KR102445015B1 - 선택적 SiO2 퇴적을 사용하여 자기 정렬된 콘택을 형성하는 방법 - Google Patents
선택적 SiO2 퇴적을 사용하여 자기 정렬된 콘택을 형성하는 방법 Download PDFInfo
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- KR102445015B1 KR102445015B1 KR1020180018268A KR20180018268A KR102445015B1 KR 102445015 B1 KR102445015 B1 KR 102445015B1 KR 1020180018268 A KR1020180018268 A KR 1020180018268A KR 20180018268 A KR20180018268 A KR 20180018268A KR 102445015 B1 KR102445015 B1 KR 102445015B1
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- 238000000034 method Methods 0.000 title claims abstract description 62
- 230000008021 deposition Effects 0.000 title abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title 2
- 229910052681 coesite Inorganic materials 0.000 title 1
- 229910052906 cristobalite Inorganic materials 0.000 title 1
- 239000000377 silicon dioxide Substances 0.000 title 1
- 235000012239 silicon dioxide Nutrition 0.000 title 1
- 229910052682 stishovite Inorganic materials 0.000 title 1
- 229910052905 tridymite Inorganic materials 0.000 title 1
- 239000010410 layer Substances 0.000 claims abstract description 126
- 229910052751 metal Inorganic materials 0.000 claims abstract description 85
- 239000002184 metal Substances 0.000 claims abstract description 85
- 229910004298 SiO 2 Inorganic materials 0.000 claims abstract description 62
- 239000000758 substrate Substances 0.000 claims abstract description 62
- 238000000151 deposition Methods 0.000 claims abstract description 35
- 239000003054 catalyst Substances 0.000 claims abstract description 21
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011248 coating agent Substances 0.000 claims abstract description 14
- 238000000576 coating method Methods 0.000 claims abstract description 14
- 238000005530 etching Methods 0.000 claims abstract description 12
- 239000011229 interlayer Substances 0.000 claims abstract description 9
- 239000007789 gas Substances 0.000 claims description 35
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 230000003301 hydrolyzing effect Effects 0.000 claims description 6
- ORJFXWYTRPGGRK-UHFFFAOYSA-N hydroxy-tris(2-methylbutan-2-yloxy)silane Chemical compound CCC(C)(C)O[Si](O)(OC(C)(C)CC)OC(C)(C)CC ORJFXWYTRPGGRK-UHFFFAOYSA-N 0.000 claims description 5
- 238000003672 processing method Methods 0.000 claims description 5
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 4
- 239000007800 oxidant agent Substances 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 3
- MBMITMZVBNZJTQ-UHFFFAOYSA-N hydroxy-bis[(2-methylpropan-2-yl)oxy]-propan-2-yloxysilane Chemical compound CC(C)O[Si](O)(OC(C)(C)C)OC(C)(C)C MBMITMZVBNZJTQ-UHFFFAOYSA-N 0.000 claims description 2
- HLDBBQREZCVBMA-UHFFFAOYSA-N hydroxy-tris[(2-methylpropan-2-yl)oxy]silane Chemical compound CC(C)(C)O[Si](O)(OC(C)(C)C)OC(C)(C)C HLDBBQREZCVBMA-UHFFFAOYSA-N 0.000 claims description 2
- 239000010936 titanium Substances 0.000 description 34
- 239000010408 film Substances 0.000 description 24
- 239000002243 precursor Substances 0.000 description 11
- 229910052782 aluminium Inorganic materials 0.000 description 8
- 230000004888 barrier function Effects 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 238000000059 patterning Methods 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- 239000010949 copper Substances 0.000 description 4
- 239000003446 ligand Substances 0.000 description 4
- 239000011295 pitch Substances 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- 229910052721 tungsten Inorganic materials 0.000 description 4
- 239000010937 tungsten Substances 0.000 description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 3
- 238000003917 TEM image Methods 0.000 description 3
- -1 aryloxides Chemical class 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 229910017083 AlN Inorganic materials 0.000 description 1
- 229910017109 AlON Inorganic materials 0.000 description 1
- 229910019001 CoSi Inorganic materials 0.000 description 1
- 229910018565 CuAl Inorganic materials 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 229910016006 MoSi Inorganic materials 0.000 description 1
- 229910005883 NiSi Inorganic materials 0.000 description 1
- 229910004491 TaAlN Inorganic materials 0.000 description 1
- 229910010041 TiAlC Inorganic materials 0.000 description 1
- 229910010037 TiAlN Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 229910010282 TiON Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000003983 crown ethers Chemical class 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 150000003235 pyrrolidines Chemical class 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- MNWRORMXBIWXCI-UHFFFAOYSA-N tetrakis(dimethylamido)titanium Chemical compound CN(C)[Ti](N(C)C)(N(C)C)N(C)C MNWRORMXBIWXCI-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
