN113801001A (zh) 2021-12-17
CN107001211B (zh) 2021-10-29
US20200216379A1 (en) 2020-07-09
US10550063B2 (en) 2020-02-04
BR112017006338B1 (pt) 2021-11-16
JP6752783B2 (ja) 2020-09-09
BR112017006338A2 (pt) 2017-12-19
EP3201164B1 (en) 2020-11-25
EP3201164A4 (en) 2018-06-06
WO2016054506A1 (en) 2016-04-07
KR20170063923A (ko) 2017-06-08
CN107001211A (zh) 2017-08-01
EP3201164A1 (en) 2017-08-09
JP2017530150A (ja) 2017-10-12
US20170247310A1 (en) 2017-08-31
US11008276B2 (en) 2021-05-18

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