KR102333045B1 - 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법 - Google Patents

중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법 Download PDF

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KR102333045B1
KR102333045B1 KR1020180074167A KR20180074167A KR102333045B1 KR 102333045 B1 KR102333045 B1 KR 102333045B1 KR 1020180074167 A KR1020180074167 A KR 1020180074167A KR 20180074167 A KR20180074167 A KR 20180074167A KR 102333045 B1 KR102333045 B1 KR 102333045B1
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feedstock
isobutene
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polymerization
water
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KR20190001943A (ko
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필립 디미트로브
리차드 제이. 세버트
토마스 스코어리스
제레미 위버
쟈콥 에머트
루돌프 파우스트
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인피니움 인터내셔날 리미티드
유니버시티 오브 매사추세츠
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
    • C08F4/14—Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
KR1020180074167A 2017-06-28 2018-06-27 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법 Active KR102333045B1 (ko)

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US15/635,460 US10167352B1 (en) 2017-06-28 2017-06-28 Polymerization initiating system and method to produce highly reactive olefin functional polymers
US15/635,460 2017-06-28

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KR20190001943A KR20190001943A (ko) 2019-01-07
KR102333045B1 true KR102333045B1 (ko) 2021-11-29

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US (1) US10167352B1 (enExample)
EP (1) EP3421509B1 (enExample)
JP (1) JP7078953B2 (enExample)
KR (1) KR102333045B1 (enExample)
CN (1) CN109134719B (enExample)
CA (1) CA3009702C (enExample)
ES (1) ES2897629T3 (enExample)
SG (1) SG10201805524WA (enExample)

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KR102203006B1 (ko) 2019-04-24 2021-01-13 대림산업 주식회사 고반응성 폴리부텐의 제조 방법
US10829573B1 (en) 2019-05-21 2020-11-10 Infineum International Limited Method for forming highly reactive olefin functional polymers
CN111171197B (zh) * 2020-02-11 2022-08-02 北京石油化工学院 一种利用双官能团引发剂制备高活性聚异丁烯的方法及应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130158217A1 (en) 2011-12-16 2013-06-20 Infineum International Limited Polymerization initiating system and method to produce highly reactive olefin functional polymers
KR102004502B1 (ko) 2013-03-12 2019-07-26 유니버시티 오브 매사추세츠 고도로 반응성인 올레핀 작용성 폴리머를 생성하기 위한 중합화 개시 시스템 및 방법
KR102065510B1 (ko) 2013-10-11 2020-01-13 유니버시티 오브 매사추세츠 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법