- 229910006400 μ-Cl Inorganic materials 0.000 description 1
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- H01L23/522—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body
- H01L23/532—Arrangements for conducting electric current within the device in operation from one component to another, i.e. interconnections, e.g. wires, lead frames including external interconnections consisting of a multilayer structure of conductive and insulating layers inseparably formed on the semiconductor body characterised by the materials
- H01L23/5329—Insulating materials
- H01L23/53295—Stacked insulating layers
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| US201762458858P | 2017-02-14 | 2017-02-14 | |
| US62/458,858 | 2017-02-14 |
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| US10847363B2 (en) | 2017-11-20 | 2020-11-24 | Tokyo Electron Limited | Method of selective deposition for forming fully self-aligned vias |
| US10957579B2 (en) | 2018-11-06 | 2021-03-23 | Samsung Electronics Co., Ltd. | Integrated circuit devices including a via and methods of forming the same |
| CN110010460B (zh) * | 2019-03-26 | 2021-03-16 | 贵阳学院 | 一种低维材料形成方法 |
| TWI801614B (zh) * | 2019-06-21 | 2023-05-11 | 聯華電子股份有限公司 | 半導體元件及其製作方法 |
| KR102833589B1 (ko) | 2019-08-23 | 2025-07-15 | 삼성전자주식회사 | 반도체 소자 및 이의 제조 방법 |
| US11227792B2 (en) * | 2019-09-19 | 2022-01-18 | International Business Machines Corporation | Interconnect structures including self aligned vias |
| US11361989B2 (en) * | 2020-02-11 | 2022-06-14 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method for manufacturing interconnect structures including air gaps |
| US20220254630A1 (en) * | 2021-02-08 | 2022-08-11 | Tokyo Electron Limited | Liquid phase conformal silicon oxide spin-on deposition |
| US11482454B2 (en) | 2021-02-17 | 2022-10-25 | Tokyo Electron Limited | Methods for forming self-aligned contacts using spin-on silicon carbide |
| US11756790B2 (en) | 2021-03-09 | 2023-09-12 | Tokyo Electron Limited | Method for patterning a dielectric layer |
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| JP2010225899A (ja) | 2009-03-24 | 2010-10-07 | Elpida Memory Inc | 半導体装置の製造方法 |
| JP2013080861A (ja) | 2011-10-05 | 2013-05-02 | Toshiba Corp | 半導体装置 |
| US20160293731A1 (en) | 2014-11-24 | 2016-10-06 | International Business Machines Corporation | Replacement metal gate dielectric cap |
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| EP0362571A3 (en) * | 1988-10-07 | 1990-11-28 | International Business Machines Corporation | Method for forming semiconductor components |
| JP3469251B2 (ja) * | 1990-02-14 | 2003-11-25 | 株式会社東芝 | 半導体装置の製造方法 |
| JP4063619B2 (ja) * | 2002-03-13 | 2008-03-19 | Necエレクトロニクス株式会社 | 半導体装置の製造方法 |
| US7294593B2 (en) | 2002-11-21 | 2007-11-13 | Kimberly-Clark Worldwide, Inc. | Absorbent article material with elastomeric borders |
| US6867152B1 (en) | 2003-09-26 | 2005-03-15 | Novellus Systems, Inc. | Properties of a silica thin film produced by a rapid vapor deposition (RVD) process |
| US8158488B2 (en) | 2004-08-31 | 2012-04-17 | Micron Technology, Inc. | Method of increasing deposition rate of silicon dioxide on a catalyst |
| US7271112B1 (en) * | 2004-12-30 | 2007-09-18 | Novellus Systems, Inc. | Methods for forming high density, conformal, silica nanolaminate films via pulsed deposition layer in structures of confined geometry |
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| US20170092533A1 (en) | 2015-09-29 | 2017-03-30 | Applied Materials, Inc. | Selective silicon dioxide deposition using phosphonic acid self assembled monolayers as nucleation inhibitor |
| US10049913B2 (en) | 2016-04-12 | 2018-08-14 | Tokyo Electron Limited | Methods for SiO2 filling of fine recessed features and selective SiO2 deposition on catalytic surfaces |
| KR20170135115A (ko) * | 2016-05-30 | 2017-12-08 | 삼성전자주식회사 | 반도체 장치 및 그 제조 방법 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010225899A (ja) | 2009-03-24 | 2010-10-07 | Elpida Memory Inc | 半導体装置の製造方法 |
| JP2013080861A (ja) | 2011-10-05 | 2013-05-02 | Toshiba Corp | 半導体装置 |
| US20160293731A1 (en) | 2014-11-24 | 2016-10-06 | International Business Machines Corporation | Replacement metal gate dielectric cap |
Also Published As
| Publication number | Publication date |
|---|---|
| JP7097713B2 (ja) | 2022-07-08 |
| TW201841215A (zh) | 2018-11-16 |
| KR20180093833A (ko) | 2018-08-22 |
| US10453749B2 (en) | 2019-10-22 |
| TWI764986B (zh) | 2022-05-21 |
| US20180233407A1 (en) | 2018-08-16 |
| JP2018133568A (ja) | 2018-08-23 |
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