Family Cites Families (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2682531A (en) 1951-03-31 1954-06-29 Standard Oil Dev Co Zirconium tetrachloride-ether complexes as low temperature polymerization catalyst
JPS4839599A (enExample) 1971-09-20 1973-06-11
US3850897A (en) 1971-11-26 1974-11-26 Snam Progetti Procedure for the production of polymers and copolymers of isobutylene
CA2019908A1 (en) 1989-12-28 1991-06-28 Rudolf Lukas Graft copolymers and the method and initiation system for preparation thereof
GB9025839D0 (en) 1990-11-28 1991-01-09 Bp Chem Int Ltd Cationic polymerisation of 1-olefins
US5286823A (en) 1991-06-22 1994-02-15 Basf Aktiengesellschaft Preparation of highly reactive polyisobutenes
US5350819A (en) 1993-02-19 1994-09-27 Exxon Chemical Patents Inc. Carbocationic catalysts and process for using said catalysts
WO1994028036A1 (en) 1993-05-20 1994-12-08 Exxon Chemical Patents Inc. Heterogeneous lewis acid-type catalysts
JP3203917B2 (ja) 1993-11-30 2001-09-04 ソニー株式会社 プロジェクタ用アクティブマトリクス液晶表示パネル
DE69513810T2 (de) 1994-03-31 2000-05-25 Infineum Usa Lp Polymerisationsreaktionen von kohlenwasserstoffen mit lewissäure enthaltende trägerkatalysatoren
US5710225A (en) 1996-08-23 1998-01-20 The Lubrizol Corporation Heteropolyacid catalyzed polymerization of olefins
DE19704482A1 (de) 1997-02-06 1998-08-13 Basf Ag Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten
DE19734176A1 (de) 1997-08-07 1999-02-11 Basf Ag Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten
US6407186B1 (en) 1997-12-12 2002-06-18 Basf Aktiengesellschaft Method for producing low-molecular, highly reactive polyisobutylene
CA2330529A1 (en) 1998-06-12 1999-12-16 Univation Technologies Llc Olefin polymerization process using activated lewis acid-base complexes
US6346585B1 (en) 1999-06-24 2002-02-12 The Lubrizol Corporation Ammonium heteropolyacid catalized polymerization of olefins
US6407170B1 (en) 1999-06-24 2002-06-18 The Lubrizol Corporation Dispersants prepared from high polydispersity olefin polymers
US6562913B1 (en) 1999-09-16 2003-05-13 Texas Petrochemicals Lp Process for producing high vinylidene polyisobutylene
DE19952030A1 (de) 1999-10-28 2001-05-03 Basf Ag Verfahren zur Herstellung von hochreaktiven Polyisobutenen
US6858690B2 (en) 1999-11-15 2005-02-22 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
DE10035298A1 (de) 2000-07-18 2002-01-31 Basf Ag Verfahren zur Herstellung von Polysiobutenen
KR100486044B1 (ko) 2000-11-13 2005-04-29 대림산업 주식회사 폴리부텐의 제조방법
WO2002040553A1 (de) 2000-11-17 2002-05-23 Basf Aktiengesellschaft Verfahren zur desaktivierung und rückgewinnung von bortrifluorid bei der herstellung von polyisobutenen
DE10061715A1 (de) 2000-12-12 2002-06-13 Basf Ag Verfahren zur Herstellung von Homo- und Copolymeren des Isobutens
DE10118182A1 (de) 2001-04-11 2002-10-17 Basf Ag Verfahren zur Aufarbeitung eines flüssigen Reaktionsaustrages der kationischen Polymerisation von Isobuten
DE10211418A1 (de) 2002-03-15 2003-09-25 Bayer Ag Verfahren zur Herstellung hochreaktiver Polyisobutene
AU2003254173A1 (en) 2002-08-13 2004-02-25 Exxonmobil Chemical Patents Inc. Process for polymerizing cationically polymerizable monomers
CN100402558C (zh) 2002-12-20 2008-07-16 埃克森美孚化学专利公司 聚合方法
AU2003297458A1 (en) 2002-12-20 2004-07-22 Exxonmobil Chemical Patents Inc. Polymerization processes
DE10303212A1 (de) 2003-01-24 2004-08-05 Basf Ag Verfahren zur Herstellung von Polyisobuten
DE10356768A1 (de) 2003-12-04 2005-07-07 Universität Karlsruhe (TH) - Körperschaft des öffentlichen Rechts Verfahren zur Herstellung von Salzen schwach koordinierender Anionen, derartige Salze sowie deren Verwendung
US20080269440A1 (en) 2005-01-05 2008-10-30 Rudolf Faust Polymerization of Olefins
DE102005055818A1 (de) 2005-11-21 2007-05-24 Basf Ag Verfahren zur Herstellung von hochreaktiven Isobutenhomo- oder -copolymeren mittels metallhaltiger Katalysatorkomplexe
WO2008095933A1 (de) 2007-02-09 2008-08-14 Basf Se Verfahren zur polymerisation von ethylenisch ungesättigten monomeren
US8394897B2 (en) 2008-03-25 2013-03-12 Chevron Oronite Company Llc Production of vinylidene-terminated polyolefins via quenching with monosulfides
US20090258803A1 (en) 2008-04-14 2009-10-15 Harrison James J Copolymers made with quasi-living polyolefins and unsaturated acidic reagents, dispersants using same, and methods of making same
US8063154B2 (en) 2008-06-24 2011-11-22 The University Of Southern Mississippi Preparation of exo-olefin terminated polyolefins via quenching with alkoxysilanes or ethers
CN101613423B (zh) 2008-06-27 2011-05-18 北京化工大学 一种用于合成高反应活性聚异丁烯的引发体系
WO2010139684A1 (de) 2009-06-05 2010-12-09 Basf Se Verbindung aus einem protonierten aromaten und einem schwach koordinierenden anion als polymerisationskatalysator für isobuten oder ein isobuten-haltiges monomerengemisch
CN101955558B (zh) * 2009-07-15 2013-03-13 北京化工大学 制备高反应活性聚异丁烯及其共聚物的引发体系
EP2496613B1 (de) 2009-11-04 2015-07-01 Basf Se Verfahren zur herstellung von homo- oder copolymeren
WO2011087057A1 (ja) 2010-01-13 2011-07-21 新日本製鐵株式会社 成形性に優れた高強度鋼板及びその製造方法
BR112012020302B1 (pt) * 2010-02-17 2021-08-17 Basf Se Processo para preparar homo- ou copolímeros de isobuteno de alta reatividade
US8349977B2 (en) 2010-02-17 2013-01-08 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
CN102050901B (zh) * 2010-11-23 2012-07-25 中国石油天然气股份有限公司吉林石化分公司 三氟化硼引发体系中分子量聚异丁烯的制备方法
US9562117B2 (en) 2010-11-30 2017-02-07 Basf Se Preparation of derivatives of isobutene copolymers
US8697820B2 (en) 2011-08-11 2014-04-15 Basf Se Process for preparing high-reactivity isobutene homo- or copolymers
BR112014002551A2 (pt) 2011-08-11 2017-03-14 Basf Se processo para preparar homo ou copolímeros de isobuteno de alta reatividade, e, polímeros de isobuteno
US9771554B2 (en) 2013-07-16 2017-09-26 Brown University Device and method for engineering living tissues
KR101658545B1 (ko) * 2014-08-22 2016-09-21 대림산업 주식회사 폴리부텐의 제조방법
US9771442B2 (en) * 2015-05-13 2017-09-26 University Of Massachusetts Polymerization initiating system and method to produce highly reactive olefin functional polymers

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130158217A1 (en) 2011-12-16 2013-06-20 Infineum International Limited Polymerization initiating system and method to produce highly reactive olefin functional polymers
KR102004502B1 (ko) 2013-03-12 2019-07-26 유니버시티 오브 매사추세츠 고도로 반응성인 올레핀 작용성 폴리머를 생성하기 위한 중합화 개시 시스템 및 방법
KR102065510B1 (ko) 2013-10-11 2020-01-13 유니버시티 오브 매사추세츠 중합 개시 시스템 및 고도로 반응성인 올레핀 작용성 폴리머를 제조하는 방법

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JP2019007003A (ja) 2019-01-17
CA3009702C (en) 2024-01-09
CA3009702A1 (en) 2018-12-28
EP3421509A1 (en) 2019-01-02
JP7078953B2 (ja) 2022-06-01
SG10201805524WA (en) 2019-01-30
KR20190001943A (ko) 2019-01-07
CN109134719A (zh) 2019-01-04
US10167352B1 (en) 2019-01-01
CN109134719B (zh) 2020-11-24
US20190002607A1 (en) 2019-01-03
EP3421509B1 (en) 2021-09-22
ES2897629T3 (es) 2022-03-02

